全文获取类型
收费全文 | 735篇 |
免费 | 34篇 |
国内免费 | 7篇 |
专业分类
化学 | 412篇 |
晶体学 | 6篇 |
力学 | 9篇 |
数学 | 154篇 |
物理学 | 195篇 |
出版年
2020年 | 8篇 |
2019年 | 10篇 |
2017年 | 11篇 |
2016年 | 14篇 |
2015年 | 16篇 |
2014年 | 18篇 |
2013年 | 43篇 |
2012年 | 28篇 |
2011年 | 21篇 |
2010年 | 19篇 |
2009年 | 22篇 |
2008年 | 27篇 |
2007年 | 30篇 |
2006年 | 28篇 |
2005年 | 28篇 |
2004年 | 49篇 |
2003年 | 28篇 |
2002年 | 29篇 |
2001年 | 16篇 |
2000年 | 8篇 |
1999年 | 11篇 |
1998年 | 7篇 |
1997年 | 13篇 |
1996年 | 13篇 |
1995年 | 7篇 |
1994年 | 8篇 |
1992年 | 6篇 |
1987年 | 10篇 |
1985年 | 8篇 |
1984年 | 9篇 |
1983年 | 9篇 |
1982年 | 11篇 |
1981年 | 6篇 |
1980年 | 6篇 |
1977年 | 6篇 |
1976年 | 9篇 |
1975年 | 6篇 |
1974年 | 11篇 |
1973年 | 9篇 |
1972年 | 9篇 |
1971年 | 5篇 |
1970年 | 7篇 |
1969年 | 5篇 |
1968年 | 9篇 |
1967年 | 6篇 |
1966年 | 6篇 |
1957年 | 5篇 |
1937年 | 6篇 |
1936年 | 5篇 |
1935年 | 8篇 |
排序方式: 共有776条查询结果,搜索用时 15 毫秒
1.
(PPh4)2HP7 · 3NH3 was prepared by the reaction of K3P7 with a proton‐charged ion exchange resin in the presence of (PPh4)Br in liquid ammonia, and characterized by low temperature X‐ray structure analysis. The thermally very unstable compound contains the hydrogenheptaphosphide anion HPequation/tex2gif-stack-1.gif, the nortricyclane‐like cage of which is slightly distorted by the attachment of the hydrogen atom. 相似文献
2.
3.
4.
5.
María Beatriz de la Calle Guntiñas Michiel Ceulemans Claudia Witte Ryszard Łobiński Freddy C. Adams 《Mikrochimica acta》1995,120(1-4):73-82
A method is presented for the selective determination of the volatile selenium species dimethylselenide and dimethyldiselenide, using a commercially available purge-and-trap injection system coupled to capillary gas chromatography-microwave induced plasma-atomic emission spectrometry. The efficiency of the purging step was evaluated and the parameters affecting the purge and trap processes were optimized. The method was applied to the determination of volatile selenium compounds in lake water. Relative detection limits of 2ng/l for dimethylselenide and dimethyldiselenide, corresponding to an absolute detection limit of 10 pg, were achieved. 相似文献
6.
Witte PT Chowdhury SR ten Elshof JE Sloboda-Rozner D Neumann R Alsters PL 《Chemical communications (Cambridge, England)》2005,(9):1206-1208
A "sandwich" type polyoxometalate catalyst ([MeN(n-C8H17)3]12[WZn3(ZnW9O34)2]) was very efficiently recycled by nanofiltration with almost quantitative retention, using an alpha-alumina supported mesoporous gamma-alumina membrane. 相似文献
7.
We examined the influence of semipolar additives on the phase behavior of mixed zwitterionic surfactant/consurfactant systems. It is shown that in these systems with increasing concentration esters like hexylacetate (HA) and ketones like hexylmethylketone (HMK) can behave both like consurfactants and like hydrocarbons. In solutions of 200 mM tetradecyldimethylamineoxide (TDMAO)/cosurfactant the additives cause first a phase transformation from the micellar L(1) phase to a lamellar L(alpha) phase. Upon further increasing concentration, the L(alpha) phase is transformed into a microemulsion. The L(alpha) phase consists of densely packed multilamellar vesicles. The vesicles are shown by electron microscopy. The multilamellar character of the vesicles is also reflected in the conductivity of the phase. It is up to 10 times lower than the conductivity of the L(1) phase. In some systems the vesicles are transformed on rest into a multidomain stacked L(alpha) phase. It is furthermore demonstrated that the two-phase L(1)/L(alpha) region in these systems is very narrow. In situations where enough HA is added to be close to the boundary of the L(1) phase, it is shown that very small amounts of cosurfactant can transform the L(1) phase into the L(alpha) phase. In extreme situations 1 mM cosurfactant is sufficient for transforming the L(1) phase with 200 mM TDMAO into the L(alpha) phase. In the investigated systems the L(alpha) phase is a highly viscoelastic fluid in which the storage modulus is 1 order of magnitude larger than the loss modulus. Besides the conventional way to prepare samples by adding all ingredients and stirring the solution intensively, all investigated systems were additionally prepared without applying any shear forces. In a surfactant/cosurfactant solution the additive was brought into the sample by diffusion. The phase behavior of both types of samples showed fundamental differences in some cases, which give insight into the influence of shear forces on these systems. Copyright 2001 Academic Press. 相似文献
8.
