全文获取类型
收费全文 | 1784篇 |
免费 | 65篇 |
国内免费 | 11篇 |
专业分类
化学 | 1156篇 |
晶体学 | 3篇 |
力学 | 87篇 |
数学 | 312篇 |
物理学 | 302篇 |
出版年
2023年 | 14篇 |
2022年 | 45篇 |
2021年 | 46篇 |
2020年 | 35篇 |
2019年 | 35篇 |
2018年 | 27篇 |
2017年 | 18篇 |
2016年 | 73篇 |
2015年 | 55篇 |
2014年 | 82篇 |
2013年 | 104篇 |
2012年 | 124篇 |
2011年 | 142篇 |
2010年 | 87篇 |
2009年 | 68篇 |
2008年 | 105篇 |
2007年 | 107篇 |
2006年 | 105篇 |
2005年 | 108篇 |
2004年 | 86篇 |
2003年 | 75篇 |
2002年 | 46篇 |
2001年 | 23篇 |
2000年 | 15篇 |
1999年 | 16篇 |
1998年 | 11篇 |
1997年 | 16篇 |
1996年 | 22篇 |
1995年 | 15篇 |
1994年 | 13篇 |
1993年 | 9篇 |
1992年 | 5篇 |
1991年 | 6篇 |
1990年 | 9篇 |
1989年 | 9篇 |
1988年 | 6篇 |
1987年 | 5篇 |
1985年 | 6篇 |
1984年 | 9篇 |
1983年 | 12篇 |
1982年 | 6篇 |
1981年 | 4篇 |
1980年 | 4篇 |
1979年 | 3篇 |
1978年 | 7篇 |
1977年 | 7篇 |
1976年 | 5篇 |
1975年 | 7篇 |
1973年 | 6篇 |
1921年 | 2篇 |
排序方式: 共有1860条查询结果,搜索用时 0 毫秒
1.
A. Di Maio A. Rocco P. Ferraro M. De Rosa P. De Natale S. De Nicola A. Finizio G. Pierattini G. Coppola M. Iodice V. Striano 《Optics and Lasers in Engineering》2007,45(3):385
In view of the growing interest for non-destructive tests of materials, geodynamical monitoring and in general remote sensing, there is a great effort to bring practical optical sensors from research labs to industrial and environmental applications. In this paper, we employ digital holographic technique as an efficient tool for evaluating the strain measurement capability of fiber Bragg gratings (FBG). A cantilever beam has been employed as a test structure under loading test. The strain measurements results obtained by fiber-based sensors have been compared to those obtained by using full-field digital holographic technique and point-wise strain gauge sensors glued on the same cantilever beam. A simple theoretical model is also presented to interpret and compare the experimental results coming from different techniques. 相似文献
2.
Laura Bader Nicola Durante Maska Law Guglielmo Lunardon Tim Penttila 《Designs, Codes and Cryptography》2003,29(1-3):41-50
We do the tentative beginnings of a study of BLT-sets of generalised quadrangles via their symmetries. In particular, the study of whorls about a line leads us to hyperbolic reflections preserving a BLT-set of Q(4, q). 相似文献
3.
Nicola Fusco Michele Gori Francesco Maggi 《NoDEA : Nonlinear Differential Equations and Applications》2006,13(4):425-433
An approximation theorem for families of weakly coercive convex functions by means of countably many smooth families of convex
functions is proved. As a consequence, the classical “three-fold” lower semicontinuity theorem for integral functionals of
the Calculus of Variations by James Serrin is unified in one single statement. 相似文献
4.
This paper outlines the results of a study undertaken to investigate the nature of Community Operational Research (COR). The objective was to contact the people involved in COR through a series of personal interviews and a questionnaire survey, in order to clarify many of the issues that have emerged within the profession relating to the practice of OR within the community and voluntary sector. A total of 20 individuals were successfully contacted, and they have been responsible for at least two-thirds of the projects in the COR area. 相似文献
5.
S. De Nicola A. E. Kaplan S. Martellucci P. Mormile G. Pierattini J. Quartieri 《Applied physics. B, Lasers and optics》1989,49(5):441-444
We have observed a hysteretic (bistable) reflection of a Gaussian laser beam at the interface between glass and a liquid solution of polystyrene microspheres as nonlinear medium with both branches of the hysteretic curve being stable, in contrast to the results of previous experiments. 相似文献
6.
