全文获取类型
收费全文 | 231篇 |
免费 | 13篇 |
国内免费 | 11篇 |
专业分类
化学 | 166篇 |
力学 | 14篇 |
综合类 | 2篇 |
数学 | 13篇 |
物理学 | 60篇 |
出版年
2024年 | 4篇 |
2023年 | 4篇 |
2022年 | 8篇 |
2021年 | 11篇 |
2020年 | 7篇 |
2019年 | 17篇 |
2018年 | 12篇 |
2017年 | 4篇 |
2016年 | 3篇 |
2015年 | 15篇 |
2014年 | 8篇 |
2013年 | 10篇 |
2012年 | 9篇 |
2011年 | 16篇 |
2010年 | 5篇 |
2009年 | 7篇 |
2008年 | 20篇 |
2007年 | 13篇 |
2006年 | 9篇 |
2005年 | 8篇 |
2004年 | 6篇 |
2003年 | 5篇 |
2002年 | 7篇 |
2001年 | 3篇 |
2000年 | 5篇 |
1999年 | 4篇 |
1998年 | 4篇 |
1997年 | 2篇 |
1996年 | 2篇 |
1995年 | 5篇 |
1994年 | 2篇 |
1993年 | 2篇 |
1992年 | 2篇 |
1990年 | 2篇 |
1989年 | 3篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1981年 | 1篇 |
1980年 | 2篇 |
1978年 | 2篇 |
1973年 | 1篇 |
排序方式: 共有255条查询结果,搜索用时 31 毫秒
1.
H. Sato A. Tani A. J. Fielding S. S. Eaton G. R. Eaton N. E. Whitehead M. Ikeya 《Applied magnetic resonance》2004,26(4):601-616
Nitrate radical NO32− in calcitic evaporate was discovered in Antarctica. The distribution and formation of nitrate radical NO32− in the calcite have been studied by pulse and continuous-wave electron spin resonance. In samples that had been annealed
to destroy the NO32−, regeneration of the radical by γ-rays or UV light indicated that the radical was formed by UV light (with wavelengths less
than 340 nm) from solar rays, not by environmental radiation. The nonuniform spatial distribution of the nitrate radical,
which was deduced from high ratios of local spin density to total spin density, suggests that the nitrate impurity was introduced
into the calcium carbonate after carbonate grain formation. Formation of the carbonate-containing nitrate requires the presence
of high amounts of nitrate and a dry climate. Formation of the nitrate radical requires sample exposure to UV light. These
conditions are satisfied in the environment of Antarctica. 相似文献
2.
具有位相型修理的离散时间可修排队系统 总被引:1,自引:0,他引:1
本文研究了具有一般独立输入,位相型修理的离散时间可修排队系统,假定服务台对顾客的服务时间和服务台寿命服从几何分布,运用矩阵解析方法我们给出系统嵌入在到达时刻的稳态队长分布和等待时间分布,并证明这些分布均为离散位相型分布.我们也得到在广义服务时间内服务台发生故障次数的分布,证明它服从一个修正的几何分布.我们对离散时间可修排队与连续时间可修排队进行了比较,说明这两种排队系统在一些性能指标方面的区别之处.最后我们通过一些数值例子说明在这类系统中顾客的到达过程、服务时间和服务台的故障率之间的关系. 相似文献
3.
Smith RA Verlet JR Boleat ED Stavros VG Fielding HH 《Faraday discussions》2000,(115):63-70; discussion 79-102
Rydberg electron wavepackets have been studied in molecular NO for a variety of rotational states of the ion core. Predominantly radial motion of the electron wavepacket is observed which is similar to that previously reported in atomic systems. Interference effects similar to those observed in unperturbed Rydberg series are evident and third and fourth order partial revivals are identified. Most interestingly, when the classical period of electronic motion is close to the classical period of rotation of the molecular ion, the molecular dynamics dominates the electronic dynamics. 相似文献
4.
The complexes of cyclohexylacetic acid and cholic acid with beta-cyclodextrin were studied by NMR diffusion coefficient measurements. The diffusion coefficient of the 1:1 cyclohexylacetic acid/beta-cyclodextrin complex, K(a) = 1800 +/- 100 M(-1), is slightly slower (3.23 +/- 0.07 x 10(-6) cm(2) s(-1)) than that of beta-cyclodextrin (3.29 +/- 0.07 x 10(-6) cm(2) s(-1)). The diffusion coefficient of the 1:1 cholic acid/beta-cyclodextrin complex, K(a) = 5900 +/- 800 M(-1), is significantly slower (2.93 +/- 0.07 x 10(-6) cm(2) s(-1)) than that of beta-cyclodextrin. The results indicate that caution should be exercised when studying host-guest complexation by the so-called 'single point' technique. A novel data treatment is introduced which takes into account the diffusion behavior of all of the species when determining K(a). Experimentally determined diffusion coefficients of complexes are also a useful probe of the size of host-guest complexes. 相似文献
5.
