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排序方式: 共有109条查询结果,搜索用时 15 毫秒
1.
Huijser A Savenije TJ Kroeze JE Siebbeles LD 《The journal of physical chemistry. B》2005,109(43):20166-20173
The photoinduced charge separation efficiency in porphyrin/TiO2 bilayers has been determined using the time-resolved microwave conductivity (TRMC) technique. Porphyrins investigated are unsubstituted meso-tetraphenylporphyrin (TPP) and meso-tetra(4-ethylphenyl)porphyrin (TEPP). TEPP/TiO2 bilayers exhibit a charge separation efficiency per incident photon at the Soret band maximum of 6.2%, which is considerably higher than the efficiency of 1.2% found for TPP/TiO2 bilayers. Exciton diffusion lengths of 7 A for TPP and 75 A for TEPP are obtained from fitting a model for the charge separation efficiency to the experimental data. Optical measurements on the porphyrin derivatives on quartz yield a 20 times higher fluorescence quantum yield and a 7 times higher fluorescence rate constant for TEPP layers as compared to TPP layers. The exciton lifetime of 800 ps found for TEPP layers is considerably longer than the lifetime of 260 ps in TPP layers. The exciton diffusion coefficients, determined from the exciton diffusion length and the exciton lifetime, are found to be 2.10(-9) m(2)/s for TPP and 7.10(-8) m(2)/s for TEPP. The difference is discussed in terms of the presence of face-to-face dimers or larger aggregates in TPP layers. 相似文献
2.
Dressings Loaded with Cyclodextrin–Hamamelitannin Complexes Increase Staphylococcus aureus Susceptibility Toward Antibiotics Both in Single as well as in Mixed Biofilm Communities 下载免费PDF全文
Gilles Brackman Maria José Garcia‐Fernandez Joke Lenoir Laurens De Meyer Jean‐Paul Remon Thomas De Beer Angel Concheiro Carmen Alvarez‐Lorenzo Tom Coenye 《Macromolecular bioscience》2016,16(6):859-869
Bacteria reside within biofilms at the infection site, making them extremely difficult to eradicate with conventional wound care products. Bacteria use quorum sensing (QS) systems to regulate biofilm formation, and QS inhibitors (QSIs) have been proposed as promising antibiofilm agents. Despite this, few antimicrobial therapies that interfere with QS exist. Nontoxic hydroxypropyl‐β‐cyclodextrin‐functionalized cellulose gauzes releasing a burst of the antibiotic vancomycin and the QSI hamamelitannin are developed, followed by a sustained release of both. The gauzes affect QS and biofilm formation of Pseudomonas aeruginosa and Staphylococcus aureus in an in vitro model of chronic wound infection and can be considered as candidates to be used to prevent wound infection as well as treat infected wounds.
3.
Mulder FM Stride J Picken SJ Kouwer PH de Haas MP Siebbeles LD Kearley GJ 《Journal of the American Chemical Society》2003,125(13):3860-3866
Discotic molecules have planar, disklike polyaromatic cores that can self-assemble into "molecular wires". Highly anisotropic charge transfer along the wires arises when there is sufficient intermolecular overlap of the pi-orbitals of the molecular cores. Discotic materials can be applied in molecular electronics, field-effect transistors, and-recently with record quantum efficiencies-photovoltaics (Schmidt-Mende, L.; Fechtenk?tter, A.; Müllen, K.; Moons, E.; Frien, R. H.; MacKenzie, J. D. Science 2001, 293, 1119). A combination of quasielastic neutron scattering (QENS) measurements with molecular dynamics simulations on the discotic molecule hexakis(n-hexyloxy)triphenylene (HAT6) shows that the dynamics of the cores and tails of discotic molecules are strongly correlated. Core and tail dynamics are not separated, the system being characterized by overall in-plane motion, on a time scale of 0.2 ps, and softer out-of-plane motions at 7 ps. Because charge transfer between the molecules is on similar time scales, these motions are relevant for the conducting properties of the materials. Both types of motion are dominated by van der Waals interactions. Small-amplitude in-plane motions in which the disks move over each other are almost entirely determined by tail/tail interactions, these also playing an important role in the out-of-plane motion. The QENS measurements reveal that these motions are little changed by passing from the columnar phase to the isotropic liquid phase, just above the clearing temperature. The model of four HAT6 molecules in a column reproduces the measured QENS spectrum of the liquid phase, suggesting that correlations persist within the liquid phase over about this number of disks. 相似文献
4.
