全文获取类型
收费全文 | 88篇 |
免费 | 1篇 |
专业分类
化学 | 53篇 |
力学 | 2篇 |
数学 | 2篇 |
物理学 | 32篇 |
出版年
2023年 | 1篇 |
2021年 | 1篇 |
2020年 | 1篇 |
2019年 | 1篇 |
2018年 | 1篇 |
2017年 | 1篇 |
2016年 | 1篇 |
2014年 | 1篇 |
2013年 | 3篇 |
2012年 | 4篇 |
2011年 | 3篇 |
2009年 | 2篇 |
2008年 | 5篇 |
2007年 | 5篇 |
2006年 | 6篇 |
2005年 | 5篇 |
2004年 | 8篇 |
2003年 | 3篇 |
2002年 | 3篇 |
2001年 | 3篇 |
2000年 | 3篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1996年 | 3篇 |
1994年 | 4篇 |
1993年 | 1篇 |
1992年 | 3篇 |
1991年 | 1篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1987年 | 1篇 |
1986年 | 3篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1978年 | 1篇 |
1975年 | 1篇 |
1970年 | 1篇 |
1968年 | 1篇 |
排序方式: 共有89条查询结果,搜索用时 0 毫秒
1.
2.
Radioimmunoassays were used to investigate the repair of cyclobutane pyrimidine dimers and pyrimidine (6-4)pyrimidone photoproducts ((6-4] photoproducts) in the epidermis of the South American opossum, Monodelphis domestica. In the absence of photoreactivating light, both types of photodamage were excised with similar kinetics, 50% of the damage remaining 8 h after UV irradiation in vivo. Exposure of UV-irradiated skin to photoreactivating light resulted in removal of most of the cyclobutane dimers and an enhanced rate of (6-4) photoproduct repair. Photoenhanced excision repair of non-dimer damage increases the range of biologically effective lesions removed by in vivo photoreactivation. 相似文献
3.
Asymmetric hydrogenation of ketone 1 using trans-RuCl(2)[(R)-xylbinap][(R)-daipen] (3) as a catalyst afforded secondary alcohol 2 quantitatively and in 99.4% ee. Further exploration of the effect of the thiazole ring substitution revealed that the catalyst was highly effective for the enantioselective hydrogenation of 5-benzoyl thiazoles, which afforded corresponding alcohols in 92-99% ee. The same protocol was applicable to a variety of aromatic-heteroaromatic ketones to generate secondary alcohols in excellent enantioselectivities. [reaction: see text] 相似文献
4.
5.
Eric Rivard Andrew R. McWilliams Alan J. Lough Ian Manners 《Phosphorus, sulfur, and silicon and the related elements》2013,188(4-5):845-847
An unusual, reversible skeletal substitution reaction involving boron- and aluminum-based heterophosphazenes is described. 相似文献
6.
Iskakov AB Schekochihin AA Cowley SC McWilliams JC Proctor MR 《Physical review letters》2007,98(20):208501
Direct numerical simulations of incompressible nonhelical randomly forced MHD turbulence are used to demonstrate for the first time that the fluctuation dynamo exists in the limit of large magnetic Reynolds number Rm>1 and small magnetic Prandtl number Pm<1. The dependence of the critical Rmc for dynamo on the hydrodynamic Reynolds number Re is obtained for 1 less than or similar Re less than or similar 6700. In the limit Pm<1, Rmc is about 3 times larger than for the previously well-established dynamo at large and moderate Prandtl numbers: Rmc less than or similar 200 for Re greater than or similar 6000 compared to Rmc approximately 60 for Pm>or=1. It is not yet possible to determine numerically whether the growth rate of the magnetic energy is proportional, Rm1/2 in the limit Rm-->infinity, as it should be if the dynamo is driven by the inertial-range motions at the resistive scale. 相似文献
7.
The flow between two concentric cylinders, V(r), is studied analytically and computationally for a fluid with stable axial density stratification. A sufficient condition for linear, inviscid instability is d(V/r)(2)/dr<0 (i.e., all anticyclonically sheared flows) rather than the Rayleigh condition for centrifugal instability, d(Vr)(2)/dr<0. This implies a far wider range of instability than previously identified. The instability persists with finite viscosity and nonlinearity, leading to chaos and fully developed turbulence through a sequence of bifurcations. Laboratory tests are feasible and desirable. 相似文献
8.
Baker JG van Meter JR McWilliams ST Centrella J Kelly BJ 《Physical review letters》2007,99(18):181101
General relativity predicts the gravitational wave signatures of coalescing binary black holes. Explicit waveform predictions for such systems, required for optimal analysis of observational data, have so far been achieved primarily using the post-Newtonian (PN) approximation. The quality of this treatment is unclear, however, for the important late-inspiral portion. We derive late-inspiral waveforms via a complementary approach, direct numerical simulation of Einstein's equations. We compare waveform phasing from simulations of the last approximately 14 cycles of gravitational radiation from equal-mass, nonspinning black holes with the corresponding 2.5PN, 3PN, and 3.5PN orbital phasing. We find phasing agreement consistent with internal error estimates for either approach, suggesting that PN waveforms for this system are effective until the last orbit prior to final merger. 相似文献
9.
Nairn McWilliams 《Applied Mathematical Finance》2013,20(5):423-446
Abstract Motivated by the increasing interest in past-dependent asset pricing models, shown in recent years by market practitioners and prominent authors such as Hobson and Rogers (1998, Complete models with stochastic volatility, Mathematical Finance, 8(1), pp. 27–48), we explore option pricing techniques for arithmetic Asian options under a stochastic delay differential equation approach. We obtain explicit closed-form expressions for a number of lower and upper bounds and compare their accuracy numerically. 相似文献
10.
High‐Frequency Fe–H Vibrations in a Bridging Hydride Complex Characterized by NRVS and DFT
下载免费PDF全文
![点击此处可从《Angewandte Chemie (International ed. in English)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Dr. Vladimir Pelmenschikov Dr. Leland B. Gee Dr. Hongxin Wang Dr. K. Cory MacLeod Sean F. McWilliams Dr. Kazimer L. Skubi Prof. Dr. Stephen P. Cramer Prof. Dr. Patrick L. Holland 《Angewandte Chemie (International ed. in English)》2018,57(30):9367-9371
High‐spin iron species with bridging hydrides have been detected in species trapped during nitrogenase catalysis, but there are few general methods of evaluating Fe?H bonds in high‐spin multinuclear iron systems. An 57Fe nuclear resonance vibrational spectroscopy (NRVS) study on an Fe(μ‐H)2Fe model complex reveals Fe?H stretching vibrations for bridging hydrides at frequencies greater than 1200 cm?1. These isotope‐sensitive vibrational bands are not evident in infrared (IR) spectra, showing the power of NRVS for identifying hydrides in this high‐spin iron system. Complementary density functional theory (DFT) calculations elucidate the normal modes of the rhomboidal iron hydride core. 相似文献