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1.
Marcella Massacesi Rosalba Pinna Gerolamo Devoto Ermanno Barni Piero Savarino Liliana Strinna Erre 《Transition Metal Chemistry》1984,9(9):351-355
Summary Complexes of general formula MLmCl2 · nH2O, where M=cobalt(II) or nickel(II); L=2-(4-methyl, 2-pyridyl)-benzimidazole (mpbi), 2-(4-methyl, 2-pyridyl)benzothiazole (mpbt), 2-(4-methyl, 2-pyridyl)benzoxazole (mpbo), 2-(4-methyl, 2-quinolyl)benzoxazole (mqbo), or 2-(4-methyl, 8-quinolyl)benzoxazole (mqbo); m=1,2; n=0–3, were prepared and characterized by t.g.a., conductance and magnetic measurements, i.r. and diffuse-reflectance electronic spectra.All the ligands behave as bidentate and coordinate through the pyridine- and isoxazole-nitrogen atoms.The nickel complexes have distorted octahedral or fivecoordinate structures. The cobalt complexes arepseudo-tet- rahedral except Co(mpbo)2Cl2·2H2O where the metal is six-coordinate. 相似文献
2.
Marco Biddau Marcella Massacesi Rosalba Pinna Gustavo Ponticelli 《Transition Metal Chemistry》1977,2(1):5-9
Summary Complexes of cobalt(II) and copper(II) with 5-amino-3,4-dimethylisoxazole (5-ADI) have been prepared and studied by means of magnetic susceptibility measurements, near and far i.r. spectra, electronic spectroscopy and, when possible, conductivity measurements. The 5-ADI generally behaves as bridging (Nring-, O- or Nring-, -NH2) ligand. All the complexes have an octahedral sterochemistry, except Co(5-ADI)2X2 (X = Cl, Br), Co2(5-ADI)7I4 which are tetrahedral and Cu(5-ADI)2 (ClO4)2 · 4 H2O which is square planar. 相似文献
3.
Ti(III)-induced free-radical decomposition of a phenyldiazonium salt, followed by phenyl radical iodine-atom abstraction from alkyl iodides, leads to a one-pot selective alkyl radical addition to the C-atom of imines generated in situ under aqueous acidic conditions. [reaction: see text] 相似文献
4.
McClenaghan ND Passalacqua R Loiseau F Campagna S Verheyde B Hameurlaine A Dehaen W 《Journal of the American Chemical Society》2003,125(18):5356-5365
Three new luminescent and redox-active Ru(II) complexes containing novel dendritic polypyridine ligands have been synthesized, and their absorption spectra, luminescence properties (both at room temperature in fluid solution and at 77 K in rigid matrix), and redox behavior have been investigated. The dendritic ligands are made of 1,10-phenanthroline coordinating subunits and of carbazole groups as branching sites. The first and second generation species of this novel class of dendritic ligands (L1 and L2, respectively; see Figure 1 for their structural formulas) have been prepared and employed. The metal dendrimers investigated are [Ru(bpy)(2)(L1)](2+) (1; bpy = 2,2'-bipyridine), [Ru(bpy)(2)(L2)](2+) (2), and [Ru(L1)(3)](2+) (3; see Figure 2). For the sake of completeness and comparison purposes, also the absorption spectra, redox behavior, and luminescence properties of L1 and L2 have been studied, together with the properties of 3,6-di(tert-butyl)carbazole (L0) and [Ru(bpy)(2)(phen)](2+) (4, phen = 1,10-phenanthroline). The absorption spectra of the free dendritic ligands show features which can be assigned to the various subunits (i.e., carbazole and phenanthroline groups) and additional bands at lower energies (at lambda > 300 nm) which are assigned to carbazole-to-phenanthroline charge-transfer (CT) transitions. These latter bands are significantly red-shifted upon acid and/or zinc acetate addition. Both L1 and L2 exhibit relatively intense luminescence at room temperature in fluid solution (lifetimes in the nanosecond time scale, quantum yields of the order of 10(-2)-10(-1)) and at 77 K in rigid matrix (lifetimes in the millisecond time scale). Such a luminescence is assigned to CT states at room temperature and to phenanthroline-centered pi-pi triplet levels at 77 K. The room-temperature luminescence of L1 and L2 is totally quenched by acid or zinc acetate. The metal dendrimers exhibit the typical absorption and luminescence properties of Ru(II) polypyridine complexes. In particular, metal-to-ligand charge-transfer (MLCT) bands dominate the visible absorption spectra, and formally triplet MLCT levels govern the excited-state properties. Excitation spectroscopy evidences that all the light absorbed by the dendritic branches is transferred with unitary efficiency to the luminescent MLCT states in 1-3, showing that the new metal dendrimers can be regarded as efficient light-harvesting antenna systems. All the free ligands and metal dendrimers exhibit a rich redox behavior (except L2 and 3, whose redox behavior was not investigated because of solubility reasons), with clearly attributable reversible carbazole- and metal-centered oxidation and polypyridine-centered reduction processes. The electronic interaction between the carbazole redox-active sites of the dendritic ligands is affected by Ru(II) coordination. 相似文献
5.
