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1.
Analysis of a second-approximation refined shear model for shallow layered composite shells and plates with a substantially inhomogeneous structure over the thickness is presented. The tangential displacements and corresponding normal stresses are expressed in the form of a polynomial of the fith degree in the transverse coordinate and contain squared rigidity characteristics. In this way, the accuracy of results and practical coincidence with the 3D solutions is ensured. Based on the refined model, a theory of shallow layered shells is developed. A system of resolving equations of sixteenth power together with appropriate boundary conditions was obtained and solved analytically. It is shown that the area of application of the formed model is extended as compared with the model of the first approximation. The model proposed allows us to examine the stress-strain state of layered composite structures of substantially different thickness and physical-mechanical characteristics of the layers, including the possibility of simulating relatively large shear deformations of rigid layers separated by a low-modulus thin interlayer pliable to transverse shear.Presented at the 10th International Conference on the Mechanics of Composite Materials (Riga, April 20–23, 1998).Ukrainian Transport University, Kiev, Ukraine. Translated from Mekhanika Kompozitnykh Materialov, Vol. 34, No. 3, pp. 363–370, May–June, 1998. 相似文献
2.
V. A. Bogatyrev V. A. Piskunov S. Yu. Shchegolev N. M. Ptichkina 《Colloid Journal》2001,63(3):270-274
Method for determining temperature of the transition of biopolymer systems to gellike state was developed using the earlier discovered effect of decaying amplitude of spontaneous fluctuations of system optical density, which significantly exceed the level of intrinsic noise of measuring devices of Specord M40 and Specord M400 spectrophotometers. These fluctuations are caused by the thermal convection resulting in the emergence of randomly distributed regions with different optical properties in the analyzed systems. The inhomogeneity can by amplified by the fraction of supermolecular particles (SMP). The effect of convection markedly decreases as a result of the loss of fluidity during the system gelation, thus underlying the instrumental registration of the sol–gel transition whose efficiency was confirmed in this work using aqueous preparations of plant polysaccharides (pectin, agar, furcellaran, and -carrageenan). It was shown that, in the cases of initially optically homogeneous systems, the role of the SMPs can be played (if necessary) by the relatively small amounts of the particles of chemically inert compounds (for example, cellulose) at slight mixing of a system using magnetic stirrer. This method was applied for constructing the fragment of the phase diagram of the furcellaran–water system during its cooling. The interpretation of its semi-logarithmic transformation in terms of the Eldridge–Ferry theory resulted in the estimation of the amount of heat evolved during the formation of gel network junctions (presumably, due to the pair associations of double helixes), which appeared to be equal to –63 kJ mol–1. 相似文献
3.
Piskunov A. V. Maslennikov S. V. Cherkasov V. K. Spirina I. V. Maslennikov V. P. 《Russian Journal of General Chemistry》2002,72(6):933-938
Kinetic regularities of zinc and cadmium oxidation in systems comprising 3,5-di-tert-butyl-1,2-benzoquinone and dimethylformamide or dimethyl sulfoxide are studied. Thermodynamic parameters of oxidant and ligand adsorption on metal surface are estimated. The oxidation of Group II metals (Be, Ca, Mg, Zn, Cd) with 3,5-di-tert-butyl-1,2-benzoquinone gives metal bis-o-semiquinolates. In the presence of excess metal in the medium of coordinating solvents, diradical products convert to the corresponding catecholate derivatives. It is shown that the dependence of the rates of metal reactions with 3,5-di-tert-butyl-1,2-benzoquinone on the donor number of solvent passes through a maximum. With less active metals, the maximum shifts to more basic ligands. 相似文献
4.
A. V. Piskunov A. V. Lado G. A. Abakumov V. K. Cherkasov O. V. Kuznetsova G. K. Fukin E. V. Baranov 《Russian Chemical Bulletin》2007,56(1):97-103
Oxidation of amalgamated magnesium metal with 3,6-di-tert-butyl-o-benzoquinone (1) in different aprotic organic solvents afforded magnesium catecholate and bis-o-semiquinolate complexes. The catecholate derivatives of magnesium CatMgL2 (Cat is the 3,6-di-tert-butyl-o-benzoquinone dianion, L = THF or Py) were synthesized in high yields in pyridine and tetrahydrofuran, respectively. The reactions
in diethyl ether or dimethoxyethane produced hexacoordinated metal bis-o-semiquinolates SQ2MgLn (SQ is the 3,6-di-tert-butyl-o-benzoquinone radical anion, L = Et2O, n = 2; L = DME, n = 1). The reaction with the use of toluene as the solvent gave a magnesium bis-o-semiquinolate complex containing the coordinated unreduced o-quinone molecule. The molecular structures of the [CatMgPy2]2 and SQ2Mg·DME complexes were established by X-ray diffraction.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 92–98, January, 2007. 相似文献
5.
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7.
A. V. Piskunov I. N. Meshcheryakova G. K. Fukin I. V. Smolyaninov N. M. Khamaletdinova O. V. Kuznetsova 《Russian Journal of Coordination Chemistry》2014,40(4):205-215
A series of new tin(IV) complexes based on 2-hydroxy-3,6-di-tert-butyl-para-benzoquinone (LH) of the general formula L2SnR2 (R = Me (I), Et (II), Bu n (III), Ph (IV)) and LSnMe3 (V) were synthesized. The obtained compounds were characterized by IR and 1H, 13C and 119Sn NMR spectroscopy and elemental analysis. The X-ray diffraction analysis was carried out for complexes L2Sn(Bu n )2 (III) and LSnMe3 (V). The low-frequency region of the IR spectra, which has not earlier been studied in detail, was interpreted for compounds I–V and previously described complex LSnPh3 (VI). The electrochemical properties of LH and related tin complexes I–VI were studied. The nature of the hydrocarbon groups at the metal atom affects the stability of the intermediates formed in the electrochemical reactions. 相似文献
8.
The paper shows that many simple rating functions constructed on the basis of the ratio analysis distort significantly the
evaluation of the production units behavior. Opposite to the ratio analysis, the DEA approach investigate production units
behaviour in the multidimentional space of indicators. In this paper, we compare the ration analysis and the DEA approach
using properties of the mappings of the multidimentional sets, we also show that it is purposeful to construct rating functions
on the basis of efficiency scores computed in DEA models.
Published in Russian in Doklady Akademii Nauk, 2009, Vol. 426, No. 5, pp. 608–612.
Presented by Academician S.K. Korovin February 1, 2009
The article was translated by the authors. 相似文献
9.
A. G. Smol’nikov V. V. Ogloblichev S. V. Verkhovskii K. N. Mikhalev A. Yu. Yakubovskii K. Kumagai Y. Furukawa A. F. Sadykov Yu. V. Piskunov A. P. Gerashchenko S. N. Barilo S. V. Shiryaev 《JETP Letters》2015,102(10):674-677
The magnetically ordered phase of the CuCrO2 single crystal has been studied by the nuclear magnetic resonance (NMR) method on 53Cr nuclei in the absence of an external magnetic field. The 53Cr NMR spectrum is observed in the frequency range νres = 61–66 MHz. The shape of the spectrum depends on the delay tdel between pulses in the pulse sequence τπ/2–t del–τπ–t del–echo. The spin–spin and spin–lattice relaxation times have been measured. Components of the electric field gradient, hyperfine fields, and the magnetic moment on chromium atoms have been estimated. 相似文献