全文获取类型
收费全文 | 109篇 |
免费 | 6篇 |
专业分类
化学 | 86篇 |
力学 | 2篇 |
数学 | 10篇 |
物理学 | 17篇 |
出版年
2022年 | 1篇 |
2021年 | 2篇 |
2019年 | 1篇 |
2018年 | 1篇 |
2016年 | 4篇 |
2015年 | 2篇 |
2014年 | 3篇 |
2013年 | 8篇 |
2012年 | 3篇 |
2011年 | 4篇 |
2010年 | 5篇 |
2009年 | 5篇 |
2008年 | 6篇 |
2007年 | 6篇 |
2006年 | 6篇 |
2005年 | 1篇 |
2004年 | 2篇 |
2003年 | 3篇 |
2002年 | 6篇 |
2001年 | 2篇 |
2000年 | 2篇 |
1999年 | 2篇 |
1997年 | 1篇 |
1995年 | 1篇 |
1993年 | 3篇 |
1992年 | 3篇 |
1991年 | 3篇 |
1990年 | 4篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1987年 | 3篇 |
1986年 | 1篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1982年 | 3篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1978年 | 3篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1974年 | 2篇 |
排序方式: 共有115条查询结果,搜索用时 15 毫秒
1.
H. Fawcett S. Barlag H. Becker E. Belau T. Böhringer M. Bosman V. Castillo V. Chabaud D. Bucholz C. Damerell C. Daum G. De Rijk H. Dietl S. Gill A. Gillman R. Gilmore T. Gooch P. Gras Z. Hajduk E. Higon B. Hyams D. Kelsey J. Kemmer R. Klanner U. Kötz S. Kwan B. Lücking G. Lütjens G. Lutz J. Malos W. Männer E. Neugebauer H. Palka M. Pepé G. Polok J. Richardson M. Rozanska K. Rybicki H. Seebrunner U. Stierlin R. Tapper H. Tiecke M. Turala G. Waltermann S. Watts P. Weilhammer F. Wickens L. Wiggers A. Wylie T. Zeludziewicz ACCMOR Collaboration 《Zeitschrift fur Physik C Particles and Fields》1990,46(4):513-519
The production of the neutralK ? (892) resonances by 200 GeVK ? andπ ? has been studied over the kinematic range 0.0<x f<1.0 andp t 2 <5.0 GeV2. Longitudinal and transverse momentum distributions are presented. In addition the decay angular distributions inK ? fragmentation to \(\bar K^{0*} \) have been investigated. 相似文献
2.
S. Barlag H. Becker T. Böhringer M. Bosman V. Castillo V. Chabaud D. Buchholz C. Damerell C. Daum H. Dietl H. Fawcett S. Gill A. Gillman R. Gilmore T. Gooch L. Görlich P. Gras Z. Hajduk E. Higon B. D. Hyams D. P. Kelsey J. Kemmer R. Klanner U. Kötz S. Kwan B. Lücking G. Lütiens G. Lutz J. Malos W. Männer E. Neugebauer H. Palka M. Pepé J. Richardson G. De Rijk K. Rybicki H. J. Seebrunner U. Stierlin H. G. Tiecke M. Turala G. Waltermann S. Watts P. Weilhammer F. Wickens L. W. Wiggers A. Wylie T. Zeludziewicz ACCMOR Collaboration 《Zeitschrift fur Physik C Particles and Fields》1987,37(1):17-23
We have measured the lifetimes of hadronically produced charged and neutralD mesons using silicon microstrip detectors and an active silicon target in the NA32 spectrometer at the CERN SPS. We obtainτ D± = (10.9± 1.5 1.9 )·10?13s andτ D (?)10 = (4.2±0.5)·10?13s based on 59 and 90 fully reconstructed decays respectively, giving a ratioτ D±/τ D (?)10 of 2.6 ±0.5. 相似文献
3.
N. Gras L. Munoz M. Thieck S. Hurtado 《Journal of Radioanalytical and Nuclear Chemistry》1993,169(1):247-253
Levels of essential and toxic trace elements in six marine species greatly in demand in the international market (canned pink clams, razor clams, clams, king crab, sardines, and frozen albacore tuna fish) were studied. A special laboratory adequately equipped for handling and preparing biological materials, is described. The elements As, Br, Na, Se, Hg, Cr, Fe, Zn and Rb were determined by INAA, while copper and cadmium content were determined using RNAA. Significant differences were found on comparing the contents of some toxic elements in mollusk and other samples of marine food. Various certified reference materials (CRMs) of the IAEA, NIST and NIES were analyzed for quality assurance purposes. 相似文献
4.
