全文获取类型
收费全文 | 80篇 |
免费 | 7篇 |
国内免费 | 1篇 |
专业分类
化学 | 42篇 |
力学 | 9篇 |
数学 | 26篇 |
物理学 | 11篇 |
出版年
2023年 | 1篇 |
2022年 | 4篇 |
2021年 | 2篇 |
2020年 | 2篇 |
2019年 | 1篇 |
2018年 | 6篇 |
2017年 | 3篇 |
2016年 | 4篇 |
2015年 | 5篇 |
2014年 | 6篇 |
2013年 | 6篇 |
2012年 | 3篇 |
2011年 | 7篇 |
2010年 | 5篇 |
2009年 | 8篇 |
2008年 | 5篇 |
2007年 | 4篇 |
2006年 | 3篇 |
2005年 | 3篇 |
2004年 | 2篇 |
2003年 | 1篇 |
2002年 | 1篇 |
2001年 | 1篇 |
1999年 | 2篇 |
1991年 | 1篇 |
1985年 | 1篇 |
1979年 | 1篇 |
排序方式: 共有88条查询结果,搜索用时 15 毫秒
1.
The reaction of 2-aminoquinizarine with α,β-unsaturated carbonyl compounds in presence of 10N-hydrochloric acid gives 2- and 4-substituted 5,12-dihydroxy-6,11-dioxo-1-azanaphthacenes. 相似文献
2.
Nizar Demni 《Comptes Rendus Mathematique》2009,347(19-20):1125-1128
We give shorter proofs of the following known results: the radial Dunkl process associated with a reduced system and a strictly positive multiplicity function is the unique strong solution for all times t of a stochastic differential equation with a singular drift, the first hitting time of the Weyl chamber by a radial Dunkl process is finite almost surely for small values of the multiplicity function. The proof of the first result allows one to give a positive answer to a conjecture announced by Gallardo–Yor while that of the second shows that the process hits almost surely the wall corresponding to the simple root with a small multiplicity value. To cite this article: N. Demni, C. R. Acad. Sci. Paris, Ser. I 347 (2009). 相似文献
3.
In this paper, a new dynamic model is presented for the experimental data generated by the Madison Symmetric Torus (MST) machine. The model is based on a modified sine-Gordon (SG) dynamic equation. The modified sine-Gordon equation model effectively captures the behavior of the slinky mode in reversed-field pinch experiments. In addition, this paper demonstrates how the derived model accurately describes the behavior of the localized magnetohydrodynamic mode (slinky mode) that appears in reversed-field pinch toroidal magnetic confinement systems. The modified SG equation model is solved analytically by using the perturbation method. The resulting model is fit to match a variety of experimental results in the MST reversed-field pinch experiment. The efficacy of the newly developed model in effectively representing the slinky mode is verified by comparing obtained analytical solution to experimentally measured data. 相似文献
4.
Wenjun Tang Dr. Andrew G. Capacci Xudong Wei Dr. Wenjie Li Dr. Andre White Dr. Nitinchandra D. Patel Jolaine Savoie Joe J. Gao Sonia Rodriguez Dr. Bo Qu Dr. Nizar Haddad Dr. Bruce Z. Lu Dr. Dhileepkumar Krishnamurthy Dr. Nathan K. Yee Dr. Chris H. Senanayake Dr. 《Angewandte Chemie (International ed. in English)》2010,49(34):5879-5883
5.
François Marin Nizar Abcha Jérôme Brossard Alexander Ezersky 《Comptes Rendus Mecanique》2005,333(3):227-233
Interaction between solitons and a sandy bed in shallow water is investigated. In our experiments, solitons are generated on the background of a harmonic wave, in a wave flume used in resonant mode. It is found that the sand ripples formed by the solitons propagation induce a significant decrease of solitons amplitude and of the phase shift between the soliton and the harmonic wave. However, the amplitude of the harmonic wave is approximately constant. The possible physical processes of such behaviour for the soliton amplitude and for the harmonic wave amplitude are discussed. To cite this article: F. Marin et al., C. R. Mecanique 333 (2005). 相似文献
6.
Journal of Theoretical Probability - We define and study the three-dimensional windings along Brownian paths in the quaternionic Euclidean, projective and hyperbolic spaces. In particular, the... 相似文献
7.
In this paper, we compute the expectation of traces of powers of the Hermitian matrix Jacobi process for a large enough but fixed size. To proceed, we first derive the semi-group density of its eigenvalues process as a bilinear series of symmetric Jacobi polynomials. Next, we use the expansion of power sums in the Schur polynomial basis and the integral Cauchy–Binet formula in order to determine the partitions having nonzero contributions after integration. It turns out that these are hooks of bounded weight and the sought expectation results from the integral of a product of two Schur functions with respect to a generalized beta distribution. For special values of the parameters on which the matrix Jacobi process depends, the last integral reduces to the Cauchy determinant and we close the paper with the investigation of the asymptotic behavior of the resulting formula as the matrix size tends to infinity. 相似文献
8.
Molecular Diversity - The TOPK enzyme (also known as PBK) is a serine-threonine protein kinase that is rarely detected in normal tissues yet is found to be overexpressed and activated in a variety... 相似文献
9.
Nizar El Guesmi Taoufik Boubaker Prof. Regis Goumont Prof. François Terrier Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(44):12018-12029
The kinetics of σ complexation of 2,4,6‐tris(trifluoromethanesulfonyl)anisole ( 7 d ) have been investigated over a large pH range of 2–13.70 at T=20 °C in methanol. Two competitive processes associated with the initial addition of MeO? at the unsubstituted 3‐position of 7 d to give a 1,3‐dimethoxy adduct ( 9 d ‐Me) and a subsequent and slow conversion of this species into a 1,1‐dimethoxy isomer ( 8 d ‐Me) have been identified. Both adducts 8 d ‐Me and 9 d ‐Me are 105–106 times more stable than the related adducts 8 a ‐Me and 9 a ‐Me of 2,4,6‐trinitroanisole ( 7 a ), a conventional reference aromatic electrophile in Meisenheimer complex chemistry. The high stability of 8 d ‐Me and 9 d ‐Me is shown to derive from greater rates of formation and lower rates of decomposition than previously determined for 8 a ‐Me and 9 a ‐Me, thereby emphasising the especially high activation of a benzene ring by SO2CF3 group(s). Analysis of the collected rate and equilibrium data for σ complexation in the anisole series 2,4,6‐tris(SO2CF3)‐, 2,6‐bis(SO2CF3)‐4‐nitro‐, 4‐SO2CF3‐2,6‐dinitro‐ and 2,4,6‐trinitro‐ supports the idea that the especially high capacity of resonance stabilisation of the negative charge of the adducts through an Fπ‐type (as defined in ref. 49 ) polarisation effect is a major factor that accounts for the strong activation provided by SO2CF3 groups. A most significant result is the finding that the 1,1‐dimethoxy adduct 8 d ‐Me is by far the most stable benzene σ adduct so far reported. With a p value of 7.32, this adduct is formed exclusively through methanol addition up to pH≈10. This is consistent with the location of 7 d in the superelectrophilic region defined by p ≤9.5–10.5. For comparison, the solvent contribution is negligible in the formation of the 1,3‐isomer 9 d ‐Me, the p (10.59) of which is situated on the upper limit of the boundary. Taking advantage of the simple relationship linking pKa values for σ complexation in methanol and water, a ranking of the triflone 7 d on the general thermodynamic scale constructed for Meisenheimer electrophiles in water is informative. An approximate calibration on the electrophilicity scale kinetically derived by Mayr et al. has also been made. 相似文献
10.