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1.
R. S. Ismagilov 《Mathematical Notes》1997,62(2):186-197
We present simple proofs of the possibility of embedding ultrametric spaces in Hilbert spaces. The main part of the paper
deals with ultrametric spaces that we call totally infinite spaces. Related Hilbert spaces, automorphisms of totally infinite
spaces, and the corresponding linear operators are considered.
Transplated fromMatematicheskie Zametki, Vol. 62, No. 2, pp. 223–237, August, 1997.
Translated by V. E. Nazaikinskii 相似文献
2.
3.
V. I. Zaikovskii A. V. Vosmerikov V. F. Anufrienko L. L. Korobitsyna E. G. Kodenev G. V. Echevskii N. T. Vasenin S. P. Zhuravkov E. V. Matus Z. R. Ismagilov V. N. Parmon 《Kinetics and Catalysis》2006,47(3):389-394
The MoZSM-5 (4.0 wt % Mo) catalyst has been characterized by high-resolution transmission electron microscopy, EDXA, and EPR. Two types of molybdenum-containing particles are stabilized in the catalyst in the course of nonoxidative methane conversion at 750°C. These are 2-to 10-nm molybdenum carbide particles on the zeolite surface and clusters smaller than 1 nm in zeolite channels. According to EPR data, these clusters contain the oxidized molybdenum form Mo5+. The surface Mo2C particles are deactivated at the early stages of the reaction because of graphite condensation on their surface. Methane is mainly activated on oxidized molybdenum clusters located in the open molecular pores of the zeolite. The catalyst is deactivated after the 420-min-long operation because of coke buildup on the zeolite surface and in the zeolite pores. 相似文献
4.
This paper characterizes the conditions required to form nanoliter-sized droplets (plugs) of viscous aqueous reagents in flows of immiscible carrier fluid within microfluidic channels. For both non-viscous (viscosity of 2.0 mPa s) and viscous (viscosity of 18 mPa s) aqueous solutions, plugs formed reliably in a flow of water-immiscible carrier fluid for Capillary number less than 0.01, although plugs were able to form at higher Capillary numbers at lower ratios of the aqueous phase flow rate to the flow rate of the carrier fluid (in all the experiments performed, the Reynolds number was less than 1). The paper also shows that combining viscous and non-viscous reagents can enhance mixing in droplets moving through straight microchannels by providing a nearly ideal initial distribution of reagents within each droplet. The study should facilitate the use of this droplet-based microfluidic platform for investigation of protein crystallization, kinetics, and assays. 相似文献
5.
Tsykoza L. T. Ismagilov Z. R. Ushakov V. A. Kuznetsov V. V. Ovsyannikova I. A. 《Kinetics and Catalysis》2003,44(6):806-812
The phase composition of supported Mn–Al–O catalysts and their activity in the reaction of methane oxidation were studied depending on the composition of aluminum oxide supports (-Al2O3 with different -Al2O3 contents modified with individual Mg, La, and Ce oxides or Mg + La and Mg + Ce oxide mixtures) and calcination temperatures (500, 900, and 1300°C). It was found that the Mn–Al–O catalysts based on -alumina containing -Al2O3 and modified with Mg, La, or Ce additives are more active and thermally stable (up to 1300°C) than the samples based on pure -Al2O3. A conclusion was drawn that a higher degree of disorder of the structure of -Al2O3, compared to that of -Al2O3, is favorable for a deeper interaction of manganese and modifying additives with the support at the early stages of the synthesis and for the formation of Mn–Al compounds with complex composition (solid solutions and/or hexaaluminates) at 1300°C. These compounds are responsible for the stability and high activity of the catalysts in methane oxidation. 相似文献
6.
R. K. Ismagilov V. V. Moskva L. M. Shamsutdinova 《Russian Journal of General Chemistry》2005,75(3):379-380
Procedures for preparing α-phosphorylated 4-methylpyrocatechols were developed. Diphenyl-(3,4-dimethoxybenzyl)phosphine oxide yields diphenyl(3,4-dihydroxybenzyl)phosphine oxide under the action of hydrobromic acid.__________Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 3, 2005, pp. 415–416.Original Russian Text Copyright © 2005 by Ismagilov, Moskva, Shamsutdinova. 相似文献
7.
N. S. Tereschenko D. A. Arendarskii Z. R. Ismagilov N. F. Simonova 《Reaction Kinetics and Catalysis Letters》1986,31(2):321-325
IR spectroscopy was employed to study acid properties of a series of alumina samples different in the phase composition and in the porous structure. The comparison of the surface acidity with the data on the quantitative formation of Cl– during the interaction of CCl4 with alumina indicates that the extent of chlorination of the samples tends to increase with increasing the surface acidity.
- , . Cl– CCl4 , .相似文献
8.
A. B. Radbil’ R. M. Ismagilov B. A. Radbil’ 《Russian Journal of Applied Chemistry》2005,78(2):286-290
Preparation of thermally curable emulsion binders for mold cores and molds using tall pitch was studied. Preparation conditions, composition, and colloid-chemical properties of the resulting emulsions were investigated.__________Translated from Zhurnal Prikladnoi Khimii, Vol. 78, No. 2, 2005, pp. 292–296.Original Russian Text Copyright © 2005 by A. Radbil’, Ismagilov, B. Radbil’. 相似文献
9.
S. F. Ruzankin V. F. Anufrienko S. A. Yashnik Z. R. Ismagilov 《Journal of Structural Chemistry》2006,47(3):404-412
This paper reports on quantum-chemical analysis of the linear structure of CuCl2 by Hartree-Fock (HF) and density functional theory (DFT) methods and also by time-dependent HF (TD HF) and DFT (TD DFT) techniques. Using pure DFT exchange correlation functional (B3LYP) yields the best agreement with the experimental electronic spectra of CuCl2. In this case, the odd electron is delocalized over the molecule, spin density on copper being 0.27. The ground state of the CuCl2 molecule is 2Πg with linear geometry. 相似文献
10.