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In the present study, controlled protein adsorption on a rigid silica microparticle is investigated numerically using classical Langmuir and two-state models under electrokinetic flow conditions. The instantaneous particle locations are simulated along a straight microchannel using an arbitrary Lagrangian−Eulerian framework in the finite element method for the electrophoretic motion of the charged particle. Within the scope of the parametric study, the strength of the external electric field (E), particle diameter (Dp), the zeta potential of the particle (ζp), and the location of the microparticle away from the channel wall (H) are systematically varied. The results are also compared to the data of pressure-driven flow having a parabolic flow profile at the inlet whose maximum magnitude is set to the particle's electrophoretic velocity magnitude. The validation studies reveal that the code developed for the particle motion in the present simulations agrees well with the experimental results. It is observed that protein adsorption can be controlled using electrokinetic phenomena. The plug-like flow profile in electrokinetics is beneficial for a microparticle at every spatial location in the microchannel, whereas it is not valid for the pressure-driven flow. The electric field strength and the zeta potential of the particle accelerate the protein adsorption. The wall shear stress and shear rate are good indicators to predict the adsorption process for electrokinetic flow. 相似文献
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A new carbon film deposition technique, based upon excimer laser vaporization of graphite in a flowing gas system has been developed. The low temperature vapor (LTV) technique alleviates high temperatures occurring in most other deposition methods. In this technique the UV laser ablation occurs in an inert flowing gas atmosphere. Atoms and molecules evaporated from graphite are cooled by gas entrainment before condensing on a substrate. The resulting films of amorphous carbon or hydrogenated amorphous carbon are free from strain. Measurement of the optical band gap of these films shows that Eg can be controlled by the hydrogen content of the carrier gas. 相似文献
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In optimum design of tuned mass dampers (TMD), several factors are effective. One of the most important factors is the characteristics of the excitation. Earthquake excitations recorded at soil and rock sites show different characteristics in period and damping. In this paper, optimum TMD properties are separately searched for seismic structures at soil sites and rock sites. For each optimization, six different earthquake records were used. A design methodology was used by employing harmony search (HS). The approach was applied to a ten story structure with one second critical period. Although more damping ratio for TMD is needed for soil sites than rock sites, TMD is more effective for rock sites than soil sites. (© 2014 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
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Slenderness is an important issue in design of reinforced concrete (RC) columns. Especially for long columns, second order effects may be not so small to neglect, but the calculation of second order effects may take too much time. For that reason, ACI 318 design code includes a simple approach in order to increase the flexural moment of columns according to their slenderness. Thus, second order effects are considered. In optimization, the effect of slenderness can be considered by using the factored design flexural moments. In this paper, harmony search (HS) algorithm is employed to find the optimum design variables of slender RC columns. These design variables are web width, height, diameter and number of reinforcements. The optimization objective is total cost of materials including concrete and steel. The developed method is effective to find the optimal design for axial force, flexural moment and shear force values. As numerical examples, optimum design of columns with different lengths, but with the same loadings and material properties were investigated. Thus, the effect of slenderness was seen on the optimum costs. By the increase of column length, increase of total material cost is more than a linear increase. This situation shows us the effect of slenderness on optimum RC columns (© 2014 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
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In structural mechanics, when the design contains two different materials with opposite mechanical behaviours and costs, the optimum design cannot exactly found. In that case, numerical optimization algorithms are a good source. Reinforced concrete design shows that behaviour since concrete is a cheap material comparing to steel while the tensile strength of concrete is very low to use. The cross sections are effective on the stresses and balance of tensile and compressive forces. This situation shows the importance of the dimension optimization of reinforced concrete members. Also, the number and size of the reinforcements need an optimization. The place of the reinforcements is effective on the place of tensile forces in the calculation of axial force and flexural moment capacity. In this paper, reinforced concrete