Influence of Gold Nanoparticle Film Porosity on the Chemiresistive Sensing Performance

The porosity of 1‐hexanethiol‐functionalised gold nanoparticle films was assessed and utilised as chemiresistor sensors. Electrochemical capacitance measurements showed that the accessibility of electrolytes of different ionic strengths into the pores depended on the thickness of the electric double layer formed. A large variation in capacitance was measured in 0.01–1000 mM NaClO₄, implying a wide pore size distribution. The change in morphology of the nanoparticle films upon storage in air, water and ethanol for two weeks was investigated. There was a significant decrease in the electrochemical capacitance at high electrolyte concentrations for the ethanol‐stored films compared to the freshly‐prepared films suggesting a decrease in the number of small pores of radii in the range of 0.3–3 nm. This was further supported by optical topographical measurements where a decrease in the thickness of ethanol‐stored films was observed relative to the freshly‐prepared films. The porous nature of the nanoparticle films was found to have an effect on the chemical sensing behaviour. When used as chemiresistor sensors, for the detection of heptane in water, the ethanol‐stored films provided larger resistance changes and longer response times. This suggests that the more densely packed ethanol‐stored films provided more sites that enabled film swelling, and that diffusion of the analyte occurred through the narrower water‐filled pores. This demonstrates the effect of different storage conditions on film morphology and subsequently sensor response.     

Quasi-degenerate neutrinos and lepton flavor violationin supersymmetric models

In supersymmetric models the misalignment between fermion and sfermion families introduces unsuppressed flavor-changing processes. Even if the mass parameters are chosen to give no flavor violation, family dependent radiative corrections make this adjustment not stable. We analyze the rate of in SUSY-GUT models with three quasi-degenerate neutrinos and universal scalar masses at the Planck scale. We pay special attention to a recently proposed scenario where the low-energy neutrino mixings are generated from identical quark and lepton mixings at large scales. We show the following. (i) To take universal slepton masses at the GUT scale is a very poor approximation, even in no-scale models. (ii) For large neutrino Yukawa couplings the decay would be observed in the planned experiment at PSI. (iii) For large values of the tau coupling gives important corrections, pushing and to accessible rates. In particular, the non-observation of these processes in the near future would exclude the scenario with unification of quark and lepton mixing angles. (iv) The absence of lepton flavor violating decays in upcoming experiments would imply a low value of , small neutrino couplings, and large ( GeV) SUSY-breaking masses.     

Integrated STEM in practice: Learning from Montessori philosophies and practices

In theory, STEM (interdisciplinary science, technology, engineering and mathematics) is cross‐disciplinary and situated in real‐world problem‐solving contexts. In practice, STEM disciplines are often implemented separately using contrived contexts. This paper examines theoretical and empirical aspects of Montessori middle school science in the United States, and its alignment with the conceptual framework of integrated STEM. We selected Montessori adolescent environments because the Montessori philosophy involves interdisciplinary application contextualized in purposeful work and learning. Our research sought to investigate how Montessori middle schools have designed their science programs, and to situate these findings within the current landscape of STEM education and reform‐based science. Based on the results of our survey of 96 U.S. Montessori middle schools, we argue Montessori offers an integrated educational approach that meaningfully situates academic disciplines to mirror local and global challenges, well supported by theory and literature on STEM and situated learning theories. We assert that integrated STEM happens organically in many Montessori middle schools, and takes place through authentic work in communities of practice. Our research communicates the value of looking outside traditional school settings to examine alternative formal education spaces, like Montessori classrooms where integrated STEM happens organically.     

Influence of MgO surface conditions on the in-plane crystal orientation and critical current density of epitaxial YBCO films

The effect of magnesium oxide (MgO) surface conditions on in-plane grain orientation and critical current density of epitaxial YBa₂Cu₃O₇ (YBCO) films was systematically investigated. The MgO substrates were either “as received” or stored for some time, cleaned using different methods and lithographically prepared for our step-edge junction devices. The YBCO films were grown via reactive thermal co-evaporation by Theva, GmbH. The surface characterisation of MgO substrates was studied using X-ray photoelectron spectroscopy (XPS). The in-plane grain orientation of the YBCO films was studied by means of X-ray diffraction (XRD) φ-scan and the critical current density was measured for the XRD scanned samples. The surface condition of the MgO substrates was found to have a strong influence on the in-plane grain orientation and the critical current density of the YBCO films. The MgO substrates with a degraded or contaminated surface gave rise to 45° grain misorientation in YBCO films and reduced the critical current density. A final process step using a low energy Ar ion beam etching (IBE) of the MgO substrates prior to the YBCO film deposition was found effective in removing the in-plane grain misorientation and promoting the growth of perfectly aligned c-axis YBCO films.     

