全文获取类型
收费全文 | 1267篇 |
免费 | 53篇 |
国内免费 | 7篇 |
专业分类
化学 | 879篇 |
晶体学 | 2篇 |
力学 | 35篇 |
数学 | 225篇 |
物理学 | 186篇 |
出版年
2023年 | 7篇 |
2022年 | 23篇 |
2021年 | 31篇 |
2020年 | 47篇 |
2019年 | 40篇 |
2018年 | 20篇 |
2017年 | 33篇 |
2016年 | 49篇 |
2015年 | 35篇 |
2014年 | 37篇 |
2013年 | 89篇 |
2012年 | 89篇 |
2011年 | 99篇 |
2010年 | 56篇 |
2009年 | 51篇 |
2008年 | 65篇 |
2007年 | 61篇 |
2006年 | 60篇 |
2005年 | 44篇 |
2004年 | 30篇 |
2003年 | 28篇 |
2002年 | 35篇 |
2001年 | 10篇 |
2000年 | 18篇 |
1999年 | 8篇 |
1998年 | 8篇 |
1997年 | 17篇 |
1996年 | 8篇 |
1994年 | 10篇 |
1993年 | 11篇 |
1992年 | 11篇 |
1991年 | 9篇 |
1990年 | 14篇 |
1989年 | 10篇 |
1988年 | 5篇 |
1986年 | 6篇 |
1985年 | 10篇 |
1984年 | 9篇 |
1983年 | 5篇 |
1981年 | 7篇 |
1980年 | 9篇 |
1978年 | 7篇 |
1977年 | 8篇 |
1976年 | 14篇 |
1975年 | 4篇 |
1973年 | 4篇 |
1970年 | 6篇 |
1961年 | 4篇 |
1957年 | 4篇 |
1905年 | 4篇 |
排序方式: 共有1327条查询结果,搜索用时 15 毫秒
1.
Interactions of Pt‐ttpy with G‐Quadruplexes Originating from Promoter Region of the c‐myc Gene Deciphered by NMR and Gel Electrophoresis Analysis
下载免费PDF全文
![点击此处可从《Chemistry (Weinheim an der Bergstrasse, Germany)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
2.
Marko Nedeljkov 《Mathematical Methods in the Applied Sciences》2004,27(8):931-955
This work gives a condition for existence of singular and delta shock wave solutions to Riemann problem for 2×2 systems of conservation laws. For a fixed left‐hand side value of Riemann data, the condition obtained in the paper describes a set of possible right‐hand side values. The procedure is similar to the standard one of finding the Hugoniot locus. Fluxes of the considered systems are globally Lipschitz with respect to one of the dependent variables. The association in a Colombeau‐type algebra is used as a solution concept. Copyright © 2004 John Wiley &Sons, Ltd. 相似文献
3.
The NH,NH-dihydrocycloadduct 1 (6-chloro-9,9-dimethyl-7,8-dihydro-9H-pyrazolo[4,3-d]tetrazolo[1,5-b]-pyridazine) obtained by the cycloaddition of 2-diazopropane to 6-chlorotetrazolo[1,5-b]pyridazine, is transformed with protected or unprotected carbohydrates 2, 5, 7,9, 11, 13 and 15 in the presence of methyl acrylate ( 3 ) into the corresponding C-nucleosides 4,6,8,10,12,14 and 16 . In this one-pot synthesis two new chiral centers are formed stereoselectively, dependent on the chirality at C-atom next to aldehydo group in the carbohydrate. 相似文献
4.
5.
Marko D. Mihovilovic Bernhard Müller Markus Spina Arjumand I. Durrani Peter Stanetty Georg Dazinger Karl Kirchner 《Monatshefte für Chemie / Chemical Monthly》2006,137(6):785-794
Summary. Recombinant Escherichia coli overexpressing Pseudomonas sp. NCIMB 9872 cyclopentanone monooxygenase (CPMO, EC 1.14.13.16) and Acinetobacter sp. NCIMB 9871 cyclohexanone monooxygenase (CHMO, EC 1.14.13.22) have been utilized in whole-cell Baeyer-Villiger biotransformations of prochiral bicycloketones. A significant difference in substrate acceptance and stereoselectivity was
observed for bicyclo[3.3.0] and bicyclo[4.3.0] substrates. A plausible mechanism of these transformations was established
by means of high level DFT/B3LYP calculations suggesting an essential difference in electronic requirements for a successful
enzymatic conversion, which was similarly encountered in recombinant whole-cell mediated biooxidations. Some of the lactones
produced in the biocatalytic Baeyer-Villiger oxidation represent key intermediates for the synthesis of indole alkaloids. 相似文献
6.
7.
Boris‐Marko Kukovec Zora Popovi Gordana Pavlovi 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(9):m389-m391
In the title compound, [Cd(C7H6NO2)2]n, the CdII ion has a distorted octahedral geometry. The 6‐methylpyridine‐2‐carboxylate anions are perpendicular to one another and act as bidentate and bridging ligands. Two carboxylate O atoms bridge the CdII ions, forming centrosymmetric dinuclear units. These units are further connected via carboxylate O atoms into a one‐dimensional polymeric chain which extends in the [100] direction. 相似文献
8.
9.
M Riedel 《Journal of multivariate analysis》1985,16(2):241-252
Let X1, X2,…, be independent, identically distributed random variables. Suppose that the linear forms L1 = Σj=1∞ajXj and L2 = Σj=1∞bjXj exist with probability one and are identically distributed; necessary and sufficient conditions assuring that X1 is normally distributed are presented. The result is an extension of a theorem of Linnik (Ukrainian Math. J.5 (1953), 207–243, 247–290) concerning the case that the linear forms L1 and L2 have a finite number of nonvanishing components. This proof only makes use of elementary properties of characteristic functions and of meromorphic functions. 相似文献
10.
I. Kúdelka P.K. Misro J. Pospíšil H. Korbanka T. Riedel G. Pfahler 《Polymer Degradation and Stability》1985,12(4):303-313
The hydroperoxide decomposing efficiencies of dioctadecylsulfide (I), dioctadecyldisulfide (IV) and dioctadecyl 3,3-thio-dipropionate (VII) have been compared at 75°C and 85°C. The formation of oxidation products from (I) and (IV) has been checked. Experimental evidence is given of the important rôle of the activation of the molecule of (IV) by the presence of two sulfidic sulfur atoms compared with the activation of the sulfur atom in (VII) by the alkoxycarbonyl group in the beta position. The explanation of the high efficiency of disulfide has been based on the formation of thiosulfinate—the key intermediate for the generation of peroxidolytic species—in the first reaction step. 相似文献