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1.
Structural characterization of lipopeptide biomarkers isolated from Bacillus globigii 总被引:2,自引:0,他引:2
Spectra obtained using matrix-assisted laser desorption/ionization (MALDI) mass spectrometry of Bacillus globigii (Bacillus subtilis niger) spores, vegetative cells and the culture supernatant show a cluster of biomarkers centered at a molecular mass of 1478 Da. Three biomarkers were isolated from the cell-free culture supernatant by solid-phase extraction and reversed-phase high-performance liquid chromatography, and characterized using various kinds of mass spectrometry. A Fourier transform mass spectrometer with a MALDI source was used to determine the monoisotopic protonated masses at 1463.8, 1477.8, and 1505.8 Da in order of elution. The mass differences of 14 and 28 Da suggest that they are homologous molecules. Alkaline hydrolysis of each species showed that it contained a lactone linkage. Strong acid hydrolysis released a fatty acid from an amide bond, consistent with a lipopeptide. A quadrupole time-of-flight instrument with a nanospray source was used to sequence the hydrolyzed forms of the three biomarkers. The cyclic lipopeptides were found to have amino acid sequences identical with those in fengycins and plipastatins, antimicrobial compounds with phospholipase inhibitor activity, previously identified in related species of Bacillus subtilis and Bacillus cereus. 相似文献
2.
G.W. Brandenburg R.K. Carnegie R.J. Cashmore M. Davier W.M. Dunwoodie T.A. Lasinski D.W.G.S. Leith J.A.J. Matthews P. Walden S.H. Williams 《Physics letters. [Part B]》1975,59(4):405-408
The results of a wire chamber spectrometer experiment studying 1 (890) production in the reaction K?p→ K?π+n at 13 GeV are presented. Strong forward structure is observed for |t|< m2π in the s-channel density matrix elements and differential cross section. These features are similar to those observed in π?p→?0n data and are characteristics of π exchange. In contrast in the intermediate, |t| ~ 0.2 GeV2, and large momentum transfer regions 1 (890) production is demonstrated by the natural parity ??A2 exchange contribution. 相似文献
3.
A technique for producing diffractive optical elements uses holographic methods to incorporate into the recorded fringe pattern a correction factor for the phase defect of the substrate. 相似文献
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The thin grating decomposition method of thick grating analysis is used to analyze guiding effects in thick phase gratings having sinusoidal refractive index modulation. 相似文献
6.
Gabrielle A. Leith Allison M. Rice Brandon J. Yarbrough Anna A. Berseneva Richard T. Ly Charles N. Buck III Dr. Denis Chusov Amy J. Brandt Prof. Dr. Donna A. Chen Benjamin W. Lamm Prof. Dr. Morgan Stefik Kenneth S. Stephenson Dr. Mark D. Smith Prof. Dr. Aaron K. Vannucci Dr. Perry J. Pellechia Prof. Dr. Sophya Garashchuk Prof. Dr. Natalia B. Shustova 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(15):6056-6062
The effect of donor (D)–acceptor (A) alignment on the materials electronic structure was probed for the first time using novel purely organic porous crystalline materials with covalently bound two- and three-dimensional acceptors. The first studies towards estimation of charge transfer rates as a function of acceptor stacking are in line with the experimentally observed drastic, eight-fold conductivity enhancement. The first evaluation of redox behavior of buckyball- or tetracyanoquinodimethane-integrated crystalline was conducted. In parallel with tailoring the D-A alignment responsible for “static” changes in materials properties, an external stimulus was applied for “dynamic” control of the electronic profiles. Overall, the presented D–A strategic design, with stimuli-controlled electronic behavior, redox activity, and modularity could be used as a blueprint for the development of electroactive and conductive multidimensional and multifunctional crystalline porous materials. 相似文献
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Stack the Bowls: Tailoring the Electronic Structure of Corannulene‐Integrated Crystalline Materials 下载免费PDF全文
Allison M. Rice Ekaterina A. Dolgopolova Brandon J. Yarbrough Gabrielle A. Leith Corey R. Martin Kenneth S. Stephenson Rebecca A. Heugh Amy J. Brandt Prof. Dr. Donna A. Chen Dr. Stavros G. Karakalos Dr. Mark D. Smith Prof. Dr. Kelsey B. Hatzell Dr. Perry J. Pellechia Prof. Dr. Sophya Garashchuk Prof. Dr. Natalia B. Shustova 《Angewandte Chemie (International ed. in English)》2018,57(35):11310-11315
We report the first examples of purely organic donor–acceptor materials with integrated π‐bowls (πBs) that combine not only crystallinity and high surface areas but also exhibit tunable electronic properties, resulting in a four‐orders‐of‐magnitude conductivity enhancement in comparison with the parent framework. In addition to the first report of alkyne–azide cycloaddition utilized for corannulene immobilization in the solid state, we also probed the charge transfer rate within the Marcus theory as a function of mutual πB orientation for the first time, as well as shed light on the density of states near the Fermi edge. These studies could foreshadow new avenues for πB utilization for the development of optoelectronic devices or a route for highly efficient porous electrodes. 相似文献
9.
Grace C. Thaggard Dr. Gabrielle A. Leith Daniil Sosnin Dr. Corey R. Martin Kyoung Chul Park Margaret K. McBride Dr. Jaewoong Lim Brandon J. Yarbrough Buddhima K. P. Maldeni Kankanamalage Gina R. Wilson Austin R. Hill Dr. Mark D. Smith Prof. Dr. Sophya Garashchuk Prof. Dr. Andrew B. Greytak Prof. Dr. Ivan Aprahamian Prof. Dr. Natalia B. Shustova 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2023,135(2):e202211776
Confinement-imposed photophysics was probed for novel stimuli-responsive hydrazone-based compounds demonstrating a conceptual difference in their behavior within 2D versus 3D porous matrices for the first time. The challenges associated with photoswitch isomerization arising from host interactions with photochromic compounds in 2D scaffolds could be overcome in 3D materials. Solution-like photoisomerization rate constants were realized for sterically demanding hydrazone derivatives in the solid state through their coordinative immobilization in 3D scaffolds. According to steady-state and time-resolved photophysical measurements and theoretical modeling, this approach provides access to hydrazone-based materials with fast photoisomerization kinetics in the solid state. Fast isomerization of integrated hydrazone derivatives allows for probing and tailoring resonance energy transfer (ET) processes as a function of excitation wavelength, providing a novel pathway for ET modulation. 相似文献
10.
We introduce a new approach to solve shape optimization problems with state constraints. The problem is reformulated on a fixed reference domain using conformal pull-back. The shape dependence is then hidden in the conformal parameter. The problem is discretized using FEM and solved as an NLP. Finally the optimal shape can be reconstructed from the optimal conformal parameter. (© 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献