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排序方式: 共有58条查询结果,搜索用时 15 毫秒
1.
Manol Ognyanov Petko Denev Desislava Teneva Yordan Georgiev Sabina Taneva Iskra Totseva Mariana Kamenova-Nacheva Yana Nikolova Svetlana Momchilova 《Molecules (Basel, Switzerland)》2022,27(6)
Gamma irradiation is efficiently applied to many foods, but nevertheless there is a distinct lack of information about the changes of macro- and micronutrients (e.g., carbohydrates, lipids, organic acids, and phenolics) in dried rose hip (RH) fruits. Therefore, in this study, for the first time, the effect of gamma irradiation (10 and 25 kGy) on RH constituents is investigated. Different analytical techniques (GC-FID, HPLC-UV, HPSEC-RID, IR-FT, and SEM) are employed to examine this effect. The irradiation treatment (10 kGy) increased the glucose content by 30% and released cellobiose from RH fruits, thus revealing cellulose destruction. The extractability of total uronic acids increased from 51% (control) to 70.5% (25 kGy-irradiated), resulting in a higher pectin yield (10.8% < 12.8% < 13.4%) and molecular heterogeneity. Moreover, de-esterification was not a major effect of the irradiation-induced degradation of pectin. The sample exposure to the highest dose did not change the content of total carotenoids, β-carotene, and (un)saturated fatty acids, but it affected the tocopherols levels. Gamma rays had a negligible effect on the phenolic constituents and did not affect ORAC and HORAC antioxidant activity. In conclusion, it can be compromised that the exposition of dried RH is safe and can be successfully applied to decontaminate fruits without affecting their nutritional value and biological activity. 相似文献
2.
Fluorous solvent was used for passive transport of molecular chlorine from one side of the U-tube to the other, where addition of chlorine to alkenes was quantitative and diffusion controlled. 相似文献
3.
Hanć A Komorowicz I Iskra M Majewski W Barałkiewicz D 《Analytical and bioanalytical chemistry》2011,399(9):3221-3231
The study was aimed to evaluate the influence of the vascular disease, atherosclerotic obliterans (AO), on the location and
concentration of elements in the arterial wall and serum. Use of a modern method for studying element’s concentration and
distribution in samples of clinical material, i.e. laser ablation inductively coupled plasma mass spectrometry, is presented.
Elements are not equally distributed between the inner (intima) and the outer (media + adventitia) layer of the arterial wall.
Among the studied elements, calcium was found to have an unquestionable role in the calcification of the wall. Increased concentration
of calcium found in the inner part of the atherosclerotic arterial wall and in the plaque, as compared to the control arterial
wall samples, demonstrates the unquestionable role of this element in the calcification of the wall observed in AO. Applied
chemometric methods were useful for demonstrating the differences in the element’s concentration in blood serum and the arterial
wall samples between AO and the control group. 相似文献
4.
V. D. Iskra 《Russian Physics Journal》1987,30(2):126-130
A calculation is performed and estimates made of the binary correlation functions of the random field produced by the difference in the atomic pseudopotentials of solvent and dissolved materials. Also evaluated are elastic deformation fields in unordered Ge-Si solid replacement solutions with low Si content (up to 10 at. %).Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 2, pp. 41–46, February, 1987.The author heartily thanks V. L. Bonch-Bruevich for his interest in the current study and many valuable discussions. 相似文献
5.
V. D. Iskra 《Russian Physics Journal》1985,28(9):733-738
Scattering amplitude in the field of a short-range force center is calculated using factorization of the potential. The results obtained are used to study the temperature dependence of charge-carrier mobility in the random field of chaotically distributed structural point defects.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 9, pp. 50–57, September, 1985.In conclusion, the author sincerely thanks V. L. Bonch-Burevich for his interest in the study and most valuable discussions. 相似文献
6.
V. D. Iskra 《Russian Physics Journal》1984,27(11):977-980
A relationship is obtained expressing the binary correlation function of an intrinsic random field in a spatially inhomogeneous semiconductor in terms of the atomic pseudopotentials and a factor determined by the binary correlation functions of the atoms.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 11, pp. 75–78, November, 1984.In conclusion, the author is grateful to V. L. Bonch-Bruevich and M. A. Krivoglaz for a number of useful discussions. 相似文献
7.
V. D. Iskra 《Russian Physics Journal》1984,27(11):981-984
The nature of the intrinsic random field of a heteropolar semiconductor with microcrystalline structure is investigated and the frequency dependence is determined for the light absorption coefficient in the tail domain, which is due to this field.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 11, pp. 78–82, November, 1984.The author is grateful to V. L. Bonch-Bruevich for useful discussion of the research. 相似文献
8.
9.
Oriol Piqu Iskra Z. Koleva Francesc Vies Hristiyan A. Aleksandrov Georgi N. Vayssilov Francesc Illas 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(6):1758-1762
Carbon moieties on late transition metals are regarded as poisoning agents in heterogeneous catalysis. Recent studies show the promoting catalytic role of subsurface C atoms in Pd surfaces and their existence in Ni and Pt surfaces. Here energetic and kinetic evidence obtained by accurate simulations on surface and nanoparticle models shows that such subsurface C species are a general issue to consider even in coinage noble‐metal systems. Subsurface C is the most stable situation in densely packed (111) surfaces of Cu and Ag, with sinking barriers low enough to be overcome at catalytic working temperatures. Low‐coordinated sites at nanoparticle edges and corners further stabilize them, even in Au, with negligible subsurface sinking barriers. The malleability of low‐coordinated sites is key in the subsurface C accommodation. The incorporation of C species decreases the electron density of the surrounding metal atoms, thus affecting their chemical and catalytic activity. 相似文献
10.
Dong Gun Oh Prof. Hristiyan A. Aleksandrov Haneul Kim Dr. Iskra Z. Koleva Dr. Konstantin Khivantsev Prof. Georgi N. Vayssilov Prof. Ja Hun Kwak 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(49):e202200684
Pd-based catalysts are the most widely used for CO oxidation because of their outstanding catalytic activity and thermal stability. However, fundamental understanding of the detailed catalytic processes occurring on Pd-based catalysts under realistic conditions is still lacking. In this study, we investigated CO oxidation on metallic Pd clusters supported on Al2O3 and SiO2. High-angle annular dark-field scanning transmission electron microscopy revealed the formation of similar-sized Pd clusters on Al2O3 and SiO2. In contrast, CO chemisorption analysis indicated a gradual change in the dispersion of Pd (from 0.79 to 0.2) on Pd/Al2O3 and a marginal change in the dispersion (from 0.4 to 0.24) on Pd/SiO2 as the Pd loading increased from 0.27 to 5.5 wt %; these changes were attributed to differences in the metal-support interactions. Diffuse reflectance infrared Fourier-transform spectroscopy revealed that fewer a-top CO species were present in Pd supported on Al2O3 than those in Pd supported on SiO2, which is related to the morphological differences in the metallic Pd clusters on these two supports. Despite the different dispersion profiles and surface characteristics of Pd, O2 titration demonstrated that linearly bound CO (with an infrared signal at 2090 cm−1) reacted first with oxygen in the case of CO-saturated Pd on Al2O3 and SiO2, which suggests that a-top CO on the terrace site plays an important role in CO oxidation. The experimental observations were corroborated by periodic density functional calculations, which confirmed that CO oxidation on the (111) terrace sites is most plausible, both kinetically and thermodynamically, compared to that on the edge or corner sites. This study will deepen the fundamental understanding of the effect of Pd clusters on CO oxidation under reaction conditions. 相似文献