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排序方式: 共有640条查询结果,搜索用时 15 毫秒
1.
Multicomponent Na2V6O16.3H2O (barnesite) single-crystalline nanobelts were synthesized by a direct reaction-crystallization growth of bulk V2O5 and NaF powders under hydrothermal treatment without using any templates or catalysts. This new strategy could be extended to prepare other one-dimensional multicomponent nanomaterials including ammonium, alkali-metal or alkali-earth metal vanadium oxide bronzes and other transition metal oxyfluorides. This is an efficient and mild solution method with clear advantages over the traditional high-temperature approach for the large-scale production of 1D multicomponent nanomaterials. The applicability of this approach toward the preparation of other inorganic systems, such as tungstates and molybdates, will be explored. 相似文献
2.
We have successfully developed a new one-pot solution-phase route, namely microwave-assisted hydrothermal reduction/carbonization (MAHRC), for a rapid synthesis of coaxial Ag/C nanocables. The nanocables can self-assemble in situ in an end-to-end fashion into interconnected chains. 相似文献
3.
Francis Garnier Pierre Krausz Jacques-Emile Dubois 《Journal of organometallic chemistry》1979,170(2):195-201
The photoinduced metathesis [W(CO)6CCl4hν] of cis- and trans-RCH=CHMe gives 2-butene in a very high trans but low cis stereoselectivity. Propene behaves like a cis olefin. These results are consistent with the proposal of a dinuclear tungsten intermediate, which requires high steric constraints in the transalkylidenation step. 相似文献
4.
A method is presented to reduce the memory requirement of normal mode analysis applied to systems containing two or more large proteins when these systems exhibit symmetry properties. We use a rigid geometry model (i.e., only the dihedral angles of the polypeptide chain are considered as variables). This model allows a reduction by a factor of 8 on average of the number of variables with a concomitant freezing of the high-frequency modes. The symmetry properties of the system are used to reduce further the number of variables that must be considered in the computation. Application of group theory leads to a factorization of the matrices of interest (the coefficient and the Hessian matrices) into independent blocks along the diagonal. The initial, reducible representation is thus transformed into a number of irreducible representations of smaller dimensions. In the case of the C2 symmetry group, the method leads to a reduction of the size of the matrices that must be manipulated during the computation (coefficient matrix, Hessian matrix, and eigenvectors matrix) by a factor of 256 compared with the usual normal mode analysis in Cartesian coordinate space. The method is particularly well adapted to the study of the dynamics of oligomeric proteins because these proteins often display symmetry properties (e.g., virus coat proteins, immunoglobulins, hemoglobin, etc.). In favorable cases, in conjunction with X-ray diffuse scattering data, the study of systems showing allosteric properties might be considered. © 1994 by John Wiley & Sons, Inc. 相似文献
5.
Cyclopropanols 5, 6 and 2 with substituent groups (-CH2OH, -CH2OTs, -CH2Br) in the 1-position, and oxaspiropentane 8, have been prepared from methylenecyclopropane. Cyclopropanols with vinyl groups in the 1-position (1-vinyl 12, 1-cyclopentenyl 13 and 1-cyclohexenyl 14) and 1-cyclopropylcyclopropanol 20 have been prepared from 1, 3-dichloroacetone.Each of the compounds readily undergoes ring expansion to the corresponding cyclobutanones. The reaction provides a simple route to cyclobutanones, the parent ketone itself being easily obtained from oxaspiropentane 8. 相似文献
6.
Kohli BM Eng JK Nitsch RM Konietzko U 《Rapid communications in mass spectrometry : RCM》2005,19(5):589-596
In liquid chromatography/tandem mass spectrometry (LC/MS/MS) analyses of complex peptide mixtures, dynamic exclusion functions are used to minimize repeat selections of identical precursors for collision induced dissociation (CID). We describe a new algorithm for the dynamic exclusion of m/z values during LC/MS/MS. Full-scan based peak exclusion (Fulspec) uses a simplified model of chromatographic peak formation to detect and exclude contaminants present throughout the run or that lead to broad peaks. Therefore, instead of excluding peptides from fragment analysis according to a rigidly predefined time window, the chromatographic properties of the detected analytes are used. The algorithm was tested on two datasets derived from previously published experiments. Fulspec achieves a distribution of CID spectra with minimal tailing on the retention time axis, without resorting to rigid exclusion of m/z values. The procedure further excludes intensities with a bias towards low-quality CID spectra. This combination frees up valuable analytical capacity. The underlying intensity vs. quality analyses challenge the assumption that abundant precursors automatically give the best identifications. Further validation of the algorithm will require its incorporation by equipment manufacturers into the instrument control programs. 相似文献
7.