columns are optimized for the cost minimization by employing a bio-inspired metaheuristic algorithm called bat algorithm. The idealization of the echolocation behaviour of bats is the inspiration of the bat algorithm. Differently from the algorithms, the bat algorithm uses global and local optimization with a changeable probability. The optimization process considers the security measures and slenderness of the according to the design regulation called ACI 318. The slenderness is taken into consideration by using a magnified design flexural moment, which is factored by a value defined according to the buckling load and axial load of columns. The proposed approach is applied for different numerical cases and the results are compared with the approach using harmony search algorithm. The present approach is effective for the optimization problem. (© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
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Üçüncü M Karakuş E Kuş M Akpınar GE Aksın-Artok Ö Krause N Karaca S Elmacı N Artok L 《The Journal of organic chemistry》2011,76(15):5959-5971
Two methods involving the rhodium-catalyzed reaction of 2-en-4-yne acetates and the palladium-catalyzed reaction of 2-en-4-yne carbonates with organoboronic acids were investigated; both afforded exclusively the (E)-configured vinylallenes. The coordinative interaction of the rhodium with the acetate group promoted the δ-elimination of Rh(I)-OAc from the alkenylrhodium intermediate II in both syn and anti modes, with the syn-elimination being the major path. DFT calculations revealed that a conformer of this intermediate (II), which can lead to the (E)-configured vinylallene product via the syn-elimination mode, is energetically the most favorable conformer. The rhodium-catalyzed procedure is not applicable to reactions involving (E)-configured enyne acetates, because the geometry of the alkenylrhodium intermediate that is derived from the corresponding (E)-enyne acetate would not allow such coordinative interaction to occur. The palladium-catalyzed method, which proceeds through formation of the σ-vinylallenylpalladium intermediate, B, is suitable for both the (E)- and (Z)-configured enyne carbonates and appears to have a wider scope for both organoboronic acids and enyne substrates. The palladium-catalyzed reaction of an enantiomerically enriched enyne carbonate proceeded with racemization. 相似文献
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Seyhmus Gunes Osman Ulkir Melih Kuncan 《Journal of polymer science. Part A, Polymer chemistry》2024,62(9):1864-1889
Additive manufacturing (AM) has begun to replace traditional fabrication because of its advantages, such as easy manufacturing of parts with complex geometry, and mass production. The most important limitation of AM is that dimensional accuracy cannot be achieved in all parts. Dimensional accuracy is essential for high reliability, high performance, and useful final products. This study investigates the impact of printing parameters on the dimensional accuracy of samples fabricated through fused deposition modeling (FDM), an additive manufacturing (AM) method utilizing polylactic acid (PLA) material. The experimental design process was performed using Taguchi methodology. ANOVA was used to determine the most important parameter affecting accuracy. Based on experimental studies, the optimal printing parameters for parts are determined as follows: concentric infill pattern, 3 mm wall thickness, 70% infill density, and a layer thickness of 200 μm. Artificial neural network (ANN) was used in the evaluation and prediction of the results. The R-square (R2) performance evaluation criterion was above 95% from the ANN results. This value shows that the results are significant. The data acquired from this study may assist in identifying optimal parameters that contribute to the fabrication of samples with high dimensional accuracy using the FDM method. 相似文献
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M. Emin Günay Nam?k Özdemir Melih Uçak Bekir Çetinkaya 《Journal of organometallic chemistry》2009,694(14):2179-3680
Deprotonation of 1,3-diorganyl imidazolinium salts, 1, with N,C-type palladacyclic acetate dimer 2 afforded novel NHC coordinated complexes 3 along with ring opening hydrolysis products 4, which may coordinate to palladium center via NH group to give 5a. The hydrolysis necessitates the study of NHC complex formation in anhydrous media. The new compounds were characterized by spectroscopic methods and three of them (3c, 4c, 5a) by X-ray single-crystal diffraction studies. 相似文献
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In this paper we develop a general approach to generate all non-dominated solutions of the multi-objective integer programming (MOIP) Problem. Our approach, which is based on the identification of objective efficiency ranges, is an improvement over classical ε-constraint method. Objective efficiency ranges are identified by solving simpler MOIP problems with fewer objectives. We first provide the classical ε-constraint method on the bi-objective integer programming problem for the sake of completeness and comment on its efficiency. Then present our method on tri-objective integer programming problem and then extend it to the general MOIP problem with k objectives. A numerical example considering tri-objective assignment problem is also provided. 相似文献