全文获取类型
收费全文 | 75篇 |
免费 | 4篇 |
专业分类
化学 | 51篇 |
力学 | 1篇 |
数学 | 3篇 |
物理学 | 24篇 |
出版年
2023年 | 2篇 |
2022年 | 2篇 |
2021年 | 1篇 |
2020年 | 1篇 |
2019年 | 1篇 |
2018年 | 2篇 |
2017年 | 1篇 |
2016年 | 3篇 |
2015年 | 1篇 |
2014年 | 5篇 |
2013年 | 9篇 |
2012年 | 4篇 |
2011年 | 3篇 |
2010年 | 7篇 |
2008年 | 1篇 |
2007年 | 3篇 |
2006年 | 2篇 |
2005年 | 4篇 |
2004年 | 5篇 |
2003年 | 2篇 |
2002年 | 3篇 |
2001年 | 3篇 |
2000年 | 1篇 |
1997年 | 1篇 |
1995年 | 1篇 |
1994年 | 3篇 |
1992年 | 3篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1986年 | 1篇 |
排序方式: 共有79条查询结果,搜索用时 15 毫秒
1.
2.
No K Bok JH Suh IH Kang SO Ko J Nam KC Kim JS 《The Journal of organic chemistry》2004,69(20):6938-6941
A series of novel tetrahomodioxacalix[4]biscrowns with crown-2, crown-3, crown-4, crown-5, and crown-6 units were synthesized. Conformations of each product are dependent on the base used and their conformation stabilities. All conformations were proven by NMR spectra and/or X-ray crystal structures. The 1,3-alternate homodioxacalix[4]biscrown-4 (4b) shows the best selectivity for K+, whereas the 1,3-alternate homodioxacalix[4]crown-5 (5) does for Cs+. Those selectivities are attributable to electrostatic interaction between the metal ion and the crown ring, as well as a pi-metal complexation. However, the C-1,2-alternate conformation does not take the metal ions regardless of the crown species as a result of steric hindrance from the methylene bridge of an ArCH2Ar unit. 相似文献
3.
4.
Three urea derivatives of anthraquinone were synthesized and they showed a high selectivity for dihydrogen phosphate ions. 相似文献
5.
Yong Sam Chung Sun Ha Kim Gwang Min Sun Jong Myoung Lim Jong Hwa Moon Kye Hong Lee Young Jin Kim Jong Il Choi Ju Woon Lee 《Journal of Radioanalytical and Nuclear Chemistry》2012,291(1):223-229
The analysis of mineral contents in space foods is needed to obtain an information on a comprehensive elemental composition
as well as the investigation on the effects of human nutrition and health based on the dietary intake of mineral elements.
Recently, six items of new Korean space foods (KSFs) such as kimchi, bibimbap, bulgogi, a ramen, a mulberry beverage and a
fruit punch which was developed by the KAERI, and the contents of more than 15 elements in the samples were examined by using
instrumental neutron activation analysis (INAA). Five biological certified reference materials, NIST SRM were used for analytical
quality control. The results were compared with those of common Korean foods reported, and these results will be applied toward
the identification of irradiated foods. 相似文献
6.
Soon Kil Ahn Nam Song Choi Byeong Seon Jeong Kye Kwang Kim Duck Jin Journ Joon Kyum Kim Sang Joon Lee Jung Woo Kim Chung Hong Sang‐Sup Jew 《Journal of heterocyclic chemistry》2000,37(5):1141-1144
A practical semi‐synthetic method of (S)‐7‐(2‐isopropylamino)ethylcamptothecin hydrochloride has been developed. The Mannich reaction of (S)‐7‐methylcamptothecin with isopropylamine hydrochloride in dimethyl sulfoxide as a formaldehyde source gave the desired product in moderate yield. 相似文献
7.
