全文获取类型
收费全文 | 318篇 |
免费 | 9篇 |
国内免费 | 1篇 |
专业分类
化学 | 198篇 |
力学 | 2篇 |
数学 | 64篇 |
物理学 | 64篇 |
出版年
2023年 | 2篇 |
2022年 | 2篇 |
2021年 | 6篇 |
2020年 | 5篇 |
2019年 | 8篇 |
2018年 | 3篇 |
2016年 | 8篇 |
2015年 | 6篇 |
2014年 | 10篇 |
2013年 | 6篇 |
2012年 | 20篇 |
2011年 | 35篇 |
2010年 | 11篇 |
2009年 | 7篇 |
2008年 | 17篇 |
2007年 | 18篇 |
2006年 | 22篇 |
2005年 | 17篇 |
2004年 | 10篇 |
2003年 | 17篇 |
2002年 | 10篇 |
2001年 | 5篇 |
2000年 | 3篇 |
1999年 | 5篇 |
1997年 | 3篇 |
1996年 | 2篇 |
1995年 | 5篇 |
1994年 | 6篇 |
1991年 | 3篇 |
1990年 | 2篇 |
1985年 | 4篇 |
1984年 | 2篇 |
1981年 | 3篇 |
1979年 | 2篇 |
1978年 | 3篇 |
1973年 | 2篇 |
1972年 | 2篇 |
1955年 | 2篇 |
1947年 | 1篇 |
1940年 | 1篇 |
1939年 | 1篇 |
1936年 | 2篇 |
1934年 | 1篇 |
1933年 | 2篇 |
1929年 | 1篇 |
1927年 | 1篇 |
1925年 | 2篇 |
1924年 | 2篇 |
1923年 | 1篇 |
1922年 | 1篇 |
排序方式: 共有328条查询结果,搜索用时 15 毫秒
1.
D. Abbaneo P. Antilogus T. Behnke S.C. Blyth M. Elsing R. Faccini R.W.L. Jones K. Mönig S. Petzold R. Tenchini 《The European Physical Journal C - Particles and Fields》1998,4(2):185-191
Measurements of the forward-backward production asymmetry of heavy quarks in Z decays provide a precise determination of
. The asymmetries are sensitive to QCD effects, in particular hard gluon radiation. In this paper QCD corrections for and are discussed. The interplay between the experimental techniques used to measure the asymmetries and the QCD effects is
investigated using simulated events. A procedure to estimate the correction needed for experimental measurements is proposed,
and some specific examples are given.
Received: 26 February 1998 / Published online: 2 June 1998 相似文献
2.
3.
Witte PT Chowdhury SR ten Elshof JE Sloboda-Rozner D Neumann R Alsters PL 《Chemical communications (Cambridge, England)》2005,(9):1206-1208
A "sandwich" type polyoxometalate catalyst ([MeN(n-C8H17)3]12[WZn3(ZnW9O34)2]) was very efficiently recycled by nanofiltration with almost quantitative retention, using an alpha-alumina supported mesoporous gamma-alumina membrane. 相似文献
4.
Majumdar A Behnke JF Hippler R Matyash K Schneider R 《The journal of physical chemistry. A》2005,109(41):9371-9377
Chemical reactions in a dielectric barrier discharge at medium pressure of 250-300 mbar have been studied in CH(4)/Ar and CH(4)/N(2) gas mixtures by means of mass spectrometry. The main reaction scheme is production of H(2) by fragmentation of CH(4), but also production of higher order hydrocarbon molecules such as C(n)H(m) with n up to 9 including formation of different functional CN groups is observed. Formation of C(2)H(2), C(2)H(4), and C(2)H(6) molecules has been investigated in some detail. Significant differences are noted in comparison to a theoretical estimate. 相似文献
5.
Ag and Ru nanoparticles stabilized by H5PV2Mo10O40, prepared by a sequence of redox reactions and supported on alpha-alumina, were effective catalysts for the direct aerobic epoxidation of alkenes in the liquid phase. 相似文献
6.
Adam W Alsters PL Neumann R Saha-Möller CR Seebach D Beck AK Zhang R 《The Journal of organic chemistry》2003,68(21):8222-8231
The epoxidation of allylic alcohols is shown to be efficiently and selectively catalyzed by the oxidatively resistant sandwich-type polyoxometalates, POMs, namely [WZnM(2)(ZnW(9)O(34))(2)](q)(-) [M = OV(IV), Mn(II), Ru(III), Fe(III), Pd(II), Pt(II), Zn(II); q = 10-12], with organic hydroperoxides as oxygen source. Conspicuous is the fact that the nature of the transition metal M in the central ring of polyoxometalate affects significantly the reactivity, chemoselectivity, regioselectivity, and stereoselectivity of the allylic alcohol epoxidation. For the first time, it is demonstrated that the oxovanadium(IV)-substituted POM, namely [ZnW(VO)(2)(ZnW(9)O(34))(2)](12-), is a highly chemoselective, regioselective, and also stereoselective catalyst for the clean epoxidation of allylic alcohols. A high enantioselectivity (er values up to 95:5) has been achieved with [ZnW(VO)(2)(ZnW(9)O(34))(2)](12)(-) and the sterically demanding TADOOL-derived hydroperoxide TADOOH as regenerative chiral oxygen source. Thus, a POM-catalyzed asymmetric epoxidation of excellent catalytic efficiency (up to 42 000 TON) has been made available for the development of sustainable oxidation processes. The high reactivity and selectivity of this unprecedented oxygen-transfer process are mechanistically rationalized in terms of a peroxy-type vanadium(V) template. 相似文献
7.
Iodination of arenes was carried out by reacting 1 equiv of arene substrate with 0.5 equiv of iodine under an oxygen atmosphere with H5PV2Mo10O40 as oxidation catalyst. The synthesis is an inherently waste-free method for the preparation of iodoarenes. 相似文献
8.
We have demonstrated that a bipyrimidinylplatinum-polyoxometalate, [Pt(Mebipym)Cl2]+[H4PV2Mo10O40]-, supported on silica is an active catalyst for the aerobic oxidation of methane to methanol in water under mild reaction conditions. Further oxidation of methanol yields acetaldehyde. The presence of the polyoxometalate is presumed to allow the facile oxidation of a Pt(II) intermediate to a Pt(IV) intermediate and to aid in the addition of methane to the Pt catalytic center. 相似文献
9.
A phenanthroline ligand has been covalently modified at the 2 and 9 positions by an aminophenylhexamolybdate substituent. The 1H NMR spectrum indicated a strong electron-withdrawing effect of the hexamolybdate (Mo6O19(2-)) moiety on the phenanthroline ligand. UV-vis and cyclic voltammetry showed extended conjugation of the hybrid phenanthroline-polyoxometalate compound and the possibility of easy oxidation of the extended phenanathroline ligand. Further EPR experiments provided strong evidence for an intramolecular charge-transfer process with the formation of a phenanthroline cation radical and a reduced hexamolybdate. 相似文献
10.
Palladium 15-20 nm particles stabilized by a Keggin-type polyoxometalate were prepared by reduction of K(5)PPdW(11)O(39) with H(2). The nanoparticles were shown to be effective catalysts for Suzuki-, Heck-, and Stille-type carbon-carbon coupling and carbon-nitrogen coupling reactions of bromoarenes in aqueous media. Chloroarenes were also reactive in reaction media without solvent. [reaction: see text] 相似文献