As12Se44—: a New Selenoarsenate Anion with a Polyarsenic Cage in the Compound [Co(NH3)6]2As12Se4 · 12 NH3 Orange coloured crystals of [Co(NH3)6]2As12Se4 · 12 NH3 were prepared by the reduction of As4Se4 with a solution of sodium in liquid ammonia and subsequent precipitation with CoBr2. The X‐ray structure determination shows them to contain the selenoarsenate anion As12Se44—, which consists of a central As12‐cage with four exo‐bonded, formally negatively charged Se atoms. The structure of the As12‐cage is equivalent to the main polyphosphorus building unit of a known organopolyphosphane and of tubular P12 in the compound (CuI)3P12. 相似文献
9.
F. Asinger D. Neuray E. C. Witte J. Hartig 《Monatshefte für Chemie / Chemical Monthly》1972,103(6):1661-1668
Zusammenfassung Durch gemeinsame Einwirkung von primären aliphat. Aminen und Schwefel auf Methylarylketone in Methanol bei Raumtemp. erhält man in meist guten Ausbeuten 8-Alkylamino-8-aryl-1,2,3,4,5,6-hexathiocan-7-thione (1a-h). Die Umsetzung von 1,4-Diacetylbenzol mit n-Propyl-bzw. n-Butylamin und Schwefel liefert Phenylen-1,4-di-hexathiocanderivate (3 a, b).Bei der Reaktion von Acetophenon mit 3-N,N-Diäthylaminopropylamin und Schwefel entstehen neben dem 8-(3-N,N-Diäthylaminopropylamino)-8-phenyl-1,2,3,4,5,6-hexathiocan-7-thion (1e) 51% einer Verbindung der Summenformel C15H22N2S2 (2), der die Struktur der (3-N,N-Diäthylaminopropylimino)-phenyldithioglyoxylsäure zugeordnet wird.1 e läßt sich durch Behandlung mit wäßr. Natriumsulfit-Lösung zu2 abbauen,2 durch Reaktion mit Schwefel wieder in1 e überführen.
77. Mitt.:F. Asinger, A. Saus, H. Offermanns undP. Scherberich, Ann. Chem.753, 151 (1971).
8. Mitt.:F. Asinger, A. Saus, H. Offermanns undF. Abo Dagga, Ann. Chem.723, 119 (1969).
Teil der DiplomarbeitJ. Hartig, Techn. Hochschule Aachen, 1969. 相似文献
Synthesis of 8-alkylamino-8-aryl-1,2,3,4,5,6-hexathiocan-7-thiones (Joint action of elemental sulfur and gaseous ammonia upon ketones, LXXVIII: Action of sulfur and amines on acetophenone, IX)
8-Alkylamino-8-aryl-1,2,3,4,5,6-hexathiocan-7-thiones (1a toh) are obtained mostly in good yields by the concomitant action of primary aliphatic amines and sulfur upon methyl aryl ketones in methanol at room temperature. Reaction of 1,4-diacetyl benzene and sulfur with n-propylamine or n-butylamine respectively leads to phenylene-1,4-dihexathiocane derivatives (3 a, b).Besides 8-(3-N,N-diethylaminopropylamino)-8-phenyl-1,2,3,4,5,6-hexathiocan-7-thione (1 e), which is obtained by reaction of acetophenone with 3-N,N-diethylaminopropylamine and sulfur, a product with the formula C15H22N2S2 (2) is isolated in 51% yield, to which the structure (3-N,N-diethylaminopropylimino)phenyl dithioglyoxylic acid is assigned. By treatment of1 e with aqueous sodium sulfite solution2 is obtained, which can be transformed back into1 e by reaction with sulfur.
77. Mitt.:F. Asinger, A. Saus, H. Offermanns undP. Scherberich, Ann. Chem.753, 151 (1971).
8. Mitt.:F. Asinger, A. Saus, H. Offermanns undF. Abo Dagga, Ann. Chem.723, 119 (1969).
Teil der DiplomarbeitJ. Hartig, Techn. Hochschule Aachen, 1969. 相似文献
10.
A. Gierulski G. Marowsky B. Nikolaus N. Vorob'ev 《Applied physics. B, Lasers and optics》1985,36(3):133-135
Second-harmonic generation from dye adsorbates has been successfully used to measure the duration of ps pulses. In the red and in the blue-green spectral range pulse durations of 2.4 and 6.1 ps—in agreement with streak camera measurements — have been obtained from collinear, slow autocorrelation traces. 相似文献