Wang X Yu JC Yip HY Wu L Wong PK Lai SY 《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,11(10):2997-3004
A novel metal/semiconductor nanocomposite with catalytic and photocatalytic functions has been prepared. The new material consists of highly dispersed platinum (Pt) nanoparticles embedded in a cubic mesoporous nanocrystalline anatase (meso-nc-TiO2) thin film. The porous thin film possesses a narrow pore-size distribution and a large surface area. The diameter of the Pt cluster can be controlled to below 5 nm, and the high dispersion of these clusters gives rise to catalytic activity for the oxidation of carbon monoxide, an important reaction for automobile exhaust treatment. This novel ordered mesoporous Pt/TiO2 nanoarchitecture is also a promising photochemical material, as demonstrated by the photo-driven killing of Micrococcus lylae cells on the film. 相似文献
8.
This paper reports a new method for preconcentration and separation of trace amounts of molybdenum in seawater samples prior to determination by inductively coupled plasma–atomic emission spectroscopy (ICP–OES). Diethylenetriaminetetraacetic acid-functionalized polysiloxane (DETAP) was synthesized by carboxymethylation of amino groups on triamine immobilized polymer, which was prepared by modification of 3-chloropropylpolysiloxane with diethylenetriamine. The resulting polysiloxane is highly selective and efficient in chelating Mo(VI) at trace levels. It can be used as a column packing material. The polysiloxane column can be reused over ten times without losing its original properties, so it is suitable for preconcentration of molybdenum species in seawater samples before determination. The parameters governing the characteristics of polysiloxane for adsorption of Mo(VI) were investigated. These include the effect of pH, amount of polysiloxane, equilibrium time, adsorption isotherm, maximum adsorption capacity, interfering ions, flow rate, capacity for reuse, and desorption. The precision of the preconcentration method, calculated as the relative standard deviation of seawater samples, was 3%. The preconcentration factor was 100. The detection limit, defined as 3 times the standard deviation of five replicate measurements of the blank sample at pH 3, was 0.17 g L–1. Measurement results for standard reference materials were in good agreement with the certified values [(CRMs), NASS-2 Seawater (Open Ocean) and CASS-2 Seawater (Coastal)]. 相似文献
9.
The binding of d- and l-tryptophan molecules to bovine serum albumin (BSA) protein has been studied using liquid chromatography and ultrafiltration in the pH range from 7 to 11. A hydrophobic interaction between tryptophan and BSA has been observed at pH 7.0 on BSA grafted chromatographic column. However, this interaction is negligible at higher pH for which the interaction to the stereospecific site was predominant. For both grafted and free proteins, the complexation mechanism was a competitive binding of d- and l-enantiomers on a single site. The apparent complexation constants for both d- and l-tryptophan show a maximum in the pH range 9-10. The variations of the apparent complexation constants versus pH were the result of the protonation of both the amino acid and a single site of the protein assuming that the complexation occurs between the zwitter-ionic amino acid form and the unprotonated BSA site. The apparent pK(BSA) is slightly shifted from 8.3 for grafted BSA protein to 9.4 for free BSA protein. This shift is presumably as a result of the different protein conformation. 相似文献
10.
Guillermina Burillo Takeshi Ogawa Jimmy S. Hwang 《Journal of polymer science. Part A, Polymer chemistry》1992,30(10):2159-2164
A number of diacetylene containing acrylate and methacrylates have been synthesized and the interaction between their propagating radicals and the diacetylene groups was studied by ESR spectroscopy. In the case of polymerization at 70°C using AIBN as an initiator, the propagating radicals of methacrylates are temporarily trapped with the diacetylenes with rapid exchange of the electron, thus showing strong signals of the propagating radicals. Gamma irradiation of the frozen state produces a blue color in samples, and the ESR signals were found to be those of uninteracted acrylate and methacrylates. From a comparison of spectral widths, there seems to exist an intramolecular interaction between the radicals and the diacetylene group at the frozen state. © 1992 John Wiley & Sons, Inc. 相似文献