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1.
The treatment of the non-linear isotherm in chromatography by one of the authors [1] is extended to other cases of practical interest. The original paper dealt with the case of an initially thin zone resulting in a Poisson distribution the asymmetry of which is a function of the plate number and the non-linearity constant. The present work shows that the same relations apply to initially thick zones and to the cases of washing and deposition leading to simple relations for breakthrough curves. For significantly non-linear isotherms other quasi-Gaussian distributions can give a better fit. 相似文献
2.
Al-Ali F Déjugnat C Etemad-Moghadam G Rico-Lattes I 《Journal of colloid and interface science》2004,273(2):512-516
Monolayers of amphiphilic (alpha-amino)phosphonocarboxylic and (alpha-amino)phosphonic acids have been formed by adsorption at the air/water interface. The influence of both the ionic strength and the pH of the subphase on the stability and compactness of the monolayers have been studied. The stability and the compactness of the Langmuir films are enhanced by introduction of metallic ions such as Ca(2+) or Mg(2+) in the subphases. These effects are more pronounced with Ca(2+). These metal ions can form dimeric complexes with the phosphorus moieties of the surfactant polar heads and therefore bring the amphiphiles closer. For the less hydrophobic derivative, complexation with Ca(2+) or Mg(2+) is required to ensure the formation of a stable monomolecular film. For both phosphonocarboxylic and phosphonic compounds, models have been proposed to represent the complexation phenomenon at the air/water interface. 相似文献
3.
4.
Mashhour Al-Ali Bani-Ata Christoph Hering Anni Neumann Aymen Rawashdeh 《Journal of Geometry》2007,86(1-2):1-5
The purpose of this paper is to prove the existence of semifields of order q
4 for any odd prime power q = pr, q > 3, admitting a free automorphism group isomorphic to Z
2 × Z
2. 相似文献
5.
This paper considers the structure of weakly nonlinear steady-state convection patterns in shallow rectangular planform containers heated from below. The lateral dimensions of the container are assumed to be much larger than the characteristic wavelength of convection, and the lateral boundaries are subject to forcing equivalent, for example, to imperfect thermal insulation in the Rayleigh–Benard problem. This has the effect of generating rolls parallel and perpendicular to the lateral boundaries. The resulting patterns are modelled by a coupled pair of nonlinear amplitude equations derived from a phenomenological model of convection introduced by Swift and Hohenberg [Phys. Rev. A15 (1977) 319]. These equations are applicable in the weakly nonlinear limit to a variety of pattern-forming systems such as the Rayleigh–Benard system. Solutions are found using both numerical and asymptotic methods. The boundary imperfection is shown to give rise to some novel effects, including the possibility of patterns containing square cells. More generally, patterns evolve that are dominated by rolls but with transitions to more complex bimodal forms near the edges of the container. The emergence and structure of transition lines, or grain boundaries, is analysed in detail. 相似文献
6.
The aim of this article is to investigate the autotopism group of a semifield of order p 4, p is an odd prime, admitting a four-group of automorphisms E? Z 2 × Z 2 acting freely on A. 相似文献
7.
In this paper we examine the Akian, Menaldi and Sulem (1996) model for the optimal management of a portfolio, when there are transaction costs which are equal to a fixed percentage of the amount transacted. We analyse this model in the realistic limit of small transaction costs. Although the full problem is a free boundary diffusion problem in as many dimensions as there are assets in the portfolio, we find explicit solutions for the optimal trading policy in this limit. This makes the solution for a realistically large number of assets a practical possibility. 相似文献
8.
Masoumah Al-Ali 《Journal of Pure and Applied Algebra》2019,223(12):5430-5443
Let be a simple, finite-dimensional complex Lie algebra, and let denote the universal affine vertex algebra associated to at level k. The Cartan involution on lifts to an involution on , and we denote by the orbifold, or fixed-point subalgebra, under this involution. Our main result is an explicit minimal strong finite generating set for for generic values of k. 相似文献
9.
Ismail Warad Maha Al-Ali Belkheir Hammouti Taibi Ben Hadda Rami Shareiah Mohamed Rzaigui 《Research on Chemical Intermediates》2013,39(6):2451-2461
A novel di-μ-chloro-bis[chloro(4,7-dimethyl-1,10-phenanthroline)cadmium(II)] dimer complex has been prepared by reacting CdCl2·2.5H2O with 4,7-dimethyl-1,10-phenanthroline (dmphen) ligand. The complex was characterized on the basis of elemental analysis, FAB-MS, IR, UV–visible, 1H, and 13C NMR spectroscopy, TG/DTA, and X-ray single-crystal diffraction studies. The Cd(II) ions in [CdCl2(C14H12N2)]2 are coordinated to three Cl atoms with the centrosymmetric dimer bridged through the Cl atoms and two N atoms in a slightly distorted square-pyramidal disposition. Several hydrogen bonds formed between the terminal Cl atoms and H-Me/H-Ph groups may stabilize the structure in the dimer form. 相似文献
10.
The concentration of HOD in biological fluids is measured by using vacuum distillation, followed by infrared spectrophotometry. 相似文献