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2.
Crosslinked poly(ethylene oxide) containing siloxanes fabricated through thiol‐ene photochemistry 下载免费PDF全文
Victor A. Kusuma Elliot A. Roth William P. Clafshenkel Steven S. Klara Xu Zhou Surendar R. Venna Erik Albenze David R. Luebke Meagan S. Mauter Richard R. Koepsel Alan J. Russell David Hopkinson Hunaid B. Nulwala 《Journal of polymer science. Part A, Polymer chemistry》2015,53(13):1548-1557
Homogenous amphiphilic crosslinked polymer films comprising of poly(ethylene oxide) and polysiloxane were synthesized utilizing thiol‐ene “ click ” photochemistry. A systematic variation in polymer composition was Carried out to obtain high quality films with varied amount of siloxane and poly(ethylene oxide). These films showed improved gas separation performance with high gas permeabilities with good CO2/N2 selectivity. Furthermore, the resulting films were also tested for its biocompatibility, as a carrier media which allow human adult mesenchymal stem cells to retain their capacity for osteoblastic differentiation after transplantation. The obtained crosslinked films were characterized using differential scanning calorimetry, dynamic mechanical analysis, thermogravimetric analysis, FTIR, Raman‐IR , and small angle X‐ray scattering. The synthesis ease and commercial availability of the starting materials suggests that these new crosslinked polymer networks could find applications in wide range of applications. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 1548–1557 相似文献
3.
Chromatographia - The reversed phase behaviour of high molecular mass polystyrenes was investigated on C18 bonded phase columns with ethyl acetate-methanol and ethyl acetateacetonitrile mobile... 相似文献
4.
Ohne Zusammenfassung 相似文献
5.
T. Engel M. Würtz S. Borneis St. Becker I. Klaft A. Kohl T. Kühl F. Laeri D. Marx K. Meier R. Neumann F. Schmitt P. Seelig L. Völker 《Hyperfine Interactions》1997,108(1-3):251-258
Laser spectroscopy at storage rings often suffers from a limited resolution due to Doppler-broadened resonances. Broadening
is caused by the velocity spread of the ions stored in the beam. In the following, the present status of our work on laser
systems specialized on the specific needs of laser spectroscopy at storage rings is reported.
Two pulsed laser systems were developed. One is a dye laser whose spectral bandwidth can be switched by inserting different
Littrow-prisms into the resonator. An increase in bandwidth up to a factor of 45 was achieved. This laser was used for fast
qualitative scans and high resolution measurements. The other laser system is a Nd : YAG laser pumped optical parametric oscillator.
It is a tunable laser system covering the spectral range from 410 to 4000 nm. Furthermore, a continuous wave laser with a
frequency shifted feedback cavity is described. It shows broadband emission with an adjustable bandwidth of up to 4.5 GHz.
This laser can be advantageous for laser cooling of ion beams.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
6.
F. C. ten Doornkaat Koolman J. Traube Jandell Henderson Donald G. Russell und H. Bunzel 《Fresenius' Journal of Analytical Chemistry》1914,53(6):404
Ohne Zusammenfassung 相似文献
7.
The Fermi and Coulomb holes of the 21
S state of the helium isoelectronic sequence are investigated. Several interesting differences between the results obtained and those which might be expected on the basis of the corresponding 23
S state are pointed out and discussed. 相似文献
8.
Szklarzewicz Janusz Samotus Alina Nowicka Beata Burgess John Fawcett John Russell David R. 《Transition Metal Chemistry》1999,24(2):177-182
The X-ray crystal structure of (bpyH2)2[W(CN)8]·4H2 O (bpyH2=2,2-bipyridinium) is described. The [W(CN)8]4– anion has an approximately square antiprismatic (D4d) conformation, seemingly imposed by strong anion–water–cation hydrogen-bonding interactions. Bond distances in the anion are: WC 2.150(5), 2.163(5); CN 1.128(6), 1.145(6)Å and the angles WCN are 177.6(5), 178.3(5)°. The dihydrate and the anhydrous salt are both intensely black solids, exhibiting ion-pair charge-transfer interaction between cation and anion. E.s.r. spectra indicate that 30% of the tungsten is present as WV in the solid state, but that in solution only the WIV complex is present. The electron withdrawing effect of the cation is discussed and compared with that in a series of salts with different bipyridinium cations. 相似文献
9.
Ningyi Chen Jiayi Xu Michael Reuman Xun Li Ronald K. Russell Zhihua Sui 《Tetrahedron letters》2006,47(33):5909-5913
Various substituents were introduced onto the methyl group in 4-methyl coumarins through lithiation, followed by reactions with a wide range of electrophiles. The presence of an alkoxy group on 6′-phenyl ring was found to be pivotal for the success of this reaction. This procedure provided a convenient synthetic pathway to elaborate the methyl group of 4-methylcoumarins. Application of this methodology was showcased with the synthesis of biologically important novel tetracyclic chromene ring systems (n = 1-3). 相似文献
10.
Anzalone PW Baru AR Danielson EM Hayes PD Nguyen MP Panico AF Smith RC Mohan RS 《The Journal of organic chemistry》2005,70(6):2091-2096
[reaction: see text] Three one-pot methods for the conversion of aldehydes to homoallyl ethers catalyzed by Bi(OTf)(3).xH(2)O (1 < x < 4) have been developed. The one-pot synthesis of homoallyl ethers can be achieved either by in situ generation of the acetal followed by its reaction with allyltrialkylsilane or by a three-component synthesis in which the aldehyde, trimethylorthoformate or an alkoxytrimethylsilane and allyltrimethylsilane are mixed together in the presence of bismuth triflate (0.1-1.0 mol %). In addition, a three-component synthesis of homoallyl acetates, which is achieved by reacting the aldehyde, acetic anhydride, and allyltrimethylsilane in the presence of bismuth triflate (3.0-5.0 mol %), has been developed. The use of a relatively nontoxic, easy to handle, and inexpensive catalyst adds to the versatility of these methods. 相似文献