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1.
The theory of A-scalar and generalized scalar operators of Colojoara and Foias [7] is generalized to unbounded closed operators. A spectral mapping theorem is proved for the (local) spectrum. Generalized scalar operators admit a calculus for, the C-functions on the C-manifold. B(C), the C-functions onC, which are bounded with all derivatives, is an other admissible algebra. If (T) is contained in a generalized circle, characterisations as in [7] and explicit expressions for the Cm(K)- and the Bm(R)-calculus are obtained.  相似文献   
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Halfsandwich Complexes of Chromium with the Trifluoromethyl Isocyanide Ligand The synthesis and properties of the halfsandwich complexes [η6-1,3,5-C6H3(CH3)3]Cr(CO)2(CNCF3), [η6-1,3,5-C6H3(CH3)3]Cr(CO)(CNCH3)(CNCF3) und [η6-1,3,5-C6H3(CH3)3]Cr(CNCF3)3 is reported. The vibrational spectroscopic data proof the strong π accepting character of the trifluoromethyl isocyanide ligand.  相似文献   
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Mesoporous NiFe2O4 for electrocatalytic water splitting was prepared via soft-templating using citric-acid-complexed metal nitrates as precursors. The mesopore evolution during thermal treatment was examined systematically giving insights into the formation process of mesoporous NiFe2O4. Detailed nitrogen physisorption analysis including desorption scanning experiments reveal the presence of highly accessible mesopores generating surface areas of up to 200 m2/g. The ability of the NiFe2O4 powders to perform electrocatalytic oxygen evolution reaction under alkaline conditions was investigated, highlighting the advantages of mesopore insertion. The most active samples reach a current density of 10 mA cm−2 at an overpotential of 410 mV with a small Tafel slope of 50 mV dec−1, indicating an enhanced activity that originated from the increased catalyst surface.  相似文献   
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Zusammenfassung Die Innenwandtemperatur eines transpirationsgekühlten Rohres, das einen Plasmabogen umgibt, kann experimentell nur mit sehr großen Schwierigkeiten bestimmt werden. Sie läßt sich jedoch aus auf einfache Weise zu messenden physikalischen Größen berechnen. Das Rechenverfahren wird erläutert und Rechenergebnisse werden diskutiert.
Calculation of temperature distribution in a transpiration cooled tube wall
Experimental determination of the inner wall temperature of a transpiration cooled tube surrounding a plasma arc is very difficult. This temperature, however, can be calculated from simply measurable physical quantities. The method is explained and results are discussed.

Bezeichnungen A =m-Bc pG/2(1–p) w - A s Strahlungszahl - B =4P/mc pG r p - c pG spez. Wärme des Gases - C =B(1+A) - C s Strahlungszahl des schwarzen Körpers - f(r) =(B r+1/r) - g(r) =(C–1/r 2) - m-B Massenstrom des Gases bezogen auf 1 cm Rohrlänge - P Porosität - q-A L Wärmemenge, die pro cm Rohrlänge durch Leitung durch die Rohrwand hindurch transportiert wird - r Rohrradius - r i Innenradius - r a Außenradius - r e Rohrradius, an dem alle Temperaturen bekannt sind - r p Porenradius - t Gastemperatur - t a Gastemperatur außerhalb des Rohres - T Rohrwandtemperatur - T a Rohrwandtemperatur an der Außenfläche - T i Rohrwandtemperatur an der Innenfläche - Wärmeübergangszahl - w Wärmeleitzahl der Wand - G Wärmeleitzahl des Gases Herrn Professor E. R. G.Eckert zur Vollendung seines 65. Lebensjahres gewidmet.  相似文献   
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An analysis is made for the influence of the moving condensate film on the mass transfer rate from the gas-vapor mixture to the condensate. The governing energy and mass conservation equations are solved using the Crank-Nicholson method. The results show that the moving condensate film may have a considerable effect on condensation mass transfer.  相似文献   
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We report the development of a metal-free four-step one-pot synthetic strategy to access high-value functionalized phthalazines using o-methyl benzophenones as starting compounds. Combining a light-mediated enolization of o-methyl benzophenones/Diels-Alder reaction domino process with a subsequent deprotection/aromatization domino reaction in one-pot leads to sustainable and efficient organic synthesis. The tangible advantages, i. e., absence of catalysts or additives, utilization of commercially available and/or easily accessible substrates, mild reaction conditions, simplicity, and single work-up procedure, make this combined process highly appealing for the direct construction of various 1-aryl-phthalazines. Importantly, in vitro bioactivity evaluation of these newly prepared heterocyclic compounds demonstrated a strong antiviral efficacy against major human pathogens like HCMV and SARS-CoV-2.  相似文献   
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In this article, we report data from an online questionnaire study with 587 respondents, representative for the adult U.S. population in terms of age, gender, and level of education. The aim of this study was to assess how interest in science and knowledge as well as beliefs about science are associated with risk and benefit perceptions of nanotechnology. The findings suggest that the U.S. public is still rather unfamiliar with nanotechnology. Those who have some knowledge mainly have gotten it from TV and the Internet. The content of current media reports is perceived as fairly positive. Knowledge of scientific methods is unrelated to benefit and risk perceptions, at least when other predictors are controlled. In contrast, positive beliefs about science (e.g., its impact on economy or health) and more sophisticated epistemological beliefs about the nature of scientific knowledge are moderately linked to more positive perceptions of nanotechnology. The only exception is the perception of scientific uncertainty: This is associated with less positive evaluations. Finally, higher engagement with science is associated with higher risk perceptions. These findings show that laypersons who are engaged with science and who are aware of the inherent uncertainty of scientific evidence might perceive nanotechnology in a somewhat more differentiated way, contrary to how it is portrayed in the media today.  相似文献   
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