全文获取类型
收费全文 | 718篇 |
免费 | 17篇 |
国内免费 | 2篇 |
专业分类
化学 | 447篇 |
晶体学 | 2篇 |
力学 | 24篇 |
数学 | 103篇 |
物理学 | 161篇 |
出版年
2022年 | 5篇 |
2021年 | 9篇 |
2020年 | 6篇 |
2019年 | 11篇 |
2018年 | 6篇 |
2017年 | 9篇 |
2016年 | 6篇 |
2015年 | 15篇 |
2014年 | 21篇 |
2013年 | 31篇 |
2012年 | 39篇 |
2011年 | 47篇 |
2010年 | 20篇 |
2009年 | 15篇 |
2008年 | 29篇 |
2007年 | 34篇 |
2006年 | 29篇 |
2005年 | 29篇 |
2004年 | 28篇 |
2003年 | 20篇 |
2002年 | 11篇 |
2001年 | 13篇 |
2000年 | 14篇 |
1999年 | 13篇 |
1998年 | 8篇 |
1997年 | 15篇 |
1996年 | 14篇 |
1995年 | 8篇 |
1994年 | 8篇 |
1993年 | 15篇 |
1992年 | 10篇 |
1991年 | 7篇 |
1990年 | 8篇 |
1988年 | 12篇 |
1986年 | 9篇 |
1985年 | 7篇 |
1984年 | 8篇 |
1983年 | 8篇 |
1982年 | 7篇 |
1981年 | 10篇 |
1980年 | 9篇 |
1979年 | 7篇 |
1977年 | 8篇 |
1976年 | 10篇 |
1975年 | 7篇 |
1974年 | 12篇 |
1973年 | 13篇 |
1969年 | 7篇 |
1968年 | 6篇 |
1960年 | 6篇 |
排序方式: 共有737条查询结果,搜索用时 15 毫秒
1.
R.J. Gardner 《Advances in Mathematics》2007,216(1):358-386
This paper develops a significant extension of E. Lutwak's dual Brunn-Minkowski theory, originally applicable only to star-shaped sets, to the class of bounded Borel sets. The focus is on expressions and inequalities involving chord-power integrals, random simplex integrals, and dual affine quermassintegrals. New inequalities obtained include those of isoperimetric and Brunn-Minkowski type. A new generalization of the well-known Busemann intersection inequality is also proved. Particular attention is given to precise equality conditions, which require results stating that a bounded Borel set, almost all of whose sections of a fixed dimension are essentially convex, is itself essentially convex. 相似文献
2.
J. B. Campbell J. M. Greene E. R. Lavagnino D. N. Gardner A. J. Pike J. Snoddy E. C. Taylor 《Journal of heterocyclic chemistry》1986,23(3):669-672
New methods of preparing 2,3-diaminopyridine ( 13 ) from 2-chloro-3-nitropyridine ( 11 ) and 3,4-diaminopy-ridine ( 8 ) from 4-ethoxy-3-nitropyridine hydrochloride ( 5 ) have been explored and evaluated. 相似文献
3.
Douglas R. Hurst Kristen L. French April J. Angel Angela R. Williams Mary E. Rampey Tina S. Guion Kam W. Chan Camille M. Kassis Shannon L. Studer Martinez Charles F. Beam 《Journal of heterocyclic chemistry》1998,35(6):1357-1359
Several acetoacetanilides were trilithiated in excess lithium diisopropylamide, and the resulting polylithiated intermediates were regioselectively condensed with lithiated methyl salicylates followed by acid cyclization to substituted 4-oxo-N-aryl-4H-1-benzopyran-2-acetamides (benzopyranone-2-acetamides). 相似文献
4.
5.
