A methodology for monitoring washing procedures applied to stabilize archaeological iron is described. It is based on the combination of voltammetry of microparticles (VMP) with electrochemical impedance spectroscopy (EIS). A semi-empirical approach is used where the impedances at low and high frequencies were related with the fraction areas of passive and corrosion layers generated during the stabilizing treatment, the thickness, and the porosity of the corrosion layer. The variation of such parameters with the time of washing was determined from EIS data for four types of desalination procedures using concentrated NaOH and/or Na2SO3 aqueous solutions on archaeological iron artifacts. After 2 months of treatment, EIS data indicate that an essentially identical “stable” state was attained in all cases, as confirmed by the formation of a passive magnetite layer identified in VMP measurements while the rate of variation of corroded surface and porosity at short washing times varied significantly from one stabilization procedure to another. 相似文献
Thermolysis studies of β-hydroxyolefins in gas phase were realized using ab initio MP2 and DFT methods at the 6-31G* levels to explore the possibility of determining a possible concerted process with a six-membered cyclic transition state (TS). Vibrational frequency calculations were carried out in order to confirm the stationary states, including TS structures. IRC calculations have been performed in all cases in order to verify that localized TS structures connect with the corresponding minimum stationary points associated with the reactant and products. With the aim of corroborating the postulated mechanism in the experimental study, we present a theoretical study in order to calculate the rate constants and the activation parameters. The results obtained are in accordance with the experimental conclusions. 相似文献
A three-dimensional nonlinear dynamo process is identified in rotating plane Couette flow in the Keplerian regime. It is analogous to the hydrodynamic self-sustaining process in nonrotating shear flows and relies on the magnetorotational instability of a toroidal magnetic field. Steady nonlinear solutions are computed numerically for a wide range of magnetic Reynolds numbers but are restricted to low Reynolds numbers. This process may be important to explain the sustenance of coherent fields and turbulent motions in Keplerian accretion disks, where all its basic ingredients are present. 相似文献
For calculating large deformations of solid bodies, we have proposed a method of successive linear approximation, by considering the relative Lagrangian formulation. In this article we briefly describe this method, which is applied for nearly incompressible Mooney-Rivlin materials. We prove the existence and uniqueness of weak solutions for associated boundary value problems that arise in each step of the method. In our analysis we consider also a non-standard case, where the coefficients present in the constitutive function of Mooney-Rivlin materials do not satisfy the usual E-inequalities. 相似文献
AbstractIn this paper, we give a theoretical and numerical analysis of a model for small vertical vibrations of an elastic membrane coupled with a heat equation and subject to linear mixed boundary conditions. We establish the existence, uniqueness, and a uniform decay rate for global solutions to this nonlinear non-local thermoelastic coupled system with linear boundary conditions. Furthermore, we introduced a numerical method based on finite element discretization in a spatial variable and finite difference scheme in time which results in a nonlinear system to be solved by Newton’s method. Numerical experiments for one-dimensional and two-dimensional cases are presented in order to estimate the rate of convergence of the numerical solution that confirm our analysis and show the efficiency of the method. 相似文献
Enzymes are gradually increasingly preferred over chemical processes, but commercial enzyme applications remain limited due to their low stability and low product recovery, so the application of an immobilization technique is required for repeated use. The aims of this work were to produce stable enzyme complexes of cross-linked xylanase on magnetic chitosan, to describe some characteristics of these complexes, and to evaluate the thermal stability of the immobilized enzyme and its reusability. A xylanase was cross-linked to magnetite particles prepared by in situ co-precipitation of iron salts in a chitosan template. The effect of temperature, pH, kinetic parameters, and reusability on free and immobilized xylanase was evaluated. Magnetization, morphology, size, structural change, and thermal behavior of immobilized enzyme were described. 1.0?±?0.1 μg of xylanase was immobilized per milligram of superparamagnetic chitosan nanoparticles via covalent bonds formed with genipin. Immobilized xylanase showed thermal, pH, and catalytic velocity improvement compared to the free enzyme and can be reused three times. Heterogeneous aggregates of 254 nm were obtained after enzyme immobilization. The immobilization protocol used in this work was successful in retaining enzyme thermal stability and could be important in using natural compounds such as Fe3O4@Chitosan@Xylanase in the harsh temperature condition of relevant industries.
The total phenolic and flavonoid content, phenolic composition, and in vitro antioxidant capacity of ethanolic extracts of Ximenia parviflora Benth. var. parviflora fruits collected at Zinaparo, Michoacan (in central Mexico) were determined. Fruit extracts present a high scavenging activity of 2,2-diphenyl-1-picrylhydrazyl and 2,2′-azino-bis[3-ethylbenzothiazoline-6-sulfonic acid] radicals (71.49?±?0.11% and 85.00?±?1.29% inhibition, respectively). The four phenolic compounds identified in fruit extracts by high-performance liquid chromatography with diode array detection were gallic acid, chlorogenic acid, caffeic acid, and quercetin. X. parviflora fruits may be used as a starting material for the extraction of high value antioxidant phenolic compounds with potential applications in the pharmaceutical and dietary supplement industries. 相似文献
A study of three Spanish and one Bulgarian basaltic rock demonstrated that, after thermal treatment at temperatures higher
than 800°C, crystallization of pyroxenes, anorthite and magnetic occurred. Following sintering of the original basalts and
powdered original glasses, the same crystalline phases were nucleated and grown in the resulting glass-ceramics. Chemical
and DTA/TG analyses suggested similar behaviour for the synthesized Canarian basalt glasses, which are located in the tephrite-basanite
field, and different behaviour for the trachy-andesite Canarian and the basaltic-andesite Bulgarian basalt glass. In consequence
of the high sensitivity of the specific heat to phase transformations, Cp(T) and TMA experiments allowed a distinction between the tephrite-basanite and trachy-andesite Canarian glasses on the basis
of their different thermal behaviour.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献