Sc0.43(2)Rb2Mo15S19, a partially Sc‐filled variant of Rb2Mo15S19

The structure of scandium dirubidium pentadecamolybdenum nonadecasulfide, Sc_{0.43 (2)}Rb₂Mo₁₅S₁₉, constitutes a partially Sc‐filled variant of Rb₂Mo₁₅S₁₉ [Picard, Saillard, Gougeon, Noel & Potel (2000), J. Solid State Chem. 155 , 417–426]. In the two compounds, which both crystallize in the Rc space group, the structural motif is characterized by a mixture of Mo₆Sⁱ₈S^a₆ and Mo₉Sⁱ₁₁S^a₆ cluster units (`i' is inner and `a' is apical) in a 1:1 ratio. The two components are interconnected through interunit Mo—S bonds. The cluster units are centred at Wyckoff positions 6b and 6a (point‐group symmetries and 32, respectively). The Rb⁺ cations occupy large voids between the different cluster units. The Rb and the two inner S atoms lie on sites with 3. symmetry (Wyckoff site 12c), and the Mo and S atoms of the median plane of the Mo₉S₁₁S₆ cluster unit lie on sites with .2 symmetry (Wyckoff site 18e). A unique feature of the structure is a partially filled octahedral Sc site with symmetry. Extended Hückel tight‐binding calculations provide an understanding of the variation in the Mo—Mo distances within the Mo clusters induced by the increase in the cationic charge transfer due to the insertion of Sc.     

Bénard–Marangoni convection in a small circular container: influence of the Biot and Prandtl numbers on pattern dynamics and free surface deformation

We studied, experimentally, the pattern dynamics and free surface deformation in Bénard–Marangoni convection, in a circular container (aspect ratio = 6). The free surface deformation fields were visualized by interferometry and temperature fields by infrared thermography. We considered the influence of the Marangoni (up to 2,623), Biot and Prandtl numbers. More dynamics are induced by increasing the Biot number and transition to a time-dependent flow has been observed. Conversely, increasing the Prandtl number reduces the dynamics. The deformation increases as a function of the Marangoni number until it reaches asymptotic values, which are functions of the Biot and Prandtl numbers.     

Angular distributions in the dimuon hadronic production at 150 GeV/c

From π^- interactions at 150 GeV/c on a heavy target, we present the final analysis of the dimuon decay angular distribution in the mass interval 4.5–8.5 GeV/c². Results are presented and discussed in various reference frames and are also given in terms of the density matrix elements. Finally the possible contribution of higher-twist effects at largex ₁ is discussed; we find that our data are not compatible with higher twist contributions as proposed by the Berger and Brodsky Model.     

Liouville Results for <Emphasis Type="Italic">m</Emphasis>-Laplace Equations in Half-Space and Strips with Mixed Boundary Value Conditions and Finite Morse Index

We consider sign-changing solutions of the equation \(-\Delta _m u= |u|^{p-1}u\) where \(m\ge 2\) and \(p>1\) in half-space and strips with nonlinear mixed boundary value conditions. We prove Liouville type theorems for stable solutions or for solutions which are stable outside a compact set. The main methods used are the integral estimates, the Pohozaev-type identity and the monotonicity formula.     

A comparative study on structural and optical properties of ZnO and Al-doped ZnO thin films obtained by ultrasonic spray method using different solvents

Transparent conducting ZnO and Al doped ZnO thin films were deposited on glass substrate by ultrasonic spray method. The thin films with concentration of 0.1 M were deposited at 350 °C with 2 min of deposition time. The effects of ethanol and methanol solution before and after doping on the structural, optical and electrical properties were examined. The DRX analyses indicated that ZnO films have nanocrystalline nature and hexagonal wurtzite structure with (1 0 0) and (0 0 2) preferential orientation corresponding to ZnO films resulting from methanol and ethanol solution, respectively. The crystallinity of the thin films improved with methanol solution after doping to (0 0 2) oriented. All films exhibit an average optical transparency about 90%, in the visible range. The band gaps values of ZnO thin films are increased after doping from 3.10 to 3.26 eV and 3.27 to 3.30 eV upon Al doping obtained by ethanol and methanol solution, respectively. The electrical conductivity increase from 7.5 to 15.2 (Ω cm)⁻¹ of undoped to Al doped ZnO thin films prepared by using ethanol solution. However, for the methanol solution; the electrical conductivity of the film is stabilized after doping.     

Study of a circuit-breaker arc with self-generated flow. I. Energytransfer in the high-current phase

This study deals with the first phase of operation, corresponding to the energy transfer between arc and gas and to the pressure rise. The experimental study is devoted to measurements of current, arc voltage, and pressure variations in N₂ and SF₆. For currents of the order of 10 kA the mean measured electric field was about 32 V/cm in SF₆ and 36 V/cm in N₂. Through a bibliographical study and a modeling approach of the interruption arc, an analysis of the role of the different mechanisms of energy transfer between the arc and SF₆ was conducted. With a 10 kA pulse, about 80% of the transfer is found to be due to convection and the rest to radiation from the arc. This transfer results in an overpressure of nearly 1 bar in SF₆ and 2 bar in N₂. It appears that the operation of this type of circuit breaker is limited to high currents: for currents below 7 kA the overpressure is lower than 0.5 bar, which does not provide efficient blowing at current zero     

ChemInform Abstract: Sc0.43(2)Rb2Mo15S19, a Partially Sc‐Filled Variant of Rb2Mo15S19.

Single crystals of the title compound are obtained from a mixture of Sc₂S₃, Rb₂MoS₄, MoS₂, and Mo (Mo crucible, 1773 K, 48 h).