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1.
J. Bendahán C. Broude E. Dafni G. Goldring M. Hass E. Naim M. H. Rafailovich 《Hyperfine Interactions》1987,34(1-4):139-142
The parity-violating mixing of the 17/2– and 17/2+ levels in93Tc nuclei, polarized by the tilted multifoil interaction, was measured by the observation of the forward-backward-ray asymmetry. The nuclear polarization, induced by the tilted multifoils, was measured directly for the neighboring88,90Zr isomers. The forward to backward asymmetry was determined to be A=(2.5±2.1) 10–3 which implies a parity violating matrix element ¦H
PV
)¦=(4.0±3.7)meV. 相似文献
2.
The total syntheses of the epoxy cyclic hemiacetal structures 8 and 9, which are isomeric with the structure 6 proposed for the phomactin known as Sch 49028 isolated from the marine fungus Phoma sp. are described. Neither of these structures showed spectroscopic data consistent with those reported for the purported natural product, adding credibility to the proposal that the structure Sch 49028 does not exist in nature and that its NMR spectroscopic data should have been assigned as phomactin A (1). 相似文献
3.
G. Goldring 《Hyperfine Interactions》1981,9(1-4):115-126
Conclusion It has been demonstrated that the effect of a tilted multifoil array on an ensemble of nuclei approaches a regular precession in a field of magnitude pH in the direction of the tilt axis. The magnitude of the precession can, under certain circumstances, be considerably larger than in a transient field, the only other method available today for measurements in the picosecond range. The technology of multifoil arrays has not been fully mastered to date, the immediate objective being the construction of arrays which keep their shape and spacings for many hours in a particle beam. 相似文献
4.
A total synthesis of phomactin A (1) based on a Cr(II)/Ni(II) macrocyclisation from the aldehyde vinyl iodide 11, leading to 12, followed by elaboration of the epoxyketone 16, which then undergoes spontaneous pyran-hemiacetal formation on deprotection, is described. 相似文献
5.
Noa Lachman Yifat Harel Adam Green Noa Iuster Jean‐Paul Lellouche H. Daniel Wagner 《Journal of Polymer Science.Polymer Physics》2012,50(14):957-962
In this article, Multi‐Walled Carbon Nanotubes (MWCNTs) of varying diameters, both untreated and polycarboxylated, were dispersed at constant weight percentage in an epoxy matrix, and resulting fracture toughnesses (KIc) were measured in each case. We show that changing the MWCNT diameter has two effects on the composite fracture toughness: (i) a small MWCNT diameter enables larger interfacial surface for adhesion maximization, which increases toughness; (ii) at the same time, it limits the available pull‐out energy and reduces the MWCNT ability to homogeneously disperse in the matrix due to this same large active surface: this decreases toughness. Most commercially available MWCNTs have a length range of several μm, thus an optimal diameter exists which depends on MWCNT wall thickness and surface treatment. Such optimal diameter maximizes pull‐out energy and thus composite fracture toughness. © 2012 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2012 相似文献
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8.
Traditionally, Hawkes processes are used to model time-continuous point processes with history dependence. Here, we propose an extended model where the self-effects are of both excitatory and inhibitory types and follow a Gaussian Process. Whereas previous work either relies on a less flexible parameterization of the model, or requires a large amount of data, our formulation allows for both a flexible model and learning when data are scarce. We continue the line of work of Bayesian inference for Hawkes processes, and derive an inference algorithm by performing inference on an aggregated sum of Gaussian Processes. Approximate Bayesian inference is achieved via data augmentation, and we describe a mean-field variational inference approach to learn the model parameters. To demonstrate the flexibility of the model we apply our methodology on data from different domains and compare it to previously reported results. 相似文献
9.
Seri N Simaan S Botoshansky M Kaftory M Biali SE 《The Journal of organic chemistry》2003,68(18):7140-7142
The use of a chiral solvating agent enabled the determination of the NMR-silent ring-inversion process of the ketocalixarene 3. Spectroscopic and crystal data indicate that 3 adopts the unusual 1,3-alternate conformation. 相似文献
10.
A total synthesis of the PAF antagonist phomactin A (1), isolated from the marine fungus Phoma sp. is described. The synthesis is based on a Cr(II)/Ni(II) macrocyclisation from the aldehyde vinyl iodide 14, leading to the key phomactatrienol intermediate 16a, followed by elaboration of 16a to the epoxyketone 21, which undergoes spontaneous pyran and hemiacetal ring formation to 1 on deprotection with DDQ. 相似文献