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1.
The quasiclassical trajectory calculation of the I + HI collision is performed in order to study the exchange and endothermic reaction channels. The rate constant of the exchange reaction I′ + HI → HI′ + I is found to be equal to 7.7 × 1011 cm3/mol s at room temperature of 300 K. The study of the endothermic reaction I + HI → H + I2 shows that it takes place only in configurations with large bend angles. Due to the non-collinear character of this reaction its threshold (2 eV) exceeds significantly the threshold of the minimal energy (collinear) reaction path (1.55 eV). 相似文献
2.
Bond IA Budding E Conway MJ Fenton KB Fujii H Fujii Z Fujimoto M Hasegawa H Hayashida N Honda M Hotta N Humble JE Kabe S Kasahara K Kifune T Masaike A Matsubara Y Mitsui K Miura Y Mori M Murakami K Muraki Y Nagano M Nakamura K Nakamura T Norris PM Ohashi Y Okada A Saito T Sakata M Sato H Shibata S Shima M Storey JR Tanimori T Teshima M Torii S Uchino K Watase Y Woodhams MD Yamamoto Y Yock PC Yuda T 《Physical review letters》1988,61(20):2292-2295
3.
Hossein A. Oskooie Majid M. Heravi Khadijeh Bakhtiari Shima Taheri 《Monatshefte für Chemie / Chemical Monthly》2007,138(9):875-877
Summary. A facile synthesis of quinoxaline derivatives catalyzed by KHSO4 in very high yields at room temperature is reported. 相似文献
4.
(Styrene-p-chlorostyrene) triblock copolymers of the ABA and BAB types (A—polystyrene; B—poly-p-chlorostyrene) were prepared by anionic polymerization and their conformational behaviours in solutions were studied from measurements of the dipole moments. Two solvents, toluene and cumene, were used for the study; toluene is a good solvent for both polystyrene and poly-p-chlorostyrene whereas cumene is a selective solvent, good for polystyrene but poor for poly-p-chlorostyrene. It was found that the dipole moments of the block copolymers measured in toluene are the same for the ABA and BAB copolymers; in cumene however the dipole moment of the BAB copolymer is smaller than that of the ABA copolymer. The results give an additional support to our previous conclusion that the conformation of the block copolymers in a good solvent such as toluene could be approximated with a pseudo-random coil form; in a selective solvent, however, some anomalies take place in the conformation of the block copolymers, as deduced from intrinsic viscosity, osmotic pressure and light scattering measurements. 相似文献
5.
The reaction of titanium isopropoxide with a Schiff base ligand containing an isobutenyl linker leads to double stranded dinuclear titanium(IV)-Schiff base complexes through self-assembly with concomitant formation of intramolecular mu-oxo bridges upon hydrolysis. 相似文献
6.
Seiji Miyano Osamu Yamashita Kunihiro Sumoto Keiyu Shima Mariko Hayashimatsu Fumio Satoh 《Journal of heterocyclic chemistry》1987,24(1):271-274
The method for preparing 7a-substituted hexahydro-1H-pyrrolizines 2 from 1,2,3,5,6,7-hexahydropyrrol-izinium Perchlorate (3) was investigated, by which introduction of a wide variety of functionalities on C(7a) could be achieved easily. 相似文献
7.
The reaction of 2-dialkylamino-5-phenyl-1,3-oxathiolium cation 1 with sulphur ylides 2 was investigated. The behavior of 1 was solvent-dependent. In CH2Cl2, carbamate ester 3 was obtained: in CH3CN, the intermediate sulphonium salt 5, which on hydrolysis gave 3, was isolated. On the other hand, reaction in MeOH gave the diphenacyl derivative 6. The reaction mechanism is discussed. 相似文献
8.
9.
We study level surfaces of non-degenerate functions inR
n+1. Such level surfaces are non-degenerate in the sense of affine differential geometry. In affine differential geometry, the affine normal plays an important role for the study of a non-degenerate hypersurface. In this note, being motivated by Koszul's work we take a canonical vector field
for level surfaces of a non-degenerate function and give certain characterizations of when
is transversal, by the shape operatorS, the transversal connection , and consider the difference between
and the affine normal. 相似文献