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1.
Ozonolysis of a Series of Methylated Alkenes: Reaction Rate Coefficients and Gas‐Phase Products
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Tristan Braure Véronique Riffault Alexandre Tomas Romeo Iulian Olariu Cecilia Arsene Yuri Bedjanian Patrice Coddeville 《国际化学动力学杂志》2015,47(9):596-605
The gas‐phase ozonolysis of three methylated alkenes, i.e., trans‐2,2‐dimethyl‐3‐hexene (22dM3H), trans‐2,5‐dimethyl‐3‐hexene (25dM3H), and 4‐methyl‐1‐pentene (4M1P), has been investigated in the presence of sufficient hydroxyl radical scavenger in a laminar flow reactor at ambient temperature (296 ± 2 K) and P = 1 atm of dry air (RH ≤ 5%). Ozone levels in the reactor were monitored by an automatic analyzer. Alkene and gas‐phase product concentrations were determined via online sampling either on three‐bed adsorbent cartridges followed by thermodesorption and GC/FID‐MS analysis or on 2,4‐dinitrophenylhydrazine (DNPH) cartridges for subsequent HPLC/UV analysis. Reaction rate coefficients of (3.38 ± 0.12) × 10?17 for 22dM3H and (2.71 ± 0.26) × 10?17 for 25dM3H, both in cm3 molecule?1 s?1 units, have been obtained under pseudo–first‐order conditions. Primary carbonyl products have been identified for the three investigated alkenes, and branching ratios are reported. In the case of 4M1P ozonolysis, the yield of a Criegee intermediate was indirectly determined. Kinetics and product study results are compared to those of literature when available. This work represents the first investigation of reaction products in the ozonolysis of 22dM3H, 25dM3H, and 4M1P in a flow reactor. 相似文献
2.
Calin Iulian Martin 《Journal of Nonlinear Mathematical Physics》2015,22(4):516-522
This paper is devoted to the subsurface current dynamics in equatorial regions, where the hallmark of a strong stratification is a sharp interface (thermocline), separating two layers of different density, and whose depth is dependent upon the strength of the winds above the ocean's surface. We give here a few monotonicity results concerning the dynamics of the thermocline in the equatorial region. The most important one asserts that the level of the thermocline decreases as the strength of the wind at ten meters above the ocean surface, denoted |Uw|, increases. Moreover, the strength of the current at the thermocline decreases as |Uw| increases. 相似文献
3.
G. Benzoni F. Azaiez S. Leoni S. Battacharyya R. Borcea A. Bracco L. Corradi D. Curien G. De France Zs. Dombrádi E. Fioretto S. Franchoo S. Grevy F. Ibrahim S. Iulian G. Mukherjee A. Navin G. Pollarolo N. Redon P. H. Regan M. Rejmund C. Schmitt G. Sletten D. Sohler M. Stanoiu S. Szilner D. Verney 《The European physical journal. Special topics》2007,150(1):83-86
A study of deep-inelastic and multi-nucleon transfer reactions to populate neutron-rich
O, Ne and F nuclei is here presented. The reaction under analysis employed a beam of radioactive
24Ne at 7.9 AMeV, provided by the
SPIRAL facility at Ganil, impingin on a 208Pb target. The reaction products have been
detected in the VAMOS spectrometer in coincidence with gamma rays
measured by the EXOGAM array. Preliminary results here presented show a selectivity
in the population of states of different nature. 相似文献
4.
Dumitru Condrat Cristina Mosoarca Alina D. Zamfir Florin Cri?an Maria R. Szabo Alfa X. Lupea 《Central European Journal of Chemistry》2010,8(3):530-535
This study presents the results obtained from qualitative and quantitative analysis of gallic acid from hydro-alcoholic extracts
(methanol, ethanol) of plants from Plantae regnum. Plant qualitative analysis was performed using a novel mass spectrometric (MS) method based on fully automated chip-nanoelectrospray
ionization (nanoESI) high capacity ion trap (HCT) while quantitative analysis was carried out by high performance liquid chromatography
(HPLC). These methods were applied to Alchemilla vulgaris — common lady’s-mantle (aerial part), Allium ursinum — bear’s garlic (leaves), Acorus calamus — common sweet flag (roots), Solidago virga-aurea — goldenrod (aerial part). Obtained results indicated that methanol extracts (96%, 80%) have a gallic acid content ranging
between 0.0011–0.0576 mg mL−1 extract while the ethanol extracts (96%, 60%) exhibit a gallic acid concentration that varies between 0.0010–0.0182 mg mL−1 extract.