正Molecular materials,together with metals,ceramics,and polymer materials,are among the most important materials.The research efforts on molecular materials are targeting three main aspects,namely the assembly technique,multi-functionality,and their diverse application.In this regard,the main attention from the community is focused on the identification and 相似文献
6.
It is the nature of crystals to exist in different polymorphs. The recent emergence of two-dimensional (2D) materials has evoked the discovery of a number of new crystal phases that are different from their bulk structures at ambient conditions, and revealed novel structure-dependent properties, which deserve in-depth understanding and further exploration. In this contribution, we review the recent development of crystal phase control in 2D materials, including group V and VI. transition metal dichalcogenides (TMDs), group IVA metal chalcogenides and noble metals. For each group of materials, we begin with introducing the various existing crystal phases and their structure-related properties, followed by a detailed discussion on factors that influence these crystal structures and thus the possible strategies for phase control. Finally, after summarizing the whole paper, we present the challenges and opportunities in this research direction. 相似文献
7.
Dr. Roberta Pievo Brigitta Angerstein Dr. Alistair J. Fielding Dr. Christian Koch Prof. Dr. Ivo Feussner Prof. Dr. Marina Bennati 《Chemphyschem》2013,14(18):4094-4101
Electron paramagnetic resonance (EPR) spectroscopy in combination with the rapid freeze‐quench (RFQ) technique is a well‐established method to trap and characterize intermediates in chemical or enzymatic reactions at the millisecond or even shorter time scales. The method is particularly powerful for mechanistic studies of enzymatic reactions when combined with high‐frequency EPR (ν≥90 GHz), which permits the identification of substrate or protein radical intermediates by their electronic g values. In this work, we describe a new custom‐designed micro‐mix rapid freeze‐quench apparatus, for which reagent volumes for biological samples as small as 20 μL are required. The apparatus was implemented with homemade sample collectors appropriate for 9, 34, and 94 GHz EPR capillaries (4, 2, and 0.87 mm outer diameter, respectively) and the performance was evaluated. We demonstrate the application potential of the RFQ apparatus by following the enzymatic reaction of PpoA, a fungal dioxygenase producing hydro(pero)xylated fatty acids. The larger spectral resolution at 94 GHz allows the discernment of structural changes in the EPR spectra, which are not detectable in the same samples at the standard 9 GHz frequency. 相似文献
8.
Poly(vinyl amine) (PVAm) was derivatised using 2-thiophenecarboxaldehyde via Michael addition to prepare a statistical copolymer stabiliser for the synthesis of primary amine-functionalised polypyrrole (PPy) particles. A minimum stabiliser concentration of around 20 % (w/v) relative to pyrrole was required for well-defined PPy particles of approximately 100–200 nm, as judged by transmission electron microscopy (TEM) and dynamic light scattering (DLS). FTIR spectroscopy confirmed that stabiliser grafting had occurred, while x-ray photoelectron spectroscopy (XPS) studies indicated a stabiliser surface coverage on the PPy particles of around 53 %. PPy particles prepared at stabiliser concentrations below 20 % (w/v) were not colloidally stable above pH 6. However, higher stabiliser concentrations (e.g., 50 % (w/v) based on pyrrole) led to a significant improvement, with colloidal stability being retained above pH 7. Long-term colloidal stability studies of PPy particles stored at pH 7.5 confirmed that the amine-based stabiliser produced more stable aqueous dispersions than the imine-based stabiliser, since the latter bond is hydrolytically unstable. 相似文献
9.
10.
Flat and crystalline materials with exceptional nonlinear optical(NLO) properties are highly desirable for their potential applications in integrated NLO photonic devices.Graphdiyne(GD),a new twodimensional(2 D) carbon allotrope,has recently evoked burgeoning research attention by virtue of its tunable bandgap along with a high carrier mobility and extended π-conjugation compared with most conventional optical materials.Here,we experimentally probe the third-order nonlinear optical response of GD dispersed in several common solvents(alcohols) using a femtosecond Z-scan technique.The measured nonlinear optical refractive index is in the order of ~10-8 cm2/W,which is approximately one order of magnitude higher than that of most 2 D materials.In particular,we find that different NLO responses can be observed from GD when dispersed in different solvents,with the strongest NLO response when dispersed in 1-propanol.It is proposed that some intrinsic properties of the solvents,such as the polarity and viscosity,could influence the NLO response of GD materials.Our experimental results confirm the assumptions on the NLO behavior in GD and demonstrate its great potential for future generations of Kerr-effect-based NLO materials and devices. 相似文献