Andrey Shatskiy Anton Axelsson Elena V. Stepanova Jian-Quan Liu Azamat Z. Temerdashev Bhushan P. Kore Bjrn Blomkvist James M. Gardner Peter Dinr Markus D. Krks 《Chemical science》2021,12(15):5430
A protocol for stereoselective C-radical addition to a chiral glyoxylate-derived N-sulfinyl imine was developed through visible light-promoted photoredox catalysis, providing a convenient method for the synthesis of unnatural α-amino acids. The developed protocol allows the use of ubiquitous carboxylic acids as radical precursors without prior derivatization. The protocol utilizes near-stoichiometric amounts of the imine and the acid radical precursor in combination with a catalytic amount of an organic acridinium-based photocatalyst. Alternative mechanisms for the developed transformation are discussed and corroborated by experimental and computational studies.A protocol for stereoselective C-radical addition to a chiral glyoxylate-derived N-sulfinyl imine was developed through visible light-promoted photoredox catalysis, providing a convenient method for the synthesis of unnatural α-amino acids. 相似文献
6.
Crystals of Ba(2)Cu(PO(4))(2) have been grown in a low-temperature eutectic flux of 32% KCl and 68% CuCl (mp = 140 degrees C). The X-ray single-crystal structure analysis shows that this barium copper(II) phosphate crystallizes in a monoclinic lattice with a = 12.160(4) ?, b = 5.133(4) ?, c = 6.885(4) ?, beta = 105.42(4) degrees, and V = 414.3(4) ?(3); C2/m (No. 12); Z = 2. The structure has been refined by the least-squares method to a final solution with R = 0.020, R(w) = 0.026, and GOF = 1.05. The framework of the title compound consists of [Cu(PO(4))(2)](infinity) linear chains with Ba(2+) cations residing between these parallel chains. The chains are composed of an array of Cu(2+) cations that are doubly bridged by PO(4) anions. Each pair of bridging PO(4) tetrahedra are in a staggered configuration above and below the CuO(4) square plane, resulting in a linear chain with a long Cu---Cu separation distance, 5.13 ? ( identical withb). This quasi-one-dimensional framework is unusual among the Cu(2+)-based phosphates. Magnetic susceptibility data shows Curie-Weiss paramagnetic behavior in the range of ca. 190-300 K and a possible antiferro-to-ferromagnetic transition at approximately 8 K. In this paper, the synthesis, structure, and properties of the title compound are presented. A structural comparison to a closely related vanadyl (VO)(2+) phosphate, Ba(2)(VO)(PO(4))(2).H(2)O, as well as Na(2)CuP(2)O(7) will be discussed. 相似文献
7.
Comparative properties of siloxane vs phosphonate monolayers on a key titanium alloy 总被引:2,自引:0,他引:2
Silverman BM Wieghaus KA Schwartz J 《Langmuir : the ACS journal of surfaces and colloids》2005,21(1):225-228
A direct comparison of surface loading, interface shear strength, and interface hydrolytic stability was made between a phosphonate and two siloxane monolayers formed on the native oxide surface of Ti-6Al-4V. Surface loading for the phosphonate was ca. four times greater (on a nanomole/area basis) than for the siloxanes; mechanical strengths per surface-bound molecule were comparable, but the hydrolytic stability (pH 7.5) of the siloxanes was poor. These results suggest that phosphonate monolayer interfaces are more desirable than comparable siloxane ones for applications where such interfaces contact even slightly alkaline water. 相似文献
8.
D. Gardner 《Analytica chimica acta》1980,119(1):167-169
The method developed earlier was found to suffer a loss in sensitivity when the magnesium perchlorate desiccant became damp. The most sensitive and consistent results were obtained when the magnesium perchlorate was removed from the sample injection manifold. Under most circumstances a desiccant is not required. 相似文献
9.
10.
Frabetti PL Cheung HW Cumalat JP Dallapiccola C Ginkel JF Greene SV Johns WE Nehring MS Butler JN Cihangir S Gaines I Garbincius PH Garren L Gourlay SA Harding DJ Kasper P Kreymer A Lebrun P Shukla S Bianco S Fabbri FL Sarwar S Zallo A Culbertson R Gardner RW Greene R Wiss J Alimonti G Bellini G Caccianiga B Cinquini L Di Corato M Giammarchi M Inzani P Leveraro F Malvezzi S Menasce D Meroni E Moroni L Pedrini D Perasso L Sala A Sala S Torretta D Vittone M Buchholz D Claes D Gobbi B O'Reilly B 《Physical review letters》1993,71(6):827-830