We prove partial regularity results for local minimisers of
相似文献
7.
Ana Bellomo 《Tetrahedron letters》2007,48(17):3047-3051
Diasterodivergent episulfides were chemoenzymatically derived from bromobenzene by sequential toluene dioxygenase dihydroxylation, followed by chemical epoxidation and thiolysis. The epoxide ring-opening by thiocyanate ion under literature conditions rendered the corresponding hydroxy thiocyanates and not the thiiranes as usually observed. Ring closing under carefully optimized conditions allowed the preparation of optically pure thiiranes that are key precursors for the preparation of thioconduritols and pseudodisaccharides. 相似文献
8.
Isomer-selective infrared photodissociation (IRPD) spectra are obtained for the first time for protonated polyfunctional aromatic molecules isolated in the gas phase. IRPD spectra of the oxonium and fluoronium isomers of protonated para-fluorophenol (C6H6FO+) were separately obtained by monitoring resonant photo-induced H2O and HF loss, respectively. Analysis of the F-H, O-H, and C-H stretch wave numbers provides valuable spectroscopic information on the chemical properties of these reactive intermediates, in particular on the substitution effects of functional groups. 相似文献
9.
Mazzaglia A Angelini N Lombardo D Micali N Patané S Villari V Scolaro LM 《The journal of physical chemistry. B》2005,109(15):7258-7265
The interaction between the anionic 5,10,15,20-tetrakis(4-sulfonatophenyl)-21H,23H-porphyrin (TPPS) and cationic vesicles formed by heptakis(2-omega-amino-O-oligo(ethylene oxide)-6-hexylthio)-beta-cyclodextrin (SC6CDNH2) has been investigated in detail through a combination of elastic light scattering (ELS), quasi-elastic light scattering (QELS), zeta potential measurements, and time-resolved fluorescence anisotropy. ELS experiments provided the first structural characterization of these cationic vesicles both in the absence and in the presence of TPPS porphyrin, modeling the system as a spherical particle described by a single thin shell form factor. The structure of mixed hetero-aggregates is modulated by charge and size of the two components as function of different porphyrin/cyclodextrin (CD) molar ratios. At the limiting molar ratio studied, the absolute value of zeta potential (/zeta/ = 12.5 mV) seems to be a reference value for the formation of stable colloidal CD vesicular aggregates at thermodynamic equilibrium. New insights on the structure of these heterotopic colloids have been obtained by analysis of rotational correlation times at different molar ratios exploiting time-resolved fluorescence anisotropy experiments. At high porphyrin loads, the anisotropy decays behave as monoexponentials and the rotational correlation times (1-2 ns) together with the r(0) values close to zero suggest the presence of small amounts of TPPS embedded in a hydrophobic environment either in monomeric or in aggregated form. At the lower porphyrin/CD molar ratios, the anisotropy decays exhibit a double-exponential behavior showing a predominant component with a slow rotational correlation time (20-25 ns) and limiting anisotropy values of approximately 0.15. This component has been assigned to molecules that are more stabilized onto the CD vesicles, that is, porphyrins embedded into the oligo-ethylene "wall" of the CD vesicles. Scanning near-field optical microscopy of the samples evaporated on glass surfaces gave further insights on the morphology and optical properties of these systems, confirming the embedding of TPPS on the vesicles and evidencing the role of the solvent. 相似文献
10.
King NC Dickinson C Zhou W Bruce DW 《Dalton transactions (Cambridge, England : 2003)》2005,(6):1027-1032
Mesoporous silicates are prepared by templating on the hexagonal (H1) mesophase of surfactant bipyridine complexes of ruthenium(II) using a true liquid-crystal templating approach. On calcination, the surfactant template is removed except for the central metal ion that is oxidised, forming nanoparticles of RuO2 that deposit within the pores. RuO2 is a known oxidation catalyst and, despite its anhydrous nature in these silicates, is found to be very active in catalyzing the oxidation of water by acidic CeIV. 相似文献
|