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Aqueous polymerization of acrylonitrile (M) initiated by the Ce(IV)-glucose (R) redox system has been studied under nitrogen in the temperature range of 30–40 °C. The rate of polymerization (Rp) is proportional to [M]2, [R] and inversely proportional to [Ce(IV)]. The rate of ceric ion disappearance is proportional to [R] and [Ce(IV)]. The end group in the polymer is characterised by IR spectra. A suitable kinetic scheme has been proposed and explained in the light of these experimental findings. 相似文献
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R. C. Padhi H. Labischinski A. Patel 《Journal of polymer science. Part A, Polymer chemistry》1983,21(10):2863-2872
The small-angle, x-ray scattering method was applied to evaluate macromolecular parameters of defated proteinous silk fibers like Eri, Muga, Tussah, and raw silk. For the experimental measurement of scattering intensities the small-angle Kratky camera, coupled with an automatic-step scanning device, pulse-height discriminator, and counter attachment was used. Macromolecular parameters like specific inner surface, percentage of void, length of coherence, range of inhomogeneity, and transversal length were evaluated by using the theories of Kratky, Porod and Debye, and Bueche. The physical properties of these defated fibers were also evaluated with Scott's IP2-inclined plane tester. The correlation of the tertiary structural parameters with textile properties like average breaking strength of the proteinous fibers indicated a dependence of physical properties on certain macromolecular parameters. 相似文献
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Quinoline‐based benzimidazole compounds have been successfully synthesized and characterized by various spectroscopic techniques like FT‐IR, 1H NMR, 13C NMR, and mass spectral analysis, and the structures have been authenticated by single crystal X‐ray diffraction method. Here, we report an economical, mild, and efficient procedure that involves condensation of 8‐hydroxyquinoline‐2‐carbaldehyde with various diamines as substrates to give bis‐imines. A systematic study towards both aliphatic and aromatic bis‐imines has been conducted to investigate the ring‐closure reaction that generates the benzimidazole moiety in the heterocyclic compounds discussed in this study. Aliphatic bis‐imines does not undergo cyclization; however, the bis‐imines derived from o‐phenylenediamine and derivatives generates heterocyclic compounds with benzimidazole moiety. In contrast to synthetic procedures reported earlier for benzimidazoles, the reaction conditions herein reported are simpler. Path for reactions holds initial condensation with one equivalent of 8‐hydroxyquinoline‐2‐carbaldehyde to form mono‐imine followed by immediate intramolecular ring closure. The subsequent nupleophilic attack to another equivalent of 8‐hydroxyquinoline‐2‐carbaldehyde and migration of hydride generates the benzimidazole moiety and the active methylene group. The ─CH2 group was confirmed from 1H and 13C NMR, wherein the two hydrogens appeared at around 6.40–6.52 ppm and the carbon center appeared at 51.54–51.77 ppm. The single crystal X‐ray diffraction also confirmed the formation of benzimidazole moiety and the active methylene group in the heterocyclic compounds discussed in this study. 相似文献
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Arjunic acid and arjunolic acid are main bioactive components of Terminalia arjuna stem bark and reported for various biological activities. In this study, microwave-assisted extraction (MAE) of arjunic and arjunolic acid from stem bark of T. arjuna was investigated with developed and validated HPLC-PDA method, which resulted in the isolation of a novel anticancer molecule i.e. arjunic acid. Effects of several experimental parameters, such as type and volume of extraction solvents, microwave power, microwave extraction time, on the extraction efficiencies of arjunic, and arjunolic acid from stem bark of T. arjuna were evaluated. The optimal extraction conditions identified were 5.0 g quantity of stem bark powder, 20 mL of ethyl acetate, preleaching time 10 min, microwave power 600 W, temperature 65°C, and microwave irradiation time 5 min. The results showed that MAE is a more rapid extraction method with higher yield and lower solvent consumptions than reported methods. The HPLC-PDA analysis method was developed and validated to have good linearity, precision, sensitivity, and accuracy. MAE-HPLC-PDA is a faster, convenient, and appropriate method for isolation and determination of arjunic acid and arjunolic acid in the stem bark of T. arjuna. 相似文献
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Mathavaraj S. Padhi Radhakant 《Journal of Optimization Theory and Applications》2021,191(2-3):823-845
Journal of Optimization Theory and Applications - A new quasi-spectral version of unscented model predictive static programming is proposed, which is a fusion of two philosophies, namely the... 相似文献
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In this paper we have proved a theorem for infinite triangular matrix using new techniques. 相似文献
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S.P. Baranov H. Jung L. Jönsson S. Padhi N.P. Zotov 《The European Physical Journal C - Particles and Fields》2002,24(3):425-437
In the framework of the semi-hard (-factorization) approach, we analyze the various charm production processes in the kinematic region covered by the HERA experiments.
Received: 4 March 2002 / Published online: 7 June 2002 相似文献
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S. K. Bhattacherjee S. K. Mitra H. C. Jain H. C. Padhi K. S. Bhatki D. C. Ephraim 《Nuclear Physics A》1967,90(3):696-704
The spin of the odd nucleus
has been determined to be I = 3 from the beta circularly-polarized gamma correlation studies on two prominent beta-gamma cascades: (i) the 1.19 MeV beta group (966 and 908) keV gamma rays and (ii) the 1.76 MeV beta group- 3.38 keV gamma ray. The matrix element ratio X for the 1.76 MeV beta transition has been determined to be X = 0.40±0.10. 相似文献