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1.
N. K. Morozova Yu. A. Pashchenko V. D. Chernyi V. G. Galstyan T. P. Dolukhanyan V. I. Muratova 《Russian Physics Journal》1987,30(2):143-149
The nature of the luminescence of zinc sulfide in the spectral range (360), 380–420 nm (SAL) at 80K is analyzed. It is shown that the appearance of SAL radiation is accompanied by additional absorption in the region (350) 365–370 nm at 80K. The low-temperature spectra of sphalerite, exposed to different radiation and subjected to different treatment, are studied. The multiband luminescence of the isoelectronic sulfur impurity in ZnO deposits in the region 383–640 nm is discussed. It is concluded that SAL luminescence is attributable to the localization of excitons in ZnS on clusters, whose formation precedes the precipitation of the ZnO·S phase. The formation of oxygen clusters and deposits on dislocations in ZnS is studied.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 2, pp. 60–66, February, 1987. 相似文献
2.
N. B. Morozova A. E. Turgambaeva I. A. Baidina V. V. Krysyuk I. K. Igumenov 《Journal of Structural Chemistry》2005,46(6):1047-1051
The structure of titanyl dipivalylmethanate TiO(dpm)2 has been studied by X-ray diffraction analysis. The compound has a molecular structure formed by isolated centrosymmetrical dimers [TiO(dpm)2]2; the unit cell contains two structurally related, crystallographically unique binuclear molecules. The Ti...Ti distance in the dimer is 2.73 Å. Crystal data for Ti2C36H76O10: a = 32.477(6) Å, b = 14.409(3) Å, c = 25.630(5) Å; β = 107.82(3)°, space group C2/c, Z = 8, d calc = 1.002 g/cm3. 相似文献
3.
I. I. Grandberg L. F. Morozova V. A. Moskalenko A. N. Kost 《Chemistry of Heterocyclic Compounds》1972,5(6):792-796
The possibility of the separation into optical antipodes of racemic amino acids of the pyrazole series has been investigated. The trans configuration of the acrylic acids obtained as by-products in the synthesis of -amino acids of the pyrazole series by the Rodionov reaction has been shown by PMR and IR spectroscopy. The IR spectra of a series of amino acids are discussed.For part LXII, see [1]. 相似文献
4.
D. B. Furman N. V. Volchkov L. S. Isaeva L. N. Morozova D. N. Kravtsov O. V. Bragin 《Russian Chemical Bulletin》1988,37(11):2220-2222
Conclusions By studying the liquid-phase dimerization of ethylene in the presence of Cat-Et3Al2-Cl3 catalytic systems based on a nickel complex heterogenized on Al2O3 and a number of model nickel complexes, a similar activity and selectivity of the process has been established (Cat=NiPPh3(CO)2L, where L=PPh3, CO, Al2O3; Ni(PPh3)2(CO)2; Ni(PPh3)2(2-C2H4); Ni[P(C6H11)3]2(H)Cl and Ni(PPh3)(Et)Cl).The results of the investigation agree with the hypothesis that mono- and diolefinic nickel complexes are formed as the active intermediates in the reaction.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2466–2469, November, 1988. 相似文献
5.
Shleev SV Khan IG Gazaryan IG Morozova OV Yaropolov AI 《Applied biochemistry and biotechnology》2003,111(3):167-184
The screening of potential redox mediators for laccase was performed using homogeneous enzyme preparations from Coriolus hirsutus and Coriolus zonatus. It was discovered that derivatives of 1-phenyl-3-methyl-pyrazolones were efficient substrates for the laccases. The characterization of two representatives of the 1-phenyl-pyrazolone class, sodium 1-phenyl-3-methyl-4- methylamino-pyrazolone-5-N(4)-methanesulfonate and 1-(3'-sulfophenyl)-3- methylpyrazolone-5, in the reaction catalyzed by laccase was carried out using spectral, electrochemical, and enzyme kinetics methods. The kinetic parameters for the oxidation of the newly discovered substrates were comparable with those for 2,2'-azino-bis(3-ethylbenzthiazoline-6-sulfonate) (ABTS) oxidation by laccase. Electrochemical experiments demonstrated that oxidation of these compounds yielded two high-potential intermediates capable of oxidizing veratryl alcohol, which was used as a lignin model substrate, to the corresponding aldehyde and acid. 1-(3'-Sulfophenyl)-3- methylpyrazolone-5 was about 30-40% as effective in degrading veratryl alcohol compared to ABTS as judged from high-performance liquid chromatography kinetic studies. 1-Phenyl-3-methyl-pyrazolones may be of commercial interest for oxidoreductase-catalyzed biodegradation of organic compounds. 相似文献
6.
