全文获取类型
收费全文 | 19948篇 |
免费 | 3120篇 |
国内免费 | 3147篇 |
专业分类
化学 | 15268篇 |
晶体学 | 262篇 |
力学 | 1167篇 |
综合类 | 253篇 |
数学 | 2425篇 |
物理学 | 6840篇 |
出版年
2024年 | 68篇 |
2023年 | 288篇 |
2022年 | 568篇 |
2021年 | 634篇 |
2020年 | 731篇 |
2019年 | 725篇 |
2018年 | 687篇 |
2017年 | 612篇 |
2016年 | 901篇 |
2015年 | 956篇 |
2014年 | 1225篇 |
2013年 | 1453篇 |
2012年 | 1668篇 |
2011年 | 1839篇 |
2010年 | 1400篇 |
2009年 | 1392篇 |
2008年 | 1539篇 |
2007年 | 1317篇 |
2006年 | 1214篇 |
2005年 | 990篇 |
2004年 | 841篇 |
2003年 | 682篇 |
2002年 | 787篇 |
2001年 | 647篇 |
2000年 | 562篇 |
1999年 | 446篇 |
1998年 | 306篇 |
1997年 | 237篇 |
1996年 | 280篇 |
1995年 | 239篇 |
1994年 | 143篇 |
1993年 | 144篇 |
1992年 | 118篇 |
1991年 | 114篇 |
1990年 | 92篇 |
1989年 | 78篇 |
1988年 | 53篇 |
1987年 | 52篇 |
1986年 | 43篇 |
1985年 | 29篇 |
1984年 | 21篇 |
1983年 | 23篇 |
1982年 | 16篇 |
1981年 | 12篇 |
1980年 | 6篇 |
1979年 | 5篇 |
1974年 | 4篇 |
1972年 | 4篇 |
1971年 | 4篇 |
1957年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Ji-Dong Lou Chun-Ling Gao Li Li Zhi-Gang Fang 《Monatshefte für Chemie / Chemical Monthly》2006,41(10):1071-1074
A new procedure for the selective oxidation of alcohols to the corresponding aldehydes and ketones with potassium permanganate
supported on aluminum silicate at room temperature under solvent-free conditions and shaking is reported. 相似文献
2.
3.
We reveal that for a realistic system, interference effects are obtained such as the suppression of central line and inner sidebands and the narrowing of the outer fluorescence sidebands. For this purpose, we consider a spontaneous decay from an excited state to a metastable state when the excited and metastable states are resonantly coupled to an auxiliary metastable state by a laser field and a microwave field, respectively. The fluorescence spectrum evolves from a five-peaked structure into a doublet of ultrasharp lines as the ratio of the laser field Rabi frequency to the microwave Rabi frequency is decreased. The physical origin is presented in terms of dressed states. 相似文献
4.
This paper undertakes a systematic treatment of the low regularity local wellposedness and ill-posedness theory in Hs andHs for semilinear wave equations with polynomial nonlinearity in u and (e)u. This ill-posed result concerns the focusing type equations with nonlinearity on u and (e)tu. 相似文献
5.
Existence, Multiplicity and Infinite Solvability of Positive Solutions for One-Dimensional p-Laplacian 总被引:5,自引:0,他引:5
Qing Liu YAO 《数学学报(英文版)》2005,21(4):691-698
The existence, multiplicity and infinite solvability of positive solutions are established for some two-point boundary value problems of one-dimensional p-Laplacian. In this paper, by multiplicity we mean the existence of m solutions, where m is an arbitrary natural number. 相似文献
6.
The first α‐diimine nickel(I) complex having a chloro bridge is reported. The centrosymmetric dinuclear structure of {[ArN?C(Me)C(Me)?NAr]NiCl}2[Ar?2,6?C6H3(i‐Pr)2] features two chelating α‐diimine ligands and two bridged chlorine atoms, so that a distorted tetrahedral N2Cl2 coordination geometry for nickel results. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
7.
A fluorous osmium catalyst was firstly developed. It had been effectively used as recoverable and reusable catalyst in the dihydroxylation of olefins. 相似文献
8.
A stochastic approximation algorithm for estimating multichannel coefficients is proposed, and the estimate is proved to converge to the true parameters a.s. up-to a constant scaling factor. The estimate is updated after receiving each new observation, so the output data need not be collected in advance. The input signal is allowed to be dependent and the observation is allowed to be corrupted by noise, but no noise statistics are used in the estimation algorithm. 相似文献
9.
Xin‐Gui Li Run‐Feng Chen Mei‐Rong Huang Mei‐Fang Zhu Qun Chen 《Journal of polymer science. Part A, Polymer chemistry》2004,42(9):2073-2092
A new series of copolymers was synthesized through the oxidative polymerization of pyrrole (PY) and o‐phenetidine (PHT) with inorganic oxidants in acidic media. The polymerization parameters including the mixing method of the oxidant with the comonomer, the comonomer ratio, the time, the temperature, the oxidant, the organic medium, and the acid were systematically optimized for the synthesis of copolymers with high yields, intrinsic viscosities, and solubility. The resultant copolymers were characterized by elemental analysis, infrared, ultraviolet–visible, solution high‐resolution 1H NMR and solid‐state high‐resolution 13C NMR, circular dichroism spectroscopy, and cyclic voltammetry. The results showed that the PY observed content in the copolymers was much higher than the PY feed content. The regular variation of the polymerization yield, intrinsic viscosity, solubility, macromolecular structure, and electroactivity of the resulting polymers with the comonomer ratio, together with the complete solubility of a PY/PHT (10/90) polymer in highly polar solvents, indicated the formation of real random copolymers containing both PY and PHT units rather than a mixture of two homopolymers. However, the polymers containing more than 59 mol % PY were not homogeneous copolymers consisting of soluble and insoluble parts. A semiquantitative relationship between the polymerization yield or solubility of the copolymers and the polarity index of the organic solvents was examined. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2073–2092, 2004 相似文献
10.
Fang‐Jung Huang Tzong‐Liu Wang 《Journal of polymer science. Part A, Polymer chemistry》2004,42(2):290-302
Liquid‐crystalline, segmented polyurethanes with methoxy–biphenyl mesogens pendant on the chain extender were synthesized by the conventional prepolymer technique and esterification reaction. Two, side‐chain, liquid‐crystalline (SCLC) polyurethanes with mesogens having spacers of six and eight methylene units were prepared. The structures of the mesogenic units and SCLC polyurethanes were confirmed by Fourier transform infrared spectroscopy and 1H NMR. Polymer properties were also examined by solubility tests, water uptakes, and inherent viscosity measurements. Differential scanning calorimetry studies indicated that the transition temperature of the isotropic to the liquid‐crystalline phase decreased with increasing spacer length. Wide‐angle X‐ray diffraction (WAXD) studies revealed the existence of liquid‐crystalline phases for both SCLC polyurethanes. Polarized optical microscopic investigations further confirmed the thermotropic liquid‐crystalline behaviors and nematic mesophases of both samples. Thermogravimetric analysis displayed better thermal stabilities for both SCLC polymers and indicated that the presence of mesogenic side chains may increase the thermal stability of segmented polyurethanes. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 290–302, 2004 相似文献