Synthesis and properties of optically active ferrocenylethylindazoles

The stereochemistry of two processes, viz., -ferrocenylalkylation of indazole with optically active S-(+)-1-ferrocenylethanol and the thermal rearrangement of S-(+)-2-N-(ferrocenylethyl)indazole into S-(+)-1-N-(ferrocenylethyl)indazole, was studied. Both reactions proceed stereoselectively.     

Ferrocenylalkyl azoles: bioactivity,synthesis, structure

The toxicity of ferrocenylethyl benzotriazole ( 1 ) and other ferrocene compounds including ferrocenylmethyl benzimidazoles ( 4,5,6,11 ), ferricenium salts ( 3,9,10 ) and ferrocenylmethyl adenine ( 7 ), was studied. All ferrocene complexes under investigation showed low or medium toxicities. On the basis of an earlier model of chemical carcinogenesis, the antitumor activity of ferrocenylalkyl azoles 1, 8 and ferricenium salts 9, 10 was studied in vivo in the so‐called sub‐capsular test on human tumors. This effectiveness was compared with that of cisplatin. A series of ferrocenylalkyl azoles were synthesized by interacting azoles either with α‐hydroxyalkyl ferrocenes FcC(OH)R₁R₂ in organic solvent in the presence of aqueous HBF₄ in quantitative yields or with trimethyl(aminomethyl)ferrocene iodide in an aqueous‐basic medium in good yields. The X‐ray determinations of molecular and crystal structures of α‐(1‐benzotriazolyl)ethylferrocene ( 1 ) and α‐(1‐naphthatriazolyl)ethylferrocene ( 12 ) were performed. Copyright © 2008 John Wiley & Sons, Ltd.     

Glass-reinforced plastic high-pressure tanks

The design and fabrication of lens-shaped tanks are described. The results of an investigation of the deformation and strength of the tanks are presented together with the data of cyclic tests.Institute of Mechanics, Academy of Sciences of the Ukrainian SSR, Kiev. Translated from Mekhanika Polimerov, No. 1, pp. 149–152, January–February, 1970.     

Simplified models of the thermodynamics of preliminarily deformed viscoelastic bodies (in the coordinates of the natural state)

Institute of Mechanics, Academy of Sciences of the Ukrainian SSR, Kiev. Translated from Prikladnaya Mekhanika, Vol. 24, No. 2, pp. 21–30, February, 1988.     

Effect of ultrasound on the properties of a glass-reinforced plastic

It is shown that removing paraffin size from the glass strands by means of ultrasound has little effect on their strength, improves the structure of the material, and raises the mechanical strength of the GRP by 11–12%. An ultrasonic strand cleaner employing focusing piezoelectric ceramic transducers is described.Institute of Mechanics, Academy of Sciences of the Ukrainian SSR, Kiev. Translated from Mekhanika Polimerov, No. 3, pp. 546–548, May–June, 1969.     

Effect of proton-electron irradiation on the strength of a glass-reinforced plastic and its components

The action of protons and electrons on the properties of glass strands under vacuum conditions has been experimentally investigated. The experimental procedure is described. The effects of irradiation, strain rate, and reduced temperature and pressure on the properties of glass reinforcement and glass-reinforced plastics are estimated.Institute of Mechanics, Academy of Sciences of the Ukrainian SSR, Kiev; Physicotechnical Institute of Low Temperatures, Academy of Sciences of the Ukrainian SSR, Kiev. Translated from Mekhanika Polimerov, No. 4, pp. 755–760, July–August, 1970.