S. S. Morozova A. N. Katyuzhanskaya A. V. Pekhov E. P. Koshevoi N. S. Mikhailova 《Chemistry of Natural Compounds》1977,12(3):269-272
Summary The conditions for the reaction of esters—bornyl acetate—with an alkaline solution of hydroxylamine have been studied by the method of steepest ascent. A method has been developed for determining esters in a CO2 extract ofAbies sibirica.Krasnodar Scientific-Research Institute of the Food Industry. Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 303–306, May–June, 1976. 相似文献
7.
E. M. Suleimenov O. V. Morozova V. A. Raldugin Yu. V. Gatilov T. V. Rybalova M. M. Shakirov R. Seidakhmetov R. M. Aksartov S. M. Adekenov 《Chemistry of Natural Compounds》2005,41(5):556-560
Four sesquiterpene lactones with the germacrane structure were isolated from the aerial part of Stizolophus balsamita. X-ray structure analyses showed that two of them were previously known balsamin derivatives. A third was a crystalline isomorphous
mixture of the known lactone stizolin and 11,13-dihydrostizolin in a 53:47 ratio. The biological activities of the balsamin
derivatives were investigated.
__________
Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 454–457, September–October, 2005. 相似文献
8.
9.
Mikhail S. Panov Natalya N. Saprygina Olga B. Morozova Alexey S. Kiryutin Yuri A. Grishin Alexandra V. Yurkovskaya 《Applied magnetic resonance》2014,45(10):1019-1033
The photooxidation reaction between 3,3′,4,4′-benzophenone tetracarboxylic acid (TCBP) and l-histidine (His) has been investigated in neutral aqueous solution using the technique of chemically induced dynamic nuclear polarization (CIDNP). Relative values of 13C isotropic hyperfine couplings in the TCBP and His radicals were obtained from the 13C-time-resolved CIDNP spectrum, recorded during the photoreaction of TCBP with His at natural abundance of the magnetic isotope 13C. Good agreement was found for the hyperfine coupling constants of the TCBP ketyl radical calculated using methods of density functional theory, and those obtained from the 13C-time-resolved CIDNP spectrum. The mechanism of the quenching reaction of triplet-excited TCBP by His in neutral aqueous solution was established. 1H CIDNP field dependencies for the photoreaction of TCBP with His were obtained and the g-factor of the histidyl radical was found. 相似文献
10.
Yu. P. Morozova O. M. Zharkova T. Yu. Balakina V. Ya. Artyukhov B. V. Korolev 《Russian Physics Journal》2011,54(5):594-600
The fluorescent probe molecule – laurdan (6-dodekanoil-2-dimetilamin naphthalene) – is investigated by experimental and quantum-chemical
methods. The influence of the structure non-rigidity on the dipole moments, arrangement of energy levels, and distribution
of charges in the laurdan molecule is studied. An optimized structure is obtained and analyzed by the molecular dynamics method.
Several structures with different rotation angles of the dimethylamino group are investigated, for which energy, oscillator
forces, and nature of electron states are calculated. Fluorescence spectra of the laurdan molecule in an inert solvent are
interpreted. Centers of possible interaction of the molecule with a proton-donor solvent are established. Rate constants of
radiative and nonradiative processes and quantum fluorescence yields of the examined probe are calculated. 相似文献