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排序方式: 共有5348条查询结果,搜索用时 15 毫秒
1.
Laurens Kooijman Dr. Matthias Schuster Christian Baumann Simon Jurt Dr. Frank Löhr Dr. Boris Fürtig Prof. Dr. Peter Güntert Prof. Dr. Oliver Zerbe 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(47):21151-21158
To achieve efficient proton pumping in the light-driven proton pump bacteriorhodopsin (bR), the protein must be tightly coupled to the retinal to rapidly convert retinal isomerization into protein structural rearrangements. Methyl group dynamics of bR embedded in lipid nanodiscs were determined in the dark-adapted state, and were found to be mostly well ordered at the cytosolic side. Methyl groups in the M145A mutant of bR, which displays only 10 % residual proton pumping activity, are less well ordered, suggesting a link between side-chain dynamics on the cytosolic side of the bR cavity and proton pumping activity. In addition, slow conformational exchange, attributed to low frequency motions of aromatic rings, was indirectly observed for residues on the extracellular side of the bR cavity. This may be related to reorganization of the water network. These observations provide a detailed picture of previously undescribed equilibrium dynamics on different time scales for ground-state bR. 相似文献
2.
3.
Lance Nielsen 《Acta Appl Math》2002,74(3):265-292
Stability properties of Feynman's operational calculus are addressed in the setting of exponential functions of noncommuting operators. Applications of some of the stability results are presented. In particular, the time-dependent perturbation theory of nonrelativistic quantum mechanics is presented in the setting of the operational calculus and application of the stability results of this paper to the perturbation theory are discussed. 相似文献
4.
We use the adiabatic hyperspheric expansion and the Faddeev decomposition of the wave function with only s-waves. We derive for a fixed hyperradius an integro-differential equation for the angular eigenvalue and wave function. The
correlations lower the interaction energy for N = 20 by about a factor of 5.
Received October 22, 2001; accepted for publication November 5, 2001 相似文献
5.
Kristian Hougaard Frederik D. Nielsen 《Journal of Optical and Fiber Communications Reports》2004,1(1):63-83
In this paper we will present an overview of the use
of photonic crystal fibers as fiber amplifiers. We
will describe the basic concepts of optical
amplification, and how to do numerical modelling of
such components. We will then identify advantages
and disadvantages of amplifiers based on PCF
technology compared to conventional fibers, and then
go into greater detail on some of these specific
applications, such as low pump power amplifiers, and
high-power double-clad amplifiers and lasers. 相似文献
6.
The modification of the number field sieve which Joux and Lercier recently used to compute logarithms in a prime field of a record 120 decimal digits makes use of the notion of a virtual logarithm of a prime ideal in a number ring. We provide necessary and sufficient conditions for their method to succeed and give an explicit formula for the virtual logarithm of an ideal. 相似文献
7.
8.
Marcel Oliver 《Theoretical and Computational Fluid Dynamics》1997,9(3-4):311-324
The so-called lake equations arise as the shallow-water limit of the rigid-lid equations—three-dimensional Euler equations
with a rigid-lid upper boundary condition—in a horizontally periodic basin with bottom topography. We prove an a priori estimate in the Sobolev space H
m
for m≥ 3 which shows that a solution to the rigid-lid equations can be approximated by a solution of the lake equations for an
interval of time which can be estimated in terms of the initial deviation from a columnar configuration and the magnitude
of the initial data in H
m
, the gradient of the bottom topography in H
m+1
, and the aspect ratio of the basin. In particular, any solution to the lake equations remains close to some solution of the
rigid-lid equations for an interval of time that can be made arbitrarily large by choosing the aspect ratio of the basin small.
Received 10 October 1996 and accepted 15 May 1997 相似文献
9.
The consecutive reactions of (CH3)2Si(OC2H5)2 and CH3Si(OC2H5)3 with methoxide ions were investigated in methanol solutions. The reverse transesterification reactions with ethoxide ions could be neglected in both cases since the concentration of ethoxide in methanol solution was assumed to be low due to the fast equilibrium reaction C2H5O? + CH3OH ? C2H5OH + CH3O?. The progress of the reactions was followed by monitoring the formation of ethanol with a Fourier-transform infrared spectrometer. All rate constants were determined at 295 K. The reactions between the dialkoxydimethylsilanes and methoxide ions were assumed to consist of two consecutive steps that can be represented by the net reaction; (CH3)2Si(OC2H5)2 + 2CH3O? → (CH3)2Si(OCH3)2 + 2C2H5O?. The two consecutive rate constants were established as 1.93 ± 0.12M?1s?1 and 1.00 ± 0.12M?1s?1, respectively. The consecutive rate constants for the reactions between the trialkoxymethylsilanes and methoxide ions can be written according to the total reaction; CH3Si(OC2H5)3 + 3CH3O? → CH3Si(OCH3)3 + 3C2H5O?. The three rate constants corresponding to each consecutive step were established as 1.12 ± 0.09 M?1s?1, 0.82 ± 0.10 M?1s?1, and 0.51 ± 0.06 M?1s?1, respectively. © 1995 John Wiley & Sons, Inc. 相似文献
10.