The gas chromatographic determination of trace gaseous impurities in highly reactive fluorinated gaseous matrices presents unique requirements to both equipment and techniques. Especially problematic are the gases normally present in ambient air namely oxygen and nitrogen. Analysing these gases at the low microl/l (ppm) level requires special equipment and this publication describes a custom-designed system utilising backflush column switching to protect the columns and detectors. A thermal conductivity detector with nickel filaments was used to determine ppm levels of impurities in ClF3. 相似文献
5.
Laurens van Gelderen Gadi Rothenberg V. Roberto Calderone Karen Wilson N. Raveendran Shiju 《应用有机金属化学》2013,27(1):23-27
Copper immobilized on a functionalized silica support is a good catalyst for the homocoupling of terminal alkynes. The so‐called Glaser–Hay coupling reaction can be run in air with catalytic amounts of base. The copper catalyst is active for multiple substituted alkynes, in both polar and non‐polar solvents, with good to excellent yields (75–95%). Depending on the alkyne, full conversion can be achieved within 3–24 h. The catalyst was characterized by TGA, inductively coupled plasma and X‐ray photoelectron spectroscopy. Leaching tests confirm that the catalyst is and remains heterogeneous. Importantly, the overall reaction requires only alkyne and oxygen (in this case, air) as reagents, making this a clean catalytic oxidative coupling reaction. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
6.
John H.J. Einmahl Laurens de Haan Ashoke Kumar Sinha 《Stochastic Processes and their Applications》1997,70(2):143-171
Let (X1, Y1), (X2, Y2),…, (Xn, Yn) be a random sample from a bivariate distribution function F which is in the domain of attraction of a bivariate extreme value distribution function G. This G is characterized by the extreme value indices and its spectral measure or angular measure. The extreme value indices determine both the marginals and the spectral measure determines the dependence structure. In this paper, we construct an empirical measure, based on the sample, which is a consistent estimator of the spectral measure. We also show for positive extreme value indices the asymptotic normality of the estimator under a suitable 2nd order strengthening of the bivariate domain of attraction condition. 相似文献
7.
Let X={X(s)}s∈S be an almost sure continuous stochastic process (S compact subset of Rd) in the domain of attraction of some max-stable process, with index function constant over S. We study the tail distribution of ∫SX(s)ds, which turns out to be of Generalized Pareto type with an extra ‘spatial’ parameter (the areal coefficient from Coles and Tawn (1996) [3]). Moreover, we discuss how to estimate the tail probability P(∫SX(s)ds>x) for some high value x, based on independent and identically distributed copies of X. In the course we also give an estimator for the areal coefficient. We prove consistency of the proposed estimators. Our methods are applied to the total rainfall in the North Holland area; i.e. X represents in this case the rainfall over the region for which we have observations, and its integral amounts to total rainfall.The paper has two main purposes: first to formalize and justify the results of Coles and Tawn (1996) [3]; further we treat the problem in a non-parametric way as opposed to their fully parametric methods. 相似文献
8.
A test statistic is developed that checks the validity of the extreme value conditions without specifiying the shape parameter of the limiting extreme value distribution. 相似文献
9.
In an Internet auction, the expected payoff acts as a benchmark of the reasonableness of the price that is paid for the purchased
item. Since the number of potential bidders is not observable, the expected payoff is difficult to estimate accurately. We
approach this problem by considering the bids as a record and 2-record sequence of the potential bidder’s valuation and using
the Extreme Value Theory models to model the tail distribution of the bidder’s valuation and study the expected payoff. Along
the discussions for three different cases regarding the extreme value index γ, we show that the observed payoff does not act as an accurate estimation of the expected payoff in all the cases except a
subclass of the case γ = 0. Within this subclass and under a second order condition, the observed payoff consistently converges to the expected
payoff and the corresponding asymptotic normality holds.
相似文献
10.