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排序方式: 共有174条查询结果,搜索用时 15 毫秒
1.
Kurenkov V. F. Zaitseva O. A. Kirdyashova G. N. 《Russian Journal of Applied Chemistry》2002,75(4):641-644
The kinetics of radical copolymerization of acrylamide with lithium, sodium, and potassium 2-acrylamido-2-methylpropanesulfonates in concentrated aqueous solutions in the presence of potassium persulfate as initiating agent at pH 9 and 50°C was studied by dilatometry. 相似文献
2.
Kurenkov V. F. Zhelonkina T. A. Ryabysheva N. A. Lobanov F. I. 《Russian Journal of Applied Chemistry》2003,76(8):1310-1314
The influence of single- and double-charged cations on degradation of metal 2-acrylamido-2-methylpropanesulfonate-N-vinylpyrrolidine copolymers in aqueous solutions in the presence of potassium peroxodisulfate, K2S2O8, at 50 and 70°C was studied by viscosimetry. 相似文献
3.
Kurenkov V. F. Gogolashvili E. L. Molgacheva I. V. Gaisina A. I. Garipova A. R. Lobanov F. I. 《Russian Journal of Applied Chemistry》2003,76(5):771-774
The efficiency of water pretreatment at heat and electric power plants using low-molecular-weight cationic Praestols (coagulants) in combination with lime, iron sulfate, and flocculant (high-molecular-weight anionic Praestol) was studied. 相似文献
4.
V. F. Kurenkov A. V. Kurenkov H. -G. Hartan F. I. Lobanov 《Russian Journal of Applied Chemistry》2007,80(8):1388-1393
The effect of solvents on the kinetics of synthesis and molecular properties of copolymers formed by radical copolymerization of acrylamide with sodium 2-acrylamido-2-methylpropanesulfonate in water and in methanol-water (75: 25, 50: 50, 25: 75), ethanol-water (50: 50), and isopropanol-water (50: 50) solutions in the presence of potassium persulfate initiating agent at pH 9 and 60°C was studied. 相似文献
5.
Photoinitiated radical carbonylation with [(11)C]carbon monoxide at low concentration was employed in syntheses of carbonyl-(11)C-labeled amides using alkyl iodides and amines as precursors. Eleven (11)C-amides were synthesized in up to 74% decay-corrected radiochemical yields with reaction times of 400 s and with up to 95% conversion of carbon monoxide. Starting with 26.3 GBq of [(11)C]carbon monoxide, 10.6 GBq of 1-cyclohexane [(11)C]carbonyl-4-phenyl-piperazine (15) was obtained within 35 min from the end of bombardment (33 microA) and with a specific radioactivity of 192 GBq/micromol at the same time point. The influence of solvents was investigated. The described procedure extends the range of accessible labeling methods. The method may also be useful for preparation of (13)C- and (14)C-substituted compounds. 相似文献
6.
A. B. Malinin N. V. Kurenkov M. D. Kozlova A. S. Sevastyanova 《Journal of Radioanalytical and Nuclear Chemistry》1988,126(1):17-25
A procedure has been worked out for the preparation of chloroplatinic acid from natural metallic platinum irradiated in a nuclear reactor and purified from199Au impurities by extraction from acidic solutions with ethyl acetate. It was shown that the effective K X-ray activity of natural platinum on irradiation with moderate neutron fluxes /3×1013/ was comparable with that of195mPt obtained from 100%194Pt/with identical neutron fluxes/. Contaminations from193Pt /50 years/ is insignificant and do not produce noticeable radiation loads on the organism on medical tests in vivo. 相似文献
7.
Forryan CL Klymenko OV Brennan CM Compton RG 《The journal of physical chemistry. B》2005,109(16):8263-8269
Understanding the mechanisms of solid-liquid systems is fundamental to the development and operation of processes for the production of agrochemicals and pharmaceuticals. The use of a strong inorganic base in an organic solvent, typically, potassium carbonate in dimethylformamide, is often used to facilitate the formation of a required anionic organic nucleophile. In this paper, the dissolution kinetics of potassium carbonate in dimethylformamide at elevated temperatures is studied in the presence of ultrasound, as revealed via monitoring of the deprotonation of 2-cyanophenol by dissolved K2CO3. Two independent experimental methods were employed; the loss of 2-cyanophenol was detected electrochemically at a platinum microdisk working electrode, and the formation of the 2-cyanophenolate anion was monitored via UV/visible spectroscopic analysis. The results were modeled by fitting the experimental data to a theoretical model for the surface-controlled dissolution of solid particles. The dissolution rate constant, k, for the dissolution of K2CO3 in DMF was found to have a value of (1.3 +/- 0.2) x 10(-7) mol cm(-2) s(-1) at 100 degrees C, and the activation energy for the dissolution was 44.2 +/- 0.4 kJ mol(-1) over the temperature range of 70-100 degrees C studied. 相似文献
8.
Tippmann EM Platz MS Svir IB Klymenko OV 《Journal of the American Chemical Society》2004,126(18):5750-5762
Laser flash photolysis (LFP, 308 nm) of endo-10-halo-10'-N,N-dimethylcarboxamidetricyclo[4.3.1.0]-deca-2,4-diene (1Cl and 1F) releases indan and halocarbene amide (2Cl and 2F). Although the carbenes are not UV-vis active, they react rapidly with pyridine to form ylides (4Cl, 4F), which are readily detected in LFP experiments (lambda(max) = 450 nm). Dioxane decreases the observed rate of carbene reaction with pyridine in CF(2)ClCFCl(2). Small amounts of THF decrease the observed rate of reaction of carbene 2F with pyridine but increase the rate of reaction of carbene 2Cl with pyridine. LFP (266 nm) of dienes 1Cl and 1F in CF(2)ClCFCl(2) with IR detection produces carbenes 2Cl and 2F with carbonyl vibrations at 1635 and 1650 cm(-1), respectively. In dioxane or THF solvent, LFP produces the corresponding ether ylides (5Cl, 5F) by capture of carbenes 2Cl and 2F. The ylides have broad carbonyl vibrations between 1560 and 1610 cm(-1). The addition of a small amount of dioxane in CFCl(2)CF(2)Cl extends the lifetime of the carbene. This observation, together with the ether-induced retardation of the rates of carbene capture by tetramethylethylene and pyridine, is evidence for solvation of the carbene by dioxane. 相似文献
9.
Alexander A. Bredikhin Zemfira A. Bredikhina Alexey V. Kurenkov Dmitry B. Krivolapov 《Tetrahedron: Asymmetry》2017,28(3):442-446
Racemic 3-(4-indolyloxy)-1,2-propanediol 2 has been effectively resolved into (S)- and (R)-enantiomers by a preferential crystallization procedure. Non-racemic (S)-2 was converted into (S)-4-(2,3-epoxypropoxy)-1H-indole (S)-4 via a Mitsunobu reaction and then into (S)-pindolol (S)-1. The crystalline (S)-1 was studied by single crystal X-ray diffraction. A large number of symmetry independent molecules (Z′ = 6) led to a weakening of the system of strong intermolecular hydrogen bonds, which combined with a loose packing (PI = 64.6%), may be the cause of the abnormally low melting point of (S)-1 as compared with rac-1. 相似文献
10.
Obernikhina Nataliya V. Kachaeva Maryna V. Kachkovsky Oleksiy D. Brovarets Volodymyr S. 《Chemistry of Heterocyclic Compounds》2022,58(8-9):412-420
Chemistry of Heterocyclic Compounds - For the estimation of the biological affinity of nitrogen-containing π-conjugated heterocyclic systems toward amino acid residues in proteins, the... 相似文献