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排序方式: 共有361条查询结果,搜索用时 15 毫秒
1.
Miyuki Harada Kentaro Aoyama Mitsukazu Ochi 《Journal of Polymer Science.Polymer Physics》2004,42(22):4044-4052
A liquid‐crystalline epoxy resin was cured at two different temperatures. The phases of the cured systems clearly showed isotropic and nematic polydomain structures, which depended on the curing temperature. The fracture toughness of the systems was measured, and the fracture mechanism was investigated with polarized IR measurements. The nematic polydomain structure system showed considerably higher fracture toughness than the isotropic structure. Moreover, both systems exhibited a reorientation of the network chains near the fracture surface during the fracture process, and the region of the network reorientation in the nematic polydomain structure system was larger than that in the isotropic structure system. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 4044–4052, 2004 相似文献
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Structure-activity relationships of a new antifungal imidazole, AFK-108, and related compounds 总被引:1,自引:0,他引:1
Hori K Sakaguchi A Kudoh M Ishida K Aoyama Y Yoshida Y 《Chemical & pharmaceutical bulletin》2000,48(1):60-64
Fungicidal activity of widely used imidazole antifungal drugs in topical applications is not so strong in spite of their fungistatic activities against dermatophytes and pathogenic yeasts. In order to improve fungicidal activity of imidazole antifungal agents, a series of novel imidazole derivatives having a hydrophobic substituent derived from isoprenoid were synthesized. The efficacy of these compounds was evaluated with respect to direct cell-membrane damaging activity, ergosterol biosynthesis inhibition, minimum growth-inhibitory concentration (MIC) and therapeutic effect for experimental dermatophytosis of guinea pigs. Among the newly synthesized compounds, the geranyl derivative named AFK-108 (2a) showed the highest in vivo fungicidal activity with both cell membrane damaging activity and ergosterol biosynthesis inhibition in vitro. 相似文献
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The free-radical-induced reactions of cyclohexene oxide in the presence of maleic anhydride have been found to lead to polyether in presence of AIBN and to a mixture of polyether, ester, and maleic anhydride adduct of polyether with di-tert-butyl peroxide (DTBP), the amounts of the mixture components depending on the concentration of DTBP and the temperature. Analogous reactions in the presence of succinic anhydride lead to no polyether. The obtained polyether has no hydroxyl group. The reaction appears to consist of three different steps, radical initiation, cationic propagation, and radical termination. 相似文献
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We have previously established a rapid catechol-O-methyltransferase (COMT) assay using norepinephrine (NE) as a natural substrate and flow-injection analysis. In this study, the method is improved for screening of COMT inhibitors or activators using reversed-phase high-performance liquid chromatographic separation with fluorescence detection. The excess substrate, NE, was removed by the addition of borate in the eluent for HPLC to make an ionic complex with NE, which was eluted faster than the enzymatic product, normetanephrine. The method had good precision and accuracy, and was able to assay one sample in 5 min, showing the usability for screening of COMT inhibitors or activators. 相似文献
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Hisanobu Ogoshi Kazurni Saita Ken-ichi Sakurai Takamichi Watanabe Hiroo Toi Yasuhiro Aoyama 《Tetrahedron letters》1986,27(52):6365-6368
Described is the preparation of chiral octaethylporphyrin derivatives having two 2-substituted naphthyl groups in a trans orientation at the 5- and 15-meso positions and formyl or hydroxymethyl or alkoxymethyl group derived therefrom at the 10-meso position. One of the derivatives has been successfully resolved into enantiomers by means of HPLC. 相似文献
9.
K. Hirose T. Miyao M. Aoyama Y. Igarashisnm> 《Journal of Radioanalytical and Nuclear Chemistry》2002,252(2):293-299
Plutonium isotopes in the Sea of Japan were determined to assess radioactive contamination. Concentrations of 239,240Pu in surface water of the Sea of Japan were maintained at a constant level over the past two decades in contrast to 137Cs. A median value of surface 239,240Pu in the Sea of Japan in this period was 5.6 mBq/m3 with the range between 2.1 and 14.0 mBq/m3, which is slightly higher than that in the western North Pacific. The vertical distribution of 239,240Pu showed a surface minimum, a subsurface maximum and gradual decrease with increasing depth. The 241Pu/239,240Pu activity ratios in water columns were almost constant except for surface water. In regard to 239,240Pu in surface water of the Sea of Japan, these findings suggest that rapid recycling of deeper plutonium occurs in the Sea of Japan due to deep convection in winter and biogeochemical processes such as particle scavenging and remineralization. 相似文献
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The present plutonium levels in the Pacific Ocean are summarized. The 239,240Pu concentrations in surface seawaters in the early 2000s were in the range of 1.5 to 9.2 mBq·m−3 in the North Pacific and 0.8 to 4.1 mBq·m−3 in the South Pacific. There is no marked difference of surface 239,240Pu distributions between the North and South Pacific subtropical gyres. The vertical profile of 239,240Pu in the South Pacific was the similar pattern to that in the North Pacific, which is controlled by biogeochemical processes.
The 239,240Pu inventories (down to 2300 m) in the North Pacific are generally greater than that in the South Pacific, which reflects
the geographical distribution of global fallout and effect of close-in fallout in the Marshall Islands. 相似文献