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排序方式: 共有387条查询结果,搜索用时 15 毫秒
1.
2.
The dilepton spectra from open charm decay inp+A reactions at $\sqrt s = 200$ AGeV are proposed to constrain gluon shadowing in nuclei. We show that the required measurements are feasible at RHIC. 相似文献
3.
Eles J Kalaus G Greiner I Kajtár-Peredy M Szabó P Keserû GM Szabó L Szántay C 《The Journal of organic chemistry》2002,67(21):7255-7260
The first syntheses of the alkaloids (-)-mehranine (3), (+)-voaphylline/conoflorine (4), (+)-N(a)-methylvoaphylline/hecubine (5), and (-)-lochnericine (2) were achieved by stereoselective epoxidation starting from (-)-tabersonine (1), through intermediates with the aspidospermane and quebrachamine skeleton. 相似文献
4.
Summary A numerically stable and well-parallelizable curve variational algorithm is described for determining tangent curves of vector fields between two given stationary points. In particular, the method is suitable for finding reaction paths and saddle points on potential energy hypersurfaces (PHS). The stability of the procedure is illustrated by an artificial mathematical function, showing phases of following the reaction on the PHS.Dedicated to Professor Zoltán G. Szabó, the great teacher and scientist in reaction kinetics and in many other fields of physical chemistry, on his 84th birthday. 相似文献
5.
The cationization of poly(ethylene glycol)s, PEG 4000 and PEG 6000, under matrix-assisted laser desorption/ionization conditions was studied by using different concentration ratios of the sodium ion, as the reference ion, and another alkali metal ion (Li(+), K(+), Rb(+), Cs(+)). A linear correlation was found between the intensity ratio of the sodiated PEGs and PEGs cationized with alkali metal ions versus the initial concentration ratio of sodium and alkali metal ions. The slopes of these straight lines are proposed as a novel selectivity ratio for the ionization process. The intensity distribution of the cationized PEGs was also investigated. It was found that the cationized oligomers follow Poisson statistics. The M(n) and M(w) values were also evaluated. An explanation for the observed effects is given. 相似文献
6.
Thapper A Behrens A Fryxelius J Johansson MH Prestopino F Czaun M Rehder D Nordlander E 《Dalton transactions (Cambridge, England : 2003)》2005,(21):3566-3571
Reaction of the tetradentate ligand N-(2-hydroxybenzyl)-N,N-bis(2-pyridylmethyl)amine (L-OH) with MoO2Cl2 in methanol in the presence of NaOMe and PF6- results in the formation of [MoO2(L-O)]PF6. Similarly, the reaction of N-(2-mercaptobenzyl)-N,N-bis(2-pyridylmethyl)amine (L-SH) with MoO2(acac)2 leads to the formation of [MoO2(L-S)]+. The dioxo-molybdenum complex [MoO2(L-O)]+ reacts with phosphines in methanol to afford phosphine oxides and an air-sensitive molybdenum complex, tentatively identified as [Mo(IV)O(L-O)(OCH3)]. The latter complex is capable of reducing biological oxygen donors such as DMSO or nitrate, thereby mimicking the activity of DMSO reductase and nitrate reductase. Reaction of [MoO2(L-O)]PF6 with PPh3 in other solvents than methanol leads to the formation of the Mo(V) dimer [(L-O)OMo(micro-O)MoO(L-O)](PF6)2. The crystal structures of [MoO2(L-O)]PF6 and the micro-oxo bridged dimer are presented. 相似文献
7.
Given two graphsH andG, letH(G) denote the number of subgraphs ofG isomorphic toH. We prove that ifH is a bipartite graph with a one-factor, then for every triangle-free graphG withn verticesH(G) H(T
2(n)), whereT
2(n) denotes the complete bipartite graph ofn vertices whose colour classes are as equal as possible. We also prove that ifK is a completet-partite graph ofm vertices,r > t, n max(m, r – 1), then there exists a complete (r – 1)-partite graphG* withn vertices such thatK(G) K(G*) holds for everyK
r
-free graphG withn vertices. In particular, in the class of allK
r
-free graphs withn vertices the complete balanced (r – 1)-partite graphT
r–1(n) has the largest number of subgraphs isomorphic toK
t
(t < r),C
4,K
2,3. These generalize some theorems of Turán, Erdös and Sauer.Dedicated to Paul Turán on his 80th Birthday 相似文献
8.
9.
Truong Son Pham Katalin Gönczi György Kardos Krisztina Süle László Hegedűs Mihály Kállay Miklós Kubinyi Pál Szabó Imre Petneházy László Tőke Zsuzsa Jászay 《Tetrahedron: Asymmetry》2013,24(24):1605-1614
Several cinchona based squaramide catalysts were applied to the asymmetric Michael addition of α-nitroethylphosphonates to acrylic acid aryl esters, resulting in high yields and enantioselectivities. The absolute configuration of one of the quaternary α-nitrophosphonate adducts was deduced from its experimental and calculated CD spectra. The adducts were reduced to their cyclic aminophosphonates by catalytic hydrogenation. 相似文献
10.
István Kapovits József Rábai Dénes Szabó Miklós Kuti 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1):435-436
The reactions of possible spiro-λ4-sulfane precursor diaryl sulfoxides with dehydrating agents have been studied resulting in the formation of cyclic anhydride, spiro-λ4-sulfane, cyclic sulfonium-ylide, lactam-sulfoxide, cyclic sulfonimide and cyclic sulfilimine type of intermediates or products. The structures of the intermediates or products depend on the functional groups attached to the aryl rings at ortho positions and on the reaction conditions applied. 相似文献