Selected action density to speed up the computation of the nonlinear wave-wave interactions

This paper deals with the development of a numerical method to study the non-linear wave-wave interactions in oceans. Based on works from Webb-Tracy-Resio, the Hasselmann’s non-linear mathematical model is reviewed numerically. With this theory and the selection of action density domain, a program to reduce time of computation has been developed. Results from new computation are displayed graphically and compared with previous program. This work augments our understanding better about the non-linear process of wave-wave interactions and it improves the numerical computations to obtain efficiency in operational forecast.     

Transfection mediated by gemini surfactants: engineered escape from the endosomal compartment

The structure of the lipoplex formed from DNA and the sugar-based cationic gemini surfactant 1, which exhibits excellent transfection efficiency, has been investigated in the pH range 8.8-3.0 utilizing small-angle X-ray scattering (SAXS) and cryo-electron microscopy (cryo-TEM). Uniquely, three well-defined morphologies of the lipoplex were observed upon gradual acidification: a lamellar phase, a condensed lamellar phase, and an inverted hexagonal (H(II)) columnar phase. Using molecular modeling, we link the observed lipoplex morphologies and physical behavior to specific structural features in the individual surfactant, illuminating key factors in future surfactant design, viz., a spacer of six methylene groups, the presence of two nitrogens that can be protonated in the physiological pH range, two unsaturated alkyl tails, and hydrophilic sugar headgroups. Assuming that the mechanism of transfection by synthetic cationic surfactants involves endocytosis, we contend that the efficacy of gemini surfactant 1 as a gene delivery vehicle can be explained by the unprecedented observation of a pH-induced formation of the inverted hexagonal phase of the lipoplex in the endosomal pH range. This change in morphology leads to destabilization of the endosome through fusion of the lipoplex with the endosomal wall, resulting in release of DNA into the cytoplasm.     

Dithiacrown Ether Substituted Porphyrazines: Synthesis, Single-Crystal Structure, and Control of Aggregation in Solution by Complexation of Transition-Metal Ions

The synthesis of novel magnesium, copper, and metal-free porphyrazines, peripherally substituted with dithia-7-crown-2 (MPz(7)), dithia-15-crown-5 (MPz(15)), and dithia-18-crown-6 (MPz(18)) macrocycles is reported. These compounds are prepared starting from dicyanoethylene containing crown ethers 3, 2(1), and 2(2), respectively, which contain sulfur as well as oxygen heteroatoms. The "crowned" porphyrazines bind silver(I) and mercury(II) perchlorates. UV/vis spectroscopy and electron paramagnetic resonance measurements reveal that addition of the transition-metal ions leads to dimerization of the porphyrazine complexes. In the case of the dithia-18-crown-6-substituted porphyrazines, the dimers break up to form monomeric 6:1 guest-host complexes when more than 2 equiv of the metal ion is added. The single-crystal structures of the crown ether 2(2) and the porphyrazine MgPz(18) are presented. Compound C(14)H(20)N(2)O(4)S(2) (2(2)) crystallizes in the monoclinic space group P2(1)/c with a = 10.9310(13) ?, b = 19.383(3) ?, c = 8.6976(14) ?, beta = 108.898(11) degrees, V = 1743.5(5) ?(3), and Z = 4. The structure refinement converged to R = 0.0366 and R(w) = 0.0504. Compound C(56)H(82)MgN(8)O(17)S(8) (MgPz(18)) crystallizes in the triclinic space group P&onemacr; with a = 9.584(3) ?, b = 17.672(2) ?, c = 19.620(4) ?, alpha = 84.904(14) degrees, beta = 85.21(2) degrees, gamma = 89.29(2) degrees, V = 3298.4(13) ?(3), and Z = 2. The structure refinement converged to R1 = 0.0839 and wR2 = 0.2196. The electrical properties of H(2)Pz(18) have been studied by complex impedance spectroscopy. The bulk electrical conductivity of this compound is approximately 1 order of magnitude higher than that of the corresponding 18-crown-6 phthalocyanine.     

Dielectrophoretically Modulated Optical Spectroscopy of Colloidal Nanoparticle Solutions in Microfluidic Channels

Optical spectroscopic techniques (e.g., extinction, scattering, and fluorescence spectroscopies) are important for the analysis of colloidal solutions of nanoparticles (NPs). They are routinely applied to plasmonic and quantum-dot NP samples assuming that these contain a single population of particles with modest size and shape dispersity. However, these spectroscopic techniques become less effective when the sample is a mixture of particles with different sizes, shapes, or composition. Here, an original microfluidic method is proposed for the optical spectroscopic analysis of colloidal NP solutions that combines periodic trapping of NPs by dielectrophoresis (DEP) with in situ optical extinction spectroscopy. The periodic trapping leads to modulation of the continuously monitored optical spectrum depending on the DEP properties of the NPs. DEP-modulated spectroscopy is demonstrated using colloidal gold NPs as small as 40 nm diameter. It is found that the DEP modulation is significantly enhanced when employing suitable microfluidic flow over a multielectrode array. Finally, it is shown that the method can identify and characterize the NP species simultaneously present in a mixture of 40 and 80 nm gold NPs, opening the way toward optical spectroscopic analysis of higher complexity NP mixtures through the combination of the DEP-modulated spectroscopy with chemometric methods.     

