全文获取类型
收费全文 | 134篇 |
免费 | 3篇 |
专业分类
化学 | 110篇 |
数学 | 20篇 |
物理学 | 7篇 |
出版年
2021年 | 2篇 |
2019年 | 2篇 |
2018年 | 2篇 |
2014年 | 1篇 |
2013年 | 8篇 |
2012年 | 2篇 |
2011年 | 6篇 |
2010年 | 1篇 |
2009年 | 2篇 |
2008年 | 4篇 |
2007年 | 6篇 |
2006年 | 1篇 |
2005年 | 2篇 |
2004年 | 4篇 |
2003年 | 7篇 |
2002年 | 6篇 |
2001年 | 4篇 |
2000年 | 2篇 |
1997年 | 1篇 |
1996年 | 2篇 |
1995年 | 1篇 |
1994年 | 2篇 |
1990年 | 2篇 |
1988年 | 1篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1985年 | 3篇 |
1984年 | 7篇 |
1983年 | 2篇 |
1981年 | 6篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1978年 | 10篇 |
1977年 | 4篇 |
1976年 | 3篇 |
1975年 | 3篇 |
1974年 | 2篇 |
1973年 | 2篇 |
1969年 | 1篇 |
1967年 | 1篇 |
1961年 | 1篇 |
1960年 | 1篇 |
1954年 | 1篇 |
1930年 | 1篇 |
1909年 | 2篇 |
1904年 | 2篇 |
1903年 | 2篇 |
1895年 | 1篇 |
1888年 | 1篇 |
1887年 | 2篇 |
排序方式: 共有137条查询结果,搜索用时 93 毫秒
1.
2.
We examine the resource allocation problem of partitioning identical servers into two parallel pooling centers, and simultaneously
assigning job types to pooling centers. Each job type has a distinct Poisson arrival rate and a distinct holding cost per
unit time. Each pooling center becomes a queueing system with an exponential service time distribution. The goal is to minimize
the total holding cost. The problem is shown to be polynomial if a job type can be divided between the pooling centers, and
NP-hard if dividing job types is not possible. When there are two servers and jobs cannot be divided, we demonstrate that
the two pooling center configuration is rarely optimal. A heuristic which checks the single pooling center has an upper bound
on the relative error of 4/3. The heuristic is extended for the multiple server problem, where relative error is bounded above
by the number of servers.
相似文献
3.
Gary H. Posner Timothy P. Kogan Stephen R. Haines Leah L. Frye 《Tetrahedron letters》1984,25(25):2627-2630
A short, reliable, and practical synthesis of ()-(+)-2-(-tolylsulfinyl)-2-buten-4-olide has been developed, and the utility of this Michael acceptor for highly enantiocontrolled synthesis of 3-substituted 4-butanolides has been demonstrated. 相似文献
4.
Geraldine S.P. Ritchie Alan M. Posner Ian M. Ritchie 《Journal of Electroanalytical Chemistry》1981,123(2):397-407
Variation of the lifetime of a mercury drop with potential was used to determine the pzc of mercury in the presence of soil humic acids and their aluminium complexes. In all cases there was an overall net shift in the pzc in the cathodic direction. Variation in the extent of the shift with pH and concentration indicated greater adsorption of negatively charged species. The shift was smaller in the presence of aluminium humates, probably due to a decrease in the negative charge of the humic acid molecules after complexing. The use of electroanalytical techniques for metal speciation studies in soils and natural water, if humic materials are known to be present, might therefore be limited. 相似文献
5.
The 29Si and 14N nmr spectra of some bissilylamides and monosilylamides are reported. The results are compared with those for model silylesters, amines and imines. The compound of formula CF3CONCH3Si(CH3)3 (MSTFA) is shown to exist as a tautemeric mixture of a silylamide and a silylimidate. This assignment is confirmed by 13C nmr. A rationale is proposed for the structure directing effect of substituents on the amide carbon atom. 相似文献
6.
Yael Diskin‐Posner Goutam Kumar Patra Israel Goldberg 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(6):m344-m346
The title compound, [5,10,15,20‐meso‐tetrakis(4‐hydroxyphenyl)porphyrinato‐κ4N]zinc(II) tris(dibenzo‐24‐crown‐8) methanol tetrasolvate, [Zn(C44H28N4O4)]·3C24H32O8·4CH4O, was synthesized and its molecular structure precisely characterized by low‐temperature single‐crystal analysis. All the components are involved in hydrogen bonding with each other, thus forming an extensively hydrogen‐bonded supramolecular lattice. The functionalized porphyrin moiety coordinates both equatorially and axially to the neighboring species. 相似文献
7.
The double bond of cholesteryl and 5-norbornen-2-yl tosylates and the cyclopropane ring of cyclopropylmethylcarbinyl tosylate participate in organocuprate substitution reactions; retention of configuration at the nucleofugal sp3-C atom and skeletal reorganizations are observed. A plausible mechanism for these reactions is discussed. Coupling of homogeranyl iodide with a four-carbon, functionalized, vinylic cuprate reagent is applied to stereospecific synthesis of trans, trans-farnesol. 相似文献
8.
A series of potentiometric titrations was carried out on alumina coated rutile pigments. The point of intersection of the adsorption isotherms obtained at three ionic strengths was independent of the titration speed, hence these experiments are considered to give a reliable estimate of the i. e. p. of the sample. The adsorption isotherms are, however, irreversible and the uptake of protons and hydroxyl ions is dependent upon titration speed. The irreversibility of the isotherms appears to be related to the slow drift in the pH of the pigment suspension that takes place during the titration. This pH drift is due to 1) a partial dissolution of the alumina coating and 2) a slow movement of protons into and out of the coating on the pigment. 相似文献
9.
10.
Dr. Ori Gidron Dr. Yael Diskin‐Posner Prof. Michael Bendikov 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(39):13140-13150
The extent of charge delocalization and of conjugation in oligofurans and oligothiophenes was studied by using mixed valence systems comprising oligofurans and oligothiophenes capped at both ends by ferrocenyl redox units. Using electrochemical, spectral, and computational tools, we find strong charge delocalization in ferrocene‐capped oligofurans which was stronger than in the corresponding oligothiophene systems. Spectroscopic studies suggest that the electronic coupling integral (Hab) is roughly 30–50 % greater for oligofuran‐bridged systems, indicating better energy matching between ferrocene units and oligofurans. The distance decay constant (damping factor), β, is similar for oligofurans (0.066 A?1) and oligothiophenes (0.070 A?1), which suggests a similar extent of delocalization in the bridge, despite the higher HOMO–LUMO gap in oligofurans. Computational studies indicate a slightly larger extent of delocalization in furan‐bridged systems compared with thiophene‐bridged systems, which is consistent with oligofurans being significantly more rigid and less aromatic than oligothiophenes. High charge delocalization in oligofurans, combined with the previously reported strong fluorescence, high mobility, and high rigidity of oligofuran‐based materials makes them attractive candidates for organic electronic applications. 相似文献