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排序方式: 共有308条查询结果,搜索用时 15 毫秒
1.
Summary We have estimated and measured the daily thermal expansion of an oceanographic platform. This has been found negligible as
far as the calibration of a satellite altimeter is concerned. 相似文献
2.
3.
Using a representation of multichannel quantum defect theory in terms of a quantum Poincaré map for bound Rydberg molecules, we apply Jung's scattering map to derive a generalized quantum map, that includes the continuum. We show that this representation not only simplifies the understanding of the method, but moreover produces considerable numerical advantages. Finally we show under what circumstances the usual semi-classical approximations yield satisfactory results. In particular we see that singularities that cause problems in semi-classics are irrelevant to the quantum map. 相似文献
4.
A. Puiu G. Giubileo G. Addolorato L. Revelli G. Gasbarrini R. Bellantone A. D’Amore C. P. Lombardi C. Carrozza 《Laser Physics》2007,17(4):448-452
Nowadays, there is high demand for sensitive gas sensors both for human and environmental monitoring. This paper deals with a high-resolution (0.2 ppb) laser-based photoacoustic spectroscopic system realized at ENEA Frascati, Italy, applied for monitoring stress in scuba divers during sustained immersion by analyzing breath samples. Blood tests and psychometric tests for scuba divers were performed at Catholic University in Rome. Results will be reported and discussed. 相似文献
5.
Anna Rizzolo Patrizia Lombardi Maristella Vanoli Stefano Polesello 《Journal of separation science》1995,18(5):309-314
Capillary GC/sensory analysis was used to judge if dynamic headspace on sliced pulp and on intact fruit, and solvent extraction could collect the “character impact” and the “contributory” aroma compounds in peaches. Capillary GC/sensory data showed that the headspace techniques selectively recovered the “contributory” volatile compounds, which are strictly related to the characteristic odor of the various peach cultivars, whereas solvent extraction better quantified the “character impact” compounds (lactones). 相似文献
6.
Rigorous definitions are presented for the kinematic angular momentum K of a system of classical particles (a concept dual to the conventional angular momentum J), the angular momentum L(xi) associated with the moments of inertia, and the contributions to the total kinetic energy of the system from various modes of the motion of the particles. Some key properties of these quantities are described-in particular, their invariance under any orthogonal coordinate transformation and the inequalities they are subject to. The main mathematical tool exploited is the singular value decomposition of rectangular matrices and its differentiation with respect to a parameter. The quantities introduced employ as ingredients particle coordinates and momenta, commonly available in classical trajectory studies of chemical reactions and in molecular dynamics simulations, and thus are of prospective use as sensitive and immediately calculated indicators of phase transitions, isomerizations, onsets of chaotic behavior, and other dynamical critical phenomena in classical microaggregates, such as nanoscale clusters. 相似文献
7.
Ilaria Serafini Livia Lombardi Claudia Fasolato Manuel Sergi Francesca Di Ottavio Fabio Sciubba 《Natural product research》2019,33(7):1040-1051
AbstractIn this paper, the application of a multi-analytical approach for the characterisation of synthetic and natural dyes in a historical textile is presented. The work is focused on a historical dress of a Sicilian noblewoman, dating from about 1865–1870. Firstly, SERS on fibre was performed, in order to individuate the classes of dyes employed. The SERS spectra suggested the presence of two main dyes: mauveine and orcein. In order to confirm these preliminary results, two different extraction protocols were applied. The extracts obtained were analysed by ESI-MS, MALDI-ToF and UHPCL-MS analyses, confirming the SERS results. In particular, the application of the ammonia mild extraction technique allowed to selectively extract the phenoxazonic dyes, separating them already in the extraction step from the synthetic ones. Thanks to this multi-analytical approach, this dress could be considered as one of the first examples of employment of synthetic dyes in association with natural ones. 相似文献
8.
Shirakawa S Lombardi PJ Leighton JL 《Journal of the American Chemical Society》2005,127(28):9974-9975
A highly diastereo- and enantioselective [3 + 2] acylhydrazone-enol ether cycloaddition mediated by a simple chiral silane Lewis acid is described. The reactions are highly practical, as demonstrated by a larger scale (5 g of the hydrazone) reaction in which the product was obtained after recrystallization in 93% yield and 99% ee. Evidence for a stepwise mechanism and a model for the asymmetric induction are presented, as well. 相似文献
9.
Summary Frequency distributions of energy deposition in microscopic tissue volumes determined by means of a ?Rossi type? proportional
counter for 31, 12 and 8 MeV proton beams and, dose response curves for mortality and chromosome aberrations in cultured human
cells exposed to the same beams are analysed with a view to determining suitable parameters to specify radiation quality.
The behaviour of quantities LET,Z
*2/β2 and the microdosimetric parameter
as a function of energy are compared with the corresponding behaviour of the most significant radiobiological parameters
as mean lethal dose per targetD
0, mean inactivation dose
, intensity of chromosome aberrations, and dicentrics. It is shown that
is the most suitable physical parameter to characterize the relative effectiveness of protons in the (8÷31) MeV range.
Work partially supported by grant No. 8000165896 for the Finalized Project ?Tumor Growth Control?. 相似文献
10.
A numerical model for the adsorption kinetics of proteins on the walls of a microchannel has been developed using the finite element method (FEM) to address the coupling with diffusion phenomena in the restricted microchannel volume. Time evolutions of the concentration of one species are given, both in solution and on the microchannel walls. The model illustrates the adsorption limitation sometimes observed when the microdimensions of these systems induce a global depletion of the bulk solution. A new non-dimensional parameter is introduced to predict the final value of the coverage of any microsystem under static adsorption. A working curve and a criteria (h/K[Gamma](max) > 10) are provided in order to choose, for given adsorption characteristics, the value of the volume-to-surface ratio (i.e. the channel height h) avoiding depletion effects on the coverage (relative coverage greater than 90% of the theoretical one). Simulations were compared with confocal microscopy measurements of IgG antibody adsorption on the walls of a PET microchannel. The fit of the model to the experimental data show that the adsorption is under apparent kinetic control. 相似文献