Dirichlet product for boolean functions

Boolean functions play an important role in many symmetric cryptosystems and are crucial for their security. It is important to design boolean functions with reliable cryptographic properties such as balancedness and nonlinearity. Most of these properties are based on specific structures such as Möbius transform and Algebraic Normal Form. In this paper, we introduce the notion of Dirichlet product and use it to study the arithmetical properties of boolean functions. We show that, with the Dirichlet product, the set of boolean functions is an Abelian monoid with interesting algebraic structure. In addition, we apply the Dirichlet product to the sub-family of coincident functions and exhibit many properties satisfied by such functions.     

Analytical Modeling of Nonaqueous Phase Liquid Dissolution with Green's Functions

Equilibrium and bicontinuum nonequilibrium formulations of the advection–dispersion equation (ADE) have been widely used to describe subsurface solute transport. The Green's Function Method (GFM) is particularly attractive to solve the ADE because of its flexibility to deal with arbitrary initial and boundary conditions, and its relative simplicity to formulate solutions for multidimensional problems. The Green's functions that are presented can be used for a wide range of problems involving equilibrium and nonequilibrium transport in semiinfinite and infinite media. The GFM is applied to analytically model multidimensional transport from persistent solute sources typical of nonaqueous phase liquids (NAPLs). Specific solutions are derived for transport from a rectangular source (parallel to the flow direction) of persistent contamination using first, second, or thirdtype boundary or source input conditions. Away from the source, the first and thirdtype condition cannot be expected to represent the exact surface condition. The secondtype condition has the disadvantage that the diffusive flux from the source needs to be specified a priori. Near the source, the thirdtype condition appears most suitable to model NAPL dissolution into the medium. The solute flux from the pool, and hence the concentration in the medium, depends strongly on the mass transfer coefficient. For all conditions, the concentration profiles indicate that nonequilibrium conditions tend to reduce the maximum solute concentration and the total amount of solute that enters the porous medium from the source. On the other hand, during nonequilibrium transport the solute may spread over a larger area of the medium compared to equilibrium transport.     

An assessment of the high frequency boundary element and Rayleigh integral approximations

This paper revisits the popular Rayleigh integral approximation and also considers a second approximation, the high frequency boundary element method, which is similar to the Rayleigh integral. The Rayleigh integral approximation under consideration is enhanced so that only the elements visible to a particular point in the field are used to calculate the sound pressure at that point. It is demonstrated how both the Rayleigh integral and high frequency boundary element method are approximations to the boundary integral equation so that similarities between the two methods are recognized. Several test cases were conducted in order to assess and compare both methods. The first set of test cases was the pulsating and oscillating sphere. Both methods were then compared on more applied examples including a running engine, construction cab, and transmission housing. It was concluded that though both methods can reliably predict the sound power for some problems, the high frequency boundary element method is the more robust.     

Quenching of molecular fluorescence on the surface of monolayer-protected gold nanoparticles investigated using place exchange equilibria

The insertion of fluorescently labeled thiols into the protecting self-assembled monolayer on the surface of gold nanoparticles through place exchange reactions and the effects of this insertion on the photophysical properties of the fluorophores are investigated. Analysis of solution-phase fluorescence data using a dynamic equilibrium model yields the equilibrium constant for the place exchange equilibrium, as well as the relative fluorescence brightness of the fluorophores on the particle surface. In all cases we find a significant quenching of the fluorescence, and potential reasons for this quenching are discussed. In the case of these relatively small particles (4.5 nm diameter), the quenching appears to be mainly related to enhanced nonradiative deactivation pathways. The place exchange equilibrium constant reveals a reduced affinity of the fluorescently labeled thiols for insertion into the nonfluorescent alkylthiol monolayer (K(eq) approximately 0.2) compared to unlabeled alkylthiols.     

Advanced Control Design for Wind Turbines

In this contribution, the concept of a general design platform for control system of wind turbines is proposed. Different models of wind turbine systems are summarized, a novel control strategy for wind turbine control is proposed as a general platform for control system design. Simulation results are presented demonstrating the success of the proposed control method based on one of the chosen models for the design platform. A benchmark model (NREL) is chosen for the platform in order to adjust the control system design. Finally, the design process of control system based on the general platform is given and explained. (© 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Foam films in the presence of functionalized gold nanoparticles

Dry aqueous foams made of anionic surfactant (SDS) and spherical gold nanoparticles are studied by small angle X-ray scattering and by optical techniques. To obtain stable foams, the surfactant concentration is well above the critical micelle concentration. The specular reflectivity signal obtained on a very thin film (thickness 20 nm) shows that functionalized nanoparticles (17 nm typical size) are trapped within the film in the form of a single monolayer. In order to isolate the film behavior, investigations are made on a single film confined in a tube. The film thinning according to the ratio of functionalized nanoparticle and SDS micelles (1:1, 1:10, 1:100) is mainly governed by the structural arrangement of SDS micelles. In thick films, nanoparticles tend to form aggregates that disappear during drainage. In particular self-organization of nanoparticles (with different surface charge) inside the film is not detected.