Rosalba Leuci Leonardo Brunetti Antonio Laghezza Luca Piemontese Antonio Carrieri Leonardo Pisani Paolo Tortorella Marco Catto Fulvio Loiodice 《Molecules (Basel, Switzerland)》2022,27(3)
A new series of aryloxyacetic acids was prepared and tested as peroxisome proliferator-activated receptors (PPARs) agonists and fatty acid amide hydrolase (FAAH) inhibitors. Some compounds exhibited an interesting dual activity that has been recently proposed as a new potential therapeutic strategy for the treatment of Alzheimer’s disease (AD). AD is a multifactorial pathology, hence multi-target agents are currently one of the main lines of research for the therapy and prevention of this disease. Given that cholinesterases represent one of the most common targets of recent research, we decided to also evaluate the effects of our compounds on the inhibition of these specific enzymes. Interestingly, two of these compounds, (S)-5 and 6, showed moderate activity against acetylcholinesterase (AChE) and even some activity, although at high concentration, against Aβ peptide aggregation, thus demonstrating, in agreement with the preliminary dockings carried out on the different targets, the feasibility of a simultaneous multi-target activity towards PPARs, FAAH, and AChE. As far as we know, these are the first examples of molecules endowed with this pharmacological profile that might represent a promising line of research for the identification of novel candidates for the treatment of AD. 相似文献
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8.
Juarez R Zavala-Oseguera C Jimenez-Halla JO Bickelhaupt FM Merino G 《Physical chemistry chemical physics : PCCP》2011,13(6):2222-2227
Quantum chemical calculations, using gradient-correct density functional at the BP86 level in conjunction with TZ2P basis sets, have been carried out for the radon hydrides HRnY (with Y = F, Cl, Br, I, CCH, CN, and NC). The bonding in HRnY is studied using different bond ruptures, establishing the role of those stabilizing (and destabilizing) factors that prevent these species to be dissociated. Although all HRnY systems studied here are bound equilibrium structures, they are metastable species with respect to the HRnY → Rn + HY decomposition channel. However, the HRnY → H + Rn + Y reaction is endothermic. So, these results indicate the possibility to identify the radon hydrides in noble-gas matrices. 相似文献
9.
Veronica Mugnaini Rosalba Liantonio Francesco Recupero Gian Franco Pedulli 《Tetrahedron letters》2006,47(19):3265-3269
Halogen-bonded complexes between aliphatic and aromatic iodoperfluorocarbons and persistent nitroxide radicals have been detected by ESR spectroscopy in solution. Quantitative data indicate that nitroxides behave as strong electron donors in halogen bonding, giving rise to interactions whose strength is close to that of strong hydrogen bonds. These results point to a novel design of supramolecular paramagnetic species. 相似文献
10.
Metrangolo P Präsang C Resnati G Liantonio R Whitwood AC Bruce DW 《Chemical communications (Cambridge, England)》2006,(31):3290-3292
New, halogen-bonded fluorinated mesogens are reported; the expected microphase separation associated with perfluoroalkyl chains is surprisingly absent in the mesophase. 相似文献