In gas chromatography (GC), highly volatile liquefied hydrocarbons are commonly injected using devices such as high-pressure syringes, piston valves, liquid rotary sampling valves, or vaporizing regulators. Although these techniques are adequate in some cases, there are known deficiencies. A new generation of sampling valve has been recently innovated and commercialized. Some of the highlights of the pressurized liquid injection system (PLIS) include compact size, the capability to directly couple to an injection port without the need for preinjection vaporization and transfer lines, and sample sizes ranging from 0.2 to 2.0 micro L. Although the valve has a specification of helium leak-free rating of 82.7 bar (1200 psig), the valve passes a hydrostatic pressure test of up to 414 bar (6000 psig). In the unheated version of PLIS, vaporization of solutes occur mainly because of the sheering effect of carrier gas in combination with thermal energy drawn from an injection port or a heated adaptor. This was found to be adequate for solutes with high to medium volatility of up to nC14 hydrocarbon. A higher molecular weight range of up to nC44 hydrocarbon can be achieved with the implementation of a heated version of PLIS, in which the channel of the shaft can be resistively heated at a rate of up to 400 degrees C/s. With its first introduction in May 2002, PLIS has gained acceptance amongst practitioners in GC because it addresses a key unarticulated need in sample introduction/enrichment and by specifically targeting many deficiencies encountered in contemporary high-pressure injection devices. In this paper, the design and performance of the various valve systems of PLIS, as well as industrial chromatographic applications, is presented. 相似文献
5.
E. Cortés N. Gras L. Muñoz V. Cassorla 《Journal of Radioanalytical and Nuclear Chemistry》1982,69(1-2):401-415
Seven trace elements were determined in milk formulas, powder milk and infant food. Instrumental neutron activation analysis
was used for the analysis of Fe, Zn, Co, Cr and Rb, while As and Cu content was determined using radiochemical neutron activation
analysis. Differences were found in the trace element content of foods of the same type. Milk formulas are comparable with
human milk according to the results obtained for the elements analyzed. The samples of powder cow's milk presented similar
concentrations of the elements studied. Liver with vegetables was found to have the highest Cu content. A meal prepared at
home, made of beef and fresh vegetables showed a higher trace element content than its similar commercial one. An estimation
of the daily intake of the elements analyzed was made and compared with minimum recommended daily ingestion. 相似文献
6.
S. Barlag H. Becker A. Bożek T. Böhringer M. Bosman V. Castillo V. Chabaud C. Damerell C. Daum H. Dietl A. Gillman R. Gilmore T. Gooch L. Görlich P. Gras Z. Hajduk E. Higon D. P. Kelsey R. Klanner S. Kwan B. Lücking G. Lütjens G. Lutz J. Malos W. Männer E. Neugebauer H. Pałka M. Pepé J. Richardson K. Rybicki H. J. Seebrunner U. Stierlin H. G. Tiecke G. Waltermann S. Watts P. Weilhammer F. Wickens L. W. Wiggers M. Witek T. Zeludziewicz 《Zeitschrift fur Physik C Particles and Fields》1992,55(3):383-390
We combine highly complementary information on branching fractions of charmed mesonsD 0,D + andD s + coming from two experiments both yielding doublecharm samples. The NA 32 experiment provided exclusive branching fractions for channels with at least two charged decay products while a recent Mark III paper provides results on inclusive charm decay properties. The knowledge of channels withK 0's in the former is used to recalculate the charged multiplicity distribution in the latter. We obtain 〈n ch〉=2.25±0.08 forD 0, 〈n ch〉=1.96±0.08 forD + and 〈n ch〉=2.41±0.38 forD s + . In turn the knowledge of the charged multiplicity improves the overall normalization of exclusive branching fractions. This reanalysis yields model-independent results for charmed mesons. In particular we obtain branching fractions for 16D s + decay channels including $$BF(D_s^ + \to \phi \pi ^ + ) = \left( {4.4\begin{array}{*{20}c} { + 2.3} \\ { - 1.8} \\ \end{array} } \right)\% .$$ . 相似文献
7.