相似文献
5.
The paper analyses the effect of normal contact with friction on the generation of full band-gaps in sonic composites. The behavior of contact interfaces are computed by using LISA (local interaction simulation approach). LISA is an efficient tool for numerical simulation of the acoustic wave propagation in heterogeneous material specimens, in particular those with contact interfaces between different materials, like in sonic composites. (© 2014 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
6.
In this paper we construct small-amplitude periodic capillary-gravity water waves with a piecewise constant vorticity distribution. They describe water waves traveling on superposed linearly sheared currents that have different vorticities. This is achieved by associating to the height function formulation of the water wave problem a diffraction problem where we impose suitable transmission conditions on each line where the vorticity function has a jump. The solutions of the diffraction problem, found by using local bifurcation theory, are the desired solutions of the hydrodynamical problem. 相似文献
7.
We report on various integration schemes of infrared microbolometers with microstrip antennas. The first integration design consists of two gold (Au) rectangular microstrip patches coupled along the radiating edges by a narrow niobium (Nb) strip. Devices using silicon oxide are compared to devices using amorphous silicon as antenna substrate. An extension of the twin-patch detector design is the microstrip dipole antenna-coupled microbolometer. Two ways of connecting the device to the contact pads via narrow dc leads are presented and compared. The contribution of the dc leads to the detector response is eliminated by directly connecting the dipole to the contact pads. The thermal isolation of the microbolometer from the silicon wafer is improved by incorporating air into the antenna dielectric substrate. This leads to higher detector responsivity and shifts the resonance towards longer antennas. The implementation of a bridge microstrip dipole antenna structure is also discussed. 相似文献
8.
Calin Iulian Martin 《Applicable analysis》2017,96(7):1207-1214
This paper is concerned with the governing equations (together with the free boundary and the bottom boundary conditions) for an inviscid, incompressible fluid, written in spherical coordinates which are fixed at a point on the rotating Earth. For a special type of a steady flow moving only in the azimuthal direction, with no variation in this direction, we provide a functional-analytic study of the link between the pressure at the free surface of the ocean and the distortion of that surface. 相似文献
9.
Iulian Rusu Daniel Sutiman Gabriela Lisa Daniel Mareci Nicoleta Melniciuc Puică 《Journal of Thermal Analysis and Calorimetry》2011,104(2):423-430
The aim of this study was to investigate the effects of immersion time on the electrochemical corrosion behaviour of three
brass alloys (CuZn) coming from religious artefacts in simulated acid rain at 25 °C, utilising the electrochemical impedance
spectroscopy (EIS). The main parameters of the corrosion process were established. On the other hand, the alloys were also
analysed by means DSC and TG/DTA before and after immersion in the corrosive environment. Finally, the obtained results were
compared in order to correlate them with each other and with the corrosion process. 相似文献
10.
Iulian Preda Leonardo Soriano Daniel Díaz‐Fernández Guillermo Domínguez‐Cañizares Alejandro Gutiérrez Germán R. Castro Jesús Chaboy 《Journal of synchrotron radiation》2013,20(4):635-640
This work reports an X‐ray absorption near‐edge structure (XANES) spectroscopy study at the Ni K‐edge in the early stages of growth of NiO on non‐ordered SiO2, Al2O3 and MgO thin films substrates. Two different coverages of NiO on the substrates have been studied. The analysis of the XANES region shows that for high coverages (80 Eq‐ML) the spectra are similar to that of bulk NiO, being identical for all substrates. In contrast, for low coverages (1 Eq‐ML) the spectra differ from that of large coverages indicating that the local order around Ni is limited to the first two coordination shells. In addition, the results also suggest the formation of cross‐linking bonds Ni—O—M (M = Si, Al, Mg) at the interface. 相似文献