Dye-sensitized solar cells fabricated with black raspberry, black carrot and rosella juice

In this work, dye sensitized solar cells (DSSC’s) were constructed from black raspberry (Rubus Ideaus), black carrot (Daucuscarota L.) and rosella juice (Hibiscus Sabdariffa L.). In order to fabricate a DSSC the fluorine-doped tin (IV) oxide (FTO) thin films obtained by using spray pyrolysis technique were used as a substrate. TiO₂ films on FTO layers were prepared by doctor-blading technique. Platinum-coated counter electrode and liquid Iodide/Iodine electrolyte solution were used to fabricate DSSC’s. The efficiencies of solar cells produced with black carrot, rosella and black raspberry juice were calculated as 0.25%, 0.16% and 0.16% respectively, under a sunny day in Kahramanmaraş-Turkey.     

TOF-SIMS investigation of degradation pathways occurring in a variety of organic photovoltaic devices - the ISOS-3 inter-laboratory collaboration

The present work is the fourth (and final) contribution to an inter-laboratory collaboration that was planned at the 3rd International Summit on Organic Photovoltaic Stability (ISOS-3). The collaboration involved six laboratories capable of producing seven distinct sets of OPV devices that were degraded under well-defined conditions in accordance with the ISOS-3 protocols. The degradation experiments lasted up to 1830 hours and involved more than 300 cells on more than 100 devices. The devices were analyzed and characterized at different points of their lifetimes by a large number of non-destructive and destructive techniques in order to identify specific degradation mechanisms responsible for the deterioration of the photovoltaic response. Work presented herein involves time-of-flight secondary ion mass spectrometry (TOF-SIMS) in order to study chemical degradation in-plane as well as in-depth in the organic solar cells. Various degradation mechanisms were investigated and correlated with cell performance. For example, photo-oxidation of the active material was quantitatively studied as a function of cell performance. The large variety of cell architectures used (some with and some without encapsulation) enabled valuable comparisons and important conclusions to be drawn on degradation behaviour. This comprehensive investigation of OPV stability has significantly advanced the understanding of degradation behaviour in OPV devices, which is an important step towards large scale application of organic solar cells.     

Fuzzy scheduling of job orders in a two-stage flowshop with batch-processing machines

In this paper, we present a mixed-integer fuzzy programming model and a genetic algorithm (GA) based solution approach to a scheduling problem of customer orders in a mass customizing furniture industry. Independent job orders are grouped into multiple classes based on similarity in style so that the required number of setups is minimized. The family of jobs can be partitioned into batches, where each batch consists of a set of consecutively processed jobs from the same class. If a batch is assigned to one of available parallel machines, a setup is required at the beginning of the first job in that batch. A schedule defines the way how the batches are created from the independent jobs and specifies the processing order of the batches and that of the jobs within the batches. A machine can only process one job at a time, and cannot perform any processing while undergoing a setup. The proposed formulation minimizes the total weighted flowtime while fulfilling due date requirements. The imprecision associated with estimation of setup and processing times are represented by fuzzy sets.     

Effect of Ethanol on the Photovoltaic Performance of ZnO Based Dye Sensitized Solar Cells

Crystallography Reports - In this study, ZnO particles were grown at different ethanol–water concentrations by using a simple hydrothermal method at 97°C. The changes in structure and...     

On the stability of a variety of organic photovoltaic devices by IPCE and in situ IPCE analyses - the ISOS-3 inter-laboratory collaboration

