An M/M/1 Driven Fluid Queue – Continued Fraction Approach

This paper presents complete solutions of the stationary distributions of buffer occupancy and buffer content of a fluid queue driven by an M/M/1 queue. We assume a general boundary condition when compared to the model discussed in Virtamo and Norros [Queueing Systems 16 (1994) 373–386] and Adan and Resing [Queueing Systems 22 (1996) 171–174]. We achieve the required solutions by transforming the underlying system of differential equations using Laplace transforms to a system of difference equations leading to a continued fraction. This continued fraction helps us to find complete solutions. We also obtain the buffer content distribution for this fluid model using the method of Sericola and Tuffin [Queueing Systems 31 (1999) 253–264].     

The Baylis–Hillman Adducts as Valuable Source for One‐Pot Multi‐Step Synthesis: A Facile Synthesis of Substituted Piperidin‐2‐ones

A facile, convenient, and one‐pot multi‐step synthesis of substituted piperidin‐2‐ones from the Baylis–Hillman alcohols derived from various aldehydes and acrylonitrile, involving Johnson–Claisen rearrangement, reduction of an α,β‐unsaturated nitrile moiety into the saturated amine‐skeleton, followed by cyclization, in an operationally simple procedure, is described.     

Simple and inexpensive method for cryopreservation of fish sperm combining straw and powdered dry ice

Here, we propose a simple and inexpensive method for fish sperm cryopreservation. Sperm samples of the loach Misgurnus anguillicaudatus (Teleostei: Cobitidae) were diluted 7-fold by an extender containing 63.5 mM NaCl, 114 mM KCl, 20 mM Tris and 10% methanol. The cryogenic straws were placed in three kinds of self-made tubes which diameter was changed by commercially available materials and then immersed into powdered dry ice for 2 min and plunged into liquid nitrogen. This procedure resulted in a cooling rate at -421.4 +/- 119.84 (control), -55.8 +/- 4.32 (tube 1), -40.2 +/- 3.43 (tube 2) and -33.3 +/- 2.09 C/min (tube 3). In the slowest cooling rate by the tube 3, total motility (72 +/- 3 %), duration (146 +/- 12 s) and hatching rates (29 +/- 04 %) were higher than those by other rates. Progressive motility (83 +/- 5 %) did not differ significantly from fresh samples.     

Growth and characterization of sulphamic acid single crystals grown by Sanakaranarayanan‐Ramasamy (SR) method

By directional solidification, single crystal of Sulphamic acid (SA) was successfully grown from aqueous solution by Sankaranarayanan‐Ramasamy (SR) method. A vertically designed L‐bend was used to avoid the effect due to spurious nucleation. A vertical bottom‐seeded ampoule was used for the growth of single crystal. A seed crystal was mounted at the bottom of the ampoule. Sulphamic acid crystals of up to 40 mm in diameter and 60 mm in length have been grown with a growth up to 10 mm per day. The grown sulphamic acid single crystal was characterized using X‐ray powder diffraction analysis, Raman, FTIR, and optical transmission studies. The dielectric behaviour was measured in the frequency range of 1 kHz–10 MHz for the temperature ranges from 30 °C to 170 °C. The sulphamic acid single crystal was also grown by conventional method. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Advances in Chalcogene Glycerophosphate Chemistry

Abstract

Achievements in the chemistry of trivalent phosphorus and phosphocyclic compounds find wide application in the synthesis of natural compounds. This paper provides fresh data on the possible use of these substances for the production of glycerophospholipids as well as their thio- and seleno-analogues. Thiol- and selenoanalogues of phosphatidylhomo-choline were obtained by a convenient thion-thiol/selenone-selenole isomerization of triester glycerophosphates in the presence of phosphonium salts as catalysts.     

Noise control of a rectangular cavity using macro perforated poro-elastic materials

The effectiveness of macro perforated porous materials to control noise levels inside a cavity is investigated. This is done using a finite element formulation based on the Biot-Allard theory that accounts for sound propagation in a poro-elastic medium. Earlier investigations have shown that macro-holes in a porous material can enhance low frequency sound absorption. However, this has been demonstrated in free field or waveguide environments. When such an approach is used in a cavity, it is seen that only certain patterns of macro-holes, dictated by cavity mode shapes, enhance noise reduction in the higher frequency ranges. This phenomenon is shown to be independent of porous material properties by considering two different materials. A correlation between the mode shapes and material removal is also established. A detailed convergence study for both cavity and poro-elastic finite element models, establishes the suitability of using higher order interpolation functions for coupled cavity-poro-elastic acoustic analysis.     

Optimization of window type and vent parameters on single-sided natural ventilation buildings

Journal of Thermal Analysis and Calorimetry - The residential building sector is one of the major areas to reduce energy demand. In this study, the single-sided top vent-based natural ventilation...     

Synthesis of hybrid mesoporous spheres using the chitosan as template

Hybrid mesoporous spheres of Al and Si oxides were synthesized for the mixture of organic material (chitosan) with inorganic material (aluminum and silicon hydroxide). It was observed that chitosan with larger polymerization degree, resulted in a larger mechanical resistance of the spheres. The oxides were characterized by the following: Fourier transform infrared spectroscopy (FTIR), X-ray diffraction analysis (XRD), differential scanning calorimetry (DSC), as well as, thermogravimetric analysis (TGA), scanning electron microscopy (SEM) and adsorption isotherms of N₂ (BET). Highly uniform oxide sphere diameters were obtained (average of 1.0 mm). The results of the adsorption isotherms indicated that the material is mesoporous. The surface area of the materials ranged between 620 and 245 m²/g, and the pore volume varied between 0.82 and 0.28 cm³/g, depending on the molar ratio of the organic and inorganic materials.     

Synthesis and Evaluation of Biological Activities of Bis(spiropyrazolone)cyclopropanes: A Potential Application against Leishmaniasis

This work focuses on the search and development of drugs that may become new alternatives to the commercial drugs currently available for treatment of leishmaniasis. We have designed and synthesized 12 derivatives of bis(spiropyrazolone)cyclopropanes. We then characterized their potential application in therapeutic use. For this, the in vitro biological activities against three eukaryotic models—S. cerevisiae, five cancer cell lines, and the parasite L. mexicana—were evaluated. In addition, cytotoxicity against non-cancerous mammalian cells has been evaluated and other properties of interest have been characterized, such as genotoxicity, antioxidant properties and, in silico predictive adsorption, distribution, metabolism, and excretion (ADME). The results that we present here represent a first screening, indicating two derivatives of bis(spiropyrazolone)cyclopropanes as good candidates for the treatment of leishmaniasis. They have good specificity against parasites with respect to mammalian cells.