Iron(II) Spin‐Crossover Complexes in Ultrathin Films: Electronic Structure and Spin‐State Switching by Visible and Vacuum‐UV Light

The electronic structure of the iron(II) spin crossover complex [Fe(H₂bpz)₂(phen)] deposited as an ultrathin film on Au(111) is determined by means of UV‐photoelectron spectroscopy (UPS) in the high‐spin and in the low‐spin state. This also allows monitoring the thermal as well as photoinduced spin transition in this system. Moreover, the complex is excited to the metastable high‐spin state by irradiation with vacuum‐UV light. Relaxation rates after photoexcitation are determined as a function of temperature. They exhibit a transition from thermally activated to tunneling behavior and are two orders of magnitude higher than in the bulk material.     

Q-Curves and Abelian Varieties of GL2-Type

The relation between Q-curves and certain abelian varietiesof GL₂-type was established by Ribet (‘Abelian varietiesover Q and modular forms’, Proceedings of the KAIST MathematicsWorkshop (1992) 53–79) and generalized to building blocks,the higher-dimensional analogues of Q-curves, by Pyle in herPhD Thesis (University of California at Berkeley, 1995). Inthis paper we investigate some aspects of Q-curves with no complexmultiplication and the corresponding abelian varieties of GL₂-type,for which we mainly use the ideas and techniques introducedby Ribet (op. cit. and ‘Fields of definition of abelianvarieties with real multiplication’, Contemp.\ Math. 174(1994) 107–118). After the Introduction, in Sections 2and 3 we obtain a characterization of the fields where a Q-curveand all the isogenies between its Galois conjugates can be definedup to isogeny, and we apply it to certain fields of type (2,...,2).In Section 4 we determine the endomorphism algebras of all theabelian varieties of GL₂-type having as a quotient a given Q-curvein easily computable terms. Section 5 is devoted to a particularcase of Weil's restriction of scalars functor applied to a Q-curve,in which the resulting abelian variety factors over Q up toisogeny as a product of abelian varieties of GL₂-type. Finally,Section 6 contains examples: we parametrize the Q-curves comingfrom rational points of the modular curves X*N having genuszero, and we apply the results of Sections 2–5 to someof the curves obtained. We also give results concerning theexistence of quadratic Q-curves. 1991 Mathematics Subject Classification:primary 11G05; secondary 11G10, 11G18, 11F11, 14K02.     

Curves of genus 2 with group of automorphisms isomorphic to or

The classification of curves of genus 2 over an algebraically closed field was studied by Clebsch and Bolza using invariants of binary sextic forms, and completed by Igusa with the computation of the corresponding three-dimensional moduli variety . The locus of curves with group of automorphisms isomorphic to one of the dihedral groups or is a one-dimensional subvariety.

In this paper we classify these curves over an arbitrary perfect field of characteristic in the case and in the case. We first parameterize the -isomorphism classes of curves defined over by the -rational points of a quasi-affine one-dimensional subvariety of ; then, for every curve representing a point in that variety we compute all of its -twists, which is equivalent to the computation of the cohomology set .

The classification is always performed by explicitly describing the objects involved: the curves are given by hyperelliptic models and their groups of automorphisms represented as subgroups of . In particular, we give two generic hyperelliptic equations, depending on several parameters of , that by specialization produce all curves in every -isomorphism class.