Aqueous solvation dynamics at metal oxide surfaces

Broadband transient absorption (TA) spectroscopy, three-pulse photon echo peak shift (3PEPS), and anisotropy decay measurements were used to study the solvation dynamics in bulk water and interfacial water at ZrO(2) surfaces, using Eosin Y as a probe. The 3PEPS results show a multiexponential behavior with two subpicosecond components that are similar in bulk and interfacial water, while a third component of several picoseconds is significantly lengthened at the interface. The bandwidth correlation function from TA spectra exhibits the same behavior, and the TA spectra are well reproduced using the doorway-window picture with the time constants from PEPS. Our results suggest that interfacial water is restricted to a thickness of less than 5 A. Also the high-frequency collective dynamics of water does not seem to be affected by the interface. On the other hand, the increase of the third component may point to a slowing down of diffusional motion at the interface, although other effects, may play a role, which are discussed.     

Analysis of bifurcation phenomena in the electron internal transport barrier in the large helical device

The electron internal transport barrier (eITB) formation in the Large Helical Device (LHD) is studied with the transport code TOTAL and a GyroBohm-like model. The reduction of anomalous transport by the E x B shear has been introduced by means of the factor [1 + (tauomega(ExB))(gamma)](-1). Simulation results show a clear critical transition between plasma regimes with rather flat electron temperature profiles (non-) to a steeped one (with eITB) when average density is low enough. With the aim of studying the eITB formation as a phase transition phenomenon, the electron average density is taken as the control parameter and the E x B shearing rate as the order parameter. Results show how the eITB formation in LHD is compatible with a continuum phase transition with critical exponent beta = 0.40.     

Récurrence positive des librairies mixtes

Summary We establish necessary and sufficient condition of positive recurrence for a large class of Markov chains on permutations known as mixed libraries. This condition takes into account both geometrical and probabilistic properties of these chains.