S. Barlag H. Becker T. Böhringer M. Bosman V. Castillo V. Chabaud C. Damerell C. Daum H. Dietl A. Gillman R. Gilmore T. Gooch L. Görlich P. Gras Z. Hajduk E. Higon D. P. Kelsey R. Klanner S. Kwan B. Lücking G. Lütjens G. Lütz J. Malos W. Männer E. Neugebauer H. Palka M. Pepé J. Richardson K. Rybicki H. J. Seebrunner U. Stierlin H. G. Tiecke G. Waltermann S. Watts P. Weilhammer F. Wickens L. W. Wiggers M. Witek T. Zeludziewicz 《Zeitschrift fur Physik C Particles and Fields》1991,49(4):555-562
We have studied the hadronic production of charmed mesons in the NA 32 experiment at CERN. A special trigger together with a high resolution vertex detector consisting of charge coupled devices and silicon microstrip detectors allowed the selection of very clean samples of charmed mesons. We have collected 852 fully reconstructed decays: 60D s + →K + K ?π+, 543D°→K ?π+ andK ?π+π?π+ as well as 249D +→K ?π+π+ (or charge conjugate). 147 mesons out of our \({{D^0 } \mathord{\left/ {\vphantom {{D^0 } {\bar D^0 }}} \right. \kern-0em} {\bar D^0 }}\) sample were produced via chargedD * state. For all charmed mesons we determine the total production cross-section and study thex F andp t 2 distributions. 相似文献
8.
Hodgson DM Buxton TJ Cameron ID Gras E Kirton EH 《Organic & biomolecular chemistry》2003,1(23):4293-4301
Enantioselective alpha-deprotonation of achiral epoxides 1, 21, and 26 using organolithiums in the presence of (-)-sparteine 2 and subsequent electrophile trapping gives access to enantioenriched trisubstituted epoxides 9-17, 22, 23, 27 and 28 (in up to 86% ee). 相似文献
9.
An integrated gas chromatographic system has been successfully developed and implemented for the measurement of oxygen, nitrogen, carbon monoxide, carbon dioxide and light hydrocarbons in one single analysis. These analytes are frequently encountered in critical industrial petrochemical and chemical processes like catalytic cracking of naphtha or diesel fuel to lighter components used in gasoline. The system employs a practical, effective configuration consisting of two three-port planar microfluidic devices in series with each other, having built-in fluidic gates, and a mid-point pressure source. The use of planar microfluidic devices offers intangible advantages like in-oven switching with no mechanical moving parts, an inert sample flow path, and a leak-free operation even with multiple thermal cycles. In this way, necessary features such as selectivity enhancement, column isolation, column back-flushing, and improved system cleanliness were realized. Porous layer open tubular capillary columns were employed for the separation of hydrocarbons followed by flame ionization detection. After separation has occurred, carbon monoxide and carbon dioxide were converted to methane with the use of a nickel-based methanizer for detection with flame ionization. Flow modulated thermal conductivity detection was employed to measure oxygen and nitrogen. Separation of all the target analytes was achieved in one single analysis of less than 12 min. Reproducibility of retention times for all compounds were found to be less than 0.1% (n = 20). Reproducibility of area counts at two levels, namely 100 ppmv and 1000 ppmv over a period of two days were found to be less than 5.5% (n = 20). Oxygen and nitrogen were found to be linear over a range from 20 ppmv to 10,000 ppmv with correlation coefficients of at least 0.998 and detection limits of less than 10 ppmv. Hydrocarbons of interest were found to be linear over a range from 200 ppbv to 1000 ppmv with correlation coefficients of greater than 0.999 and detection limits of less than 100 ppbv. 相似文献
10.
Pierre Gras Nicolas Ratel‐Ramond Sbastien Teychn Christian Rey Erik Elkaim Batrice Biscans Stphanie Sarda Christle Combes 《Acta Crystallographica. Section C, Structural Chemistry》2014,70(9):862-866
Calcium pyrophosphate hydrate (CPP, Ca2P2O7·nH2O) and calcium orthophosphate compounds (including apatite, octacalcium phosphate etc.) are among the most prevalent pathological calcifications in joints. Even though only two dihydrated forms of CPP (CPPD) have been detected in vivo (monoclinic and triclinic CPPD), investigations of other hydrated forms such as tetrahydrated or amorphous CPP are relevant to a further understanding of the physicochemistry of those phases of biological interest. The synthesis of single crystals of calcium pyrophosphate monohydrate (CPPM; Ca2P2O7·H2O) by diffusion in silica gel at ambient temperature and the structural analysis of this phase are reported in this paper. Complementarily, data from synchrotron X‐ray diffraction on a CPPM powder sample have been fitted to the crystal parameters. Finally, the relationship between the resolved structure for the CPPM phase and the structure of the tetrahydrated calcium pyrophosphate β phase (CPPT‐β) is discussed. 相似文献