Setting gates for activities in the stochastic project scheduling problem through the cross entropy methodology

This paper addresses the problem of scheduling activities in projects with stochastic activity durations. The aim is to determine for each activity a gate—a time before it the activity cannot begin. Setting these gates is analogous to setting inventory levels in the news vendor problem. The resources required for each activity are scheduled to arrive according to its gate. Since activities’ durations are stochastic, the start and finish time of each activity is uncertain. This fact may lead to one of two outcomes: (1) an activity is ready to start its processing as all its predecessors have finished, but it cannot start because the resources required for it were scheduled to arrive at a later time. (2) The resources required for the activity have arrived and are ready to be used but the activity is not ready to start because of precedence constraints. In the first case we will incur a “holding” cost while in the second case, we will incur a “shortage” cost. Our objective is to set gates so as to minimize the sum of the expected holding and shortage costs. We employ the Cross-Entropy method to solve the problem. The paper describes the implementation of the method, compares its results to various heuristic methods and provides some insights towards actual applications.     

TeV strings and the neutrino-nucleon cross section at ultrahigh energies

In scenarios with the fundamental unification scale at the TeV one expects string excitations of the standard model fields at accessible energies. We study the neutrino-nucleon cross section in these models. We show that duality of the scattering amplitude forces the existence of a tower of massive leptoquarks that mediate the process in the s channel. Using the narrow-width approximation we find a sum rule for the production rate of resonances with different spin at each mass level. We show that these contributions can increase substantially the standard model neutrino-nucleon cross section, although they seem insufficient to explain the cosmic ray events above the Greisen-Zatsepin-Kuz'min cutoff energy.     

Predetermined intervals for start times of activities in?the?stochastic project scheduling problem

This paper proposes a new methodology to schedule activities in projects with stochastic activity durations. The main idea is to determine for each activity an interval in which the activity is allowed to start its processing. Deviations from these intervals result in penalty costs. We employ the Cross-Entropy methodology to set the intervals so as to minimize the sum of the expected penalty costs. The paper describes the implementation of the method, compares its results to other heuristic methods and provides some insights towards actual applications.     

Setting gates for activities in the stochastic project scheduling problem through the cross entropy methodology

This paper addresses the problem of scheduling activities in projects with stochastic activity durations. The aim is to determine for each activity a gate—a time before it the activity cannot begin. Setting these gates is analogous to setting inventory levels in the news vendor problem. The resources required for each activity are scheduled to arrive according to its gate. Since activities’ durations are stochastic, the start and finish time of each activity is uncertain. This fact may lead to one of two outcomes: (1) an activity is ready to start its processing as all its predecessors have finished, but it cannot start because the resources required for it were scheduled to arrive at a later time. (2) The resources required for the activity have arrived and are ready to be used but the activity is not ready to start because of precedence constraints. In the first case we will incur a “holding” cost while in the second case, we will incur a “shortage” cost. Our objective is to set gates so as to minimize the sum of the expected holding and shortage costs. We employ the Cross-Entropy method to solve the problem. The paper describes the implementation of the method, compares its results to various heuristic methods and provides some insights towards actual applications.     

Cosmogenic neutrinos and signals of TeV gravity in air showers and neutrino telescopes

The existence of extra dimensions allows the possibility that the fundamental scale of gravity is at the TeV. If that is the case, gravity could dominate the interactions of ultrahigh energy cosmic rays. In particular, the production of microscopic black holes by cosmogenic neutrinos has been estimated in a number of papers. We consider here gravity-mediated interactions at larger distances, where they can be calculated in the eikonal approximation. We show that for the expected flux of cosmogenic neutrinos these elastic processes give a stronger signal than black hole production in neutrino telescopes. Taking the bounds on the higher-dimensional Planck mass M(D) (D=4 + n) from current air shower experiments, for n=2(6) elastic collisions could produce up to 118 (34) events per year at IceCube. On the other hand, the absence of any signal would imply a bound of M(D) > or approximately 5 TeV.