Lack of dissipativity is not symplecticness

We show that, when numerically integrating Hamiltonian problems, nondissipative numerical methods do not in general share the advantages possessed by symplectic integrators. Here a numerical method is called nondissipative if, when applied with a small stepsize to the test equationdy/dt = iy, real, has amplification factors of unit modulus. We construct a fourth order, nondissipative, explicit Runge-Kutta-Nyström procedure with small error constants. Numerical experiments show that this scheme does not perform efficiently in the numerical integration of Hamiltonian problems.This research has been supported by project DGICYT PB92-254.     

Absolute doubly differential cross sections for electron bremsstrahlung from rare gas atoms at 28 and 50 keV

Absolute doubly differential bremsstrahlung cross sections from Xe, Kr, Ar, and Ne have been measured for electron bombarding energies of 28 and 50 keV. Bremsstrahlung photons have been detected at 90 degrees to the incident electron beam at energies ranging from 5 keV up to the kinematic end point. The results are compared with predictions of ordinary bremsstrahlung and of total bremsstrahlung that include polarizational bremsstrahlung from the target atom calculated in the stripping approximation. All previous absolute cross sections have been from thin-film solid targets and have not shown any polarizational bremsstrahlung contribution. The present results, the first from free atoms, provide definitive evidence for the contribution of polarizational bremsstrahlung to the photon spectrum from electron bremsstrahlung.     

ATR/FTIR characterization of Steinernema glaseri and Heterorhabditis indica

The use of Fourier transform mid-infrared spectroscopy with attenuated total reflection for characterizing entomopathogenic nematodes is evaluated for the first time. The resulting spectra of Steinernema glaseri and Heterorhabditis indica were compared with the spectrum of Caenorhabditis elegans. In the absorption spectra generated by the nematodes samples, the absorption bands were assigned to the molecular species and some important components were identified including triglycerides, trehalose, glycogen and collagen. Also, the use of star diagrams for the fingerprint section of nematode spectra for separating genera is discussed.     

Status of the EBIT in the ReA3 reaccelerator at NSCL

At the NSCL a reaccelerator with design end energy of 3 MeV/u for ²³⁸U, called ReA3, is approaching the end of construction. ReA3 will be coupled to a gas stopper at the NSCL fragmentation facility to provide rare-isotope beams of nuclides not available at ISOL facilities in this energy range. An Electron Beam Ion Trap (EBIT) will be used to provide highly charged ions at an energy of about 12 keV/u. The charge breeder is followed by a room-temperature radiofrequency quadrupole (RFQ) and a series of superconducting linear accelerator structures. Initial commissioning results from the EBIT and its charge-over-mass separator are presented.     

Synthesis,characterization and anticancer activity of new palladacycles derived from chiral α‐diimines

Optically pure α‐diimines quantitatively obtained in solvent‐free conditions starting from 2,3‐butanedione and (S)‐(?)‐1‐phenylethylamine and (S)‐(?)‐1‐(4‐methylphenyl)ethylamine, respectively, yielded the new chiral mono‐Pd complexes 2a–b, which have been partly characterized by IR, ¹H‐ and ¹³C‐NMR spectroscopies along with MS‐FAB⁺ spectrometry. The crystal and molecular structure for palladacycle 2a has been fully confirmed by single‐crystal X‐ray studies. Studies in vitro of 2a–b have displayed growth inhibition against different classes of cancer: leukemia (K‐562 CML), colon cancer (HCT‐15), breast cancer (MCF‐7), central nervous system (U‐251 Glio) and prostate cancer (PC‐3) cell lines. Copyright © 2009 John Wiley & Sons, Ltd.     

Evaluation of isotope-coded protein labeling (ICPL) in the quantitative analysis of complex proteomes

An evaluation of the ICPL (isotope-coded protein labeling) non-isobaric labeling technique was performed using two different biological models. Two samples containing phage T4 capsids were mixed in a 1:1 ratio after being labeled with the light or heavy versions of the ICPL reagent. The analysis of this proteome demonstrated the feasibility of this approach for differential quantitative proteomics and was employed to optimize the experimental parameters of the ICPL workflow. ICPL-mediated analysis of two more complex proteomes, those of a Salmonella enterica serovar Typhimurium virulent strain and an isogenic attenuated mutant, and its comparison with the results obtained in a 2D-PAGE “classical” approach confirmed that ICPL is a valuable alternative to other labeling techniques currently in use. In addition, our results suggest that labeling at the peptide level instead of following the standard ICPL workflow should increase both the number of proteins quantified and the reliability of the quantification.     

Viscoelastic boundary stabilization for a transmission problem in elasticity

We consider an anisotropic body which is constituted of twodifferent types of materials supporting a memory boundary conditionand we show that its energy decays uniformly as time goes toinfinity with the same rate as the relaxation function g, thatis, the energy decays exponentially when g decays exponentially,and polynomially when g decays polynomially.     

The Transmission Problem of Viscoelastic Waves

In this paper we consider the transmission problem of viscoelastic waves. That is, we study the wave propagations over materials consisting of elastic and viscoelastic components. We show that for this types of materials the dissipation produced by the viscoelastic part is strong enough to produce exponential decay of the solution, no matter how small is its size. We also show that the linear model is well posed.     

Long‐Term Photostability in Terephthalate Metal–Organic Frameworks

Prolonged (weeks) UV/Vis irradiation under Ar of UiO‐66(Zr), UiO66 Zr‐NO₂, MIL101 Fe, MIL125 Ti‐NH₂, MIL101 Cr and MIL101 Cr(Pt) shows that these MOFs undergo photodecarboxylation of benzenedicarboxylate (BDC) linker in a significant percentage depending on the structure and composition of the material. Routine characterization techniques such as XRD, UV/Vis spectroscopy and TGA fail to detect changes in the material, although porosity and surface area change upon irradiation of powders. In contrast to BCD‐containing MOFs, zeolitic imidazolate ZIF‐8 does not evolve CO₂ or any other gas upon irradiation.