全文获取类型
收费全文 | 1944篇 |
免费 | 114篇 |
国内免费 | 29篇 |
专业分类
化学 | 1544篇 |
晶体学 | 23篇 |
力学 | 76篇 |
数学 | 135篇 |
物理学 | 309篇 |
出版年
2024年 | 9篇 |
2023年 | 13篇 |
2022年 | 85篇 |
2021年 | 86篇 |
2020年 | 94篇 |
2019年 | 75篇 |
2018年 | 85篇 |
2017年 | 74篇 |
2016年 | 142篇 |
2015年 | 84篇 |
2014年 | 115篇 |
2013年 | 233篇 |
2012年 | 143篇 |
2011年 | 128篇 |
2010年 | 95篇 |
2009年 | 69篇 |
2008年 | 98篇 |
2007年 | 82篇 |
2006年 | 59篇 |
2005年 | 57篇 |
2004年 | 38篇 |
2003年 | 38篇 |
2002年 | 30篇 |
2001年 | 17篇 |
2000年 | 9篇 |
1999年 | 10篇 |
1998年 | 5篇 |
1997年 | 4篇 |
1996年 | 11篇 |
1995年 | 5篇 |
1994年 | 5篇 |
1993年 | 6篇 |
1992年 | 7篇 |
1991年 | 9篇 |
1989年 | 9篇 |
1988年 | 3篇 |
1987年 | 3篇 |
1986年 | 4篇 |
1985年 | 4篇 |
1984年 | 4篇 |
1983年 | 2篇 |
1982年 | 9篇 |
1981年 | 4篇 |
1980年 | 5篇 |
1979年 | 2篇 |
1978年 | 3篇 |
1977年 | 5篇 |
1974年 | 2篇 |
1973年 | 3篇 |
1963年 | 1篇 |
排序方式: 共有2087条查询结果,搜索用时 15 毫秒
1.
Saleh Z. M. Nasser H. Özkol E. Günöven M. Abak K. Canli S. Bek A. Turan R. 《Journal of nanoparticle research》2015,17(10):1-12
Journal of Nanoparticle Research - Plasmonic interfaces consisting of silver nanoparticles of different sizes (50–100&;nbsp;nm) have been processed by the self-assembled dewetting... 相似文献
2.
Abdo Y. Alfakih 《Discrete Applied Mathematics》2007,155(10):1244-1253
Let V={1,2,…,n}. A mapping p:V→Rr, where p1,…,pn are not contained in a proper hyper-plane is called an r-configuration. Let G=(V,E) be a simple connected graph on n vertices. Then an r-configuration p together with graph G, where adjacent vertices of G are constrained to stay the same distance apart, is called a bar-and-joint framework (or a framework) in Rr, and is denoted by G(p). In this paper we introduce the notion of dimensional rigidity of frameworks, and we study the problem of determining whether or not a given G(p) is dimensionally rigid. A given framework G(p) in Rr is said to be dimensionally rigid iff there does not exist a framework G(q) in Rs for s?r+1, such that ∥qi-qj∥2=∥pi-pj∥2 for all (i,j)∈E. We present necessary and sufficient conditions for G(p) to be dimensionally rigid, and we formulate the problem of checking the validity of these conditions as a semidefinite programming (SDP) problem. The case where the points p1,…,pn of the given r-configuration are in general position, is also investigated. 相似文献
3.
Saeed Balalaie Elahe Kowsari Mehri S. Hashtroudi 《Monatshefte für Chemie / Chemical Monthly》2003,134(3):453-456
Summary. Three component condensation of alkylacetoacetates, primary amines, and alkyl cyanoacetates catalyzed by solid supports under
microwave irradiation gave N-alkyl 3-cyano-6-hydroxy-2(1H)-pyridinones with high yields. Upon carrying out the reaction under the same condition on acidic alumina, zeolite HY, silica
gel, and montmorillonite K-10, the best yields were achieved by silica gel.
Corresponding author. E-mail: balalaie@yahoo.com
Received August 28, 2002; accepted September 3, 2002 相似文献
4.
Ali. Elamin. M. Saeed 《Annals of Differential Equations》2006,22(2):127-133
The purpose of this paper is to study a general Lienard type cubic system with one antisaddle and two saddles. We give some results of the existence and uniqueness of limit cycles as well as the evolution of limit cycles around the antisaddle for system (2) in the following when parameter a1 changes. 相似文献
5.
6.
D-3-Hydroxybutyrate dehydrogenase (BDH) is an NAD(+)-dependent dehydrogenase of the mitochondrial inner membrane involved in the energetic balance between the liver and peripheral organs in mammals. It allows the conversion of ketone bodies (acetoacetate and D-3-hydroxybutyrate) and it is one of the best documented lipid-requiring enzymes with a dependence on lecithins. After release of proteins from the membrane by phospholipase A2 treatment of salt-treated mitochondria, the rat liver enzyme is absorbed on controlled-pore glass beads. After batch washing, the enzyme, devoid of lipids (apoBDH), is specifically eluted at pH 8.05-8.15 with a 0.1 M Tris-1 M LiBr buffer under reducing conditions (5 mM dithiothreitol). It appears that during BDH absorption, the glass beads mimic the phospholipid surface of biomembranes. 相似文献
7.
Nicolas Meyer Mohamad Nasser Eddine Christelle Delaite Guy Hurtrez Philippe Dumas 《Journal of polymer science. Part A, Polymer chemistry》2003,41(21):3329-3335
The reactions of polystyryllithium and potassium on dimethoxymethyl 1,1‐diphenylethylene derivatives were studied in different solvents. In a polar medium, A3 and A6 star types were formed according to the stoichiometry, whereas in a nonpolar medium, hyperbranched structures were synthesized. Extensions of an already proposed mechanism in polar and nonpolar media were examined. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3329–3335, 2003 相似文献
8.
Ti(IV) as TiCl3(O3SCF3) and TiO(O2CCF3)2 are used as efficient catalysts for oxidative coupling of aliphatic, aromatic and heteroaromatic thiols to their disulfides in the presence of NaI under air atmosphere. 相似文献
9.
Mohammad M. Mojtahedi Hassan Abbasi M. Saeed Abaee 《Journal of molecular catalysis. A, Chemical》2006,250(1-2):6-8
Various types of alcohols and phenols were rapidly protected by hexamethyldisilazane in good to excellent yields at room temperature in the presence of catalytic amount of magnesium bromide ethyl etherate under solvent-free conditions. Good to excellent chemoselectivity was demonstrated for competitive protection of primary hydroxyls in the presence of secondary and tertiary alcohols. Highly selective protection of phenols in the presence of aromatic amines was also demonstrated successfully. 相似文献
10.
M. I. Nasser M. A. Moharram 《International Journal of Infrared and Millimeter Waves》1989,10(1):73-82
In this work, the temperature dependence of the intensities of the IR absorption bands corresponding to the fundamental vibrations, overtones and combination frequencies of diphenyl is presented. A thorough discussion of the interpretation of the fundamental modes of vibration has been made on the basis of the temperature dependence of the intensities of these absorption bands.The structure of the diphenyl molecule has been the subject of numerous investigations. Despite a considerable amount of work on the Raman(1), IR(3,4,5) and ultraviolet (2) spectra, the assignment of the fundamental frequencies has not yet been established with certainty, Some assistance can be obtained from the temperature dependence of the IR spectrum of this material. 相似文献