Sunwoo Kang Sang Joo Lee Shihai Yan Kye Chun Nam Jin Yong Lee 《Journal of inclusion phenomena and macrocyclic chemistry》2010,66(1-2):67-73
We investigated the binding nature of the 1,2,3-alternate calix[6]arene with one piperidine, two piperidines, and two triethyl amines with a special emphasis on the hydrogen bonding networks by density functional theory calculations. The 1,2,3-alternate calix[6]arene strongly binds with piperidines and triethylamines at two different binding sites, exo and endo sites. In the two binding sites, the hydrogen bonding nature shows a characteristic difference. In the exo site, there formed only one hydrogen bond, while in the endo site, two hydrogen bonds except for the triethylamine. The proton transfer within the hydrogen bonding and the hydrogen bonding types, normal hydrogen bonding (NHB), short strong hydrogen bond (SSHB), and low barrier hydrogen bonding (LBHB), will be discussed in detail. 相似文献
8.
Sunwoo Kang Sang Joo Lee Shihai Yan Kye Chun Nam Jin Yong Lee 《Journal of inclusion phenomena and macrocyclic chemistry》2010,66(1-2):75-79
The variations in geometry structure, IR spectra, as well as the molecular orbitals upon anion recognition for polyamide cryptand are explored with the hybrid density functional theory. The cavity generated by six amide NH groups shrinks upon F ? recognition because of the strong hydrogen bonds between the amide protons and F ? , while the cavity expands upon Cl ? binding because of the strong electron repulsion between the p electron of Cl ? and the lone pair electrons of the nitrogen atom of the pyridine moieties. The “electropositive field space” …Cl ? coupling exists when Cl ? is recognized. The strong anion binding energy with F ? indicates that the polyamide cryptand prefers F ? to Cl ? . 相似文献
9.
Dong Chan Kim Kyung Ho Yoo Kye Jung Shin Sang Woo Park Dong Jin Kim 《Journal of heterocyclic chemistry》1997,34(1):57-63
The pKa′s of several thiazole heterocyclic compounds have been determined and represent products with significantly high values. Because of their high basicities, sometimes these compounds were able to act as not only nucleophiles but also strong organic bases. 4-Substituted-3-methyl-2-methylimino-Δ4-thiazolines 5a-d reacted with ethyl bromoacetate in refluxing benzene, giving the corresponding N-alkylated salts 8a-d , while the products obtained from the reaction with 2-bromoacetophenone in the presence of base were pyrrolothiazines 10b-d. 相似文献
10.
Jun Zhou Young-Sik Kye Alexander I. Kolesnikov 《Isotopes in environmental and health studies》2013,49(3):271-277
The complex formed between 4-methylpyridine and pentachlorophenol (4MPPCP) crystallises in a triclinic space group. If the same complex is synthesized from deuterated pentachlorophenol, it crystallizes in an entirely different monoclinic polymorph. Using solid-state NMR of samples synthesized with a full range of deuteration levels, crystallized from solution or the melt, and in the presence or absence of seeds, we have confirmed that the isotopomers indeed have different thermodynamically stable crystal structures. The roots of this phenomenon of isotopomeric polymorphism apparently lie in the differences in hydrogen bonding between the polymorphs. The triclinic form has a relatively short hydrogen bond. High-field solid-state NMR shows both the 1H chemical shift and the 2H electric quadrupole coupling of the hydrogen involved in the bond to be strongly temperature-dependent, indicating a low-lying excited state of the hydrogen bond longitudinal vibration. Inelastic neutron scattering of isotopomers of 4MPPCP has allowed us to identify the three orthogonal vibrational modes of the hydrogen in the hydrogen bond, at 29.7, 145, and 205 meV (240, 1168, and 1651 cm?1). The longitudinal mode is the lowest in energy, and it indicates a slightly asymmetric low-barrier double-well potential. Intrinsic to such potentials is a very small difference in zero-point energies (ZPEs) between the protonated and deuterated forms. As a contrast, the monoclinic form has a comparatively normal hydrogen bond, in which the proton and deuteron ZPEs should be different by approximately 500 cm?1. A scenario can be envisaged where the triclinic protonated form is lower in energy than the monoclinic protonated form, but the triclinic deuterated form is higher in energy than the monoclinic deuterated form. This evidently accounts for the difference in relative stabilities of the two forms upon isotope substitution. 相似文献