This work is part of the inter-laboratory collaboration to study the stability of seven distinct sets of state-of-the-art organic photovoltaic (OPV) devices prepared by leading research laboratories. All devices have been shipped to and degraded at RIS?-DTU up to 1830 hours in accordance with established ISOS-3 protocols under defined illumination conditions. In this work, we apply the Incident Photon-to-Electron Conversion Efficiency (IPCE) and the in situ IPCE techniques to determine the relation between solar cell performance and solar cell stability. Different ageing conditions were considered: accelerated full sun simulation, low level indoor fluorescent lighting and dark storage. The devices were also monitored under conditions of ambient and inert (N(2)) atmospheres, which allows for the identification of the solar cell materials more susceptible to degradation by ambient air (oxygen and moisture). The different OPVs configurations permitted the study of the intrinsic stability of the devices depending on: two different ITO-replacement alternatives, two different hole extraction layers (PEDOT:PSS and MoO(3)), and two different P3HT-based polymers. The response of un-encapsulated devices to ambient atmosphere offered insight into the importance of moisture in solar cell performance. Our results demonstrate that the IPCE and the in situ IPCE techniques are valuable analytical methods to understand device degradation and solar cell lifetime.     

Stereoselective Synthesis of 1,2,3‐Triazolooxazine and Fused 1,2,3‐Triazolo‐δ‐Lactone Derivatives

The stereoselective synthesis of 1,2,3‐triazolooxazine and fused 1,2,3‐triazolo‐δ‐lactone by applying chemoenzymatic methods is described. trans‐2‐Azidocyclohexanol was successfully resolved by Novozyme 435 with an ee value of 99%. Installation of the alkyne moiety on the enantiomerically enriched azidoalcohol by O‐alkylation, followed by intramolecular azide? alkyne [3+2] cycloaddition resulted in the desired 1,2,3‐triazolooxazine derivative. Enantiomerically pure azidocyclohexanol was also subjected to the Huisgen 1,3‐dipolar cycloaddition reaction with dimethylacetylene dicarboxylate, followed by intramolecular cyclization of the corresponding cycloadduct, to furnish a fused 1,2,3‐triazolo‐δ‐lactone.     

Lamb wave scattering by a symmetric pair of surface-breaking cracks in a plate

The scattering problem of a Lamb wave incident on a symmetric pair of surface-breaking transverse cracks in a plate is considered. The Lamb wave is assumed to be obliquely incident on the crack plane. Since the cracks are part-through, the scattered field will contain reflected as well as transmitted waves. The energy of the incoming wave is partitioned into reflected and transmitted wave modes. Energy coefficients of the reflected and transmitted waves are calculated as a function of incident frequency and crack depth. The incidence angle of the incoming wave is also treated as a parameter. Both the reflected and transmitted wave fields are considered as linear superpositions of all real and complex wave modes in the plate. Decomposition of modes is achieved with the help of an orthogonality condition based on the principle of reciprocal work. Continuity of displacement and stress fields is imposed at the crack plane. Energy coefficients for reflection and transmission are obtained from the mode amplitudes. Energy coefficients are shown to be a strong function of incident frequency and crack depth. Experiments are conducted with a PZT transducer network interacting with a symmetric pair of machined cracks in an aluminum plate. Trends predicted by the analysis are reflected in the experimental results.     

Spray pyrolysis deposition of ZnO thin films on FTO coated substrates from zinc acetate and zinc chloride precursor solution at different growth temperatures

ZnO thin films were fabricated using zinc chloride and zinc acetate precursors by the spray pyrolysis technique on FTO coated glass substrates. The ZnO films were grown in different deposition temperature ranges varying from 400 to 550 °C. Influences of substrate temperature and zinc precursors on crystal structure, morphology and optical property of the ZnO thin films were investigated. XRD patterns of the films deposited using chloride precursor indicate that (1 0 1) is dominant at low temperatures, while those deposited using acetate precursor show that (1 0 1) is dominant at high temperatures. SEM images show that deposition temperature and type of precursor have a strong effect on the surface morphology. Optical measurements show that ZnO films are obviously influenced by the substrate temperatures and different types of precursor solutions. It is observed that as temperature increases, transmittance decreases for ZnO films obtained using zinc chloride precursor, but the optical transmittance of ZnO films obtained using zinc acetate precursor increases as temperature increases.