全文获取类型
收费全文 | 58篇 |
免费 | 4篇 |
专业分类
化学 | 28篇 |
晶体学 | 1篇 |
力学 | 2篇 |
数学 | 7篇 |
物理学 | 24篇 |
出版年
2022年 | 4篇 |
2021年 | 4篇 |
2020年 | 1篇 |
2019年 | 1篇 |
2016年 | 3篇 |
2015年 | 2篇 |
2014年 | 2篇 |
2013年 | 3篇 |
2012年 | 4篇 |
2011年 | 2篇 |
2009年 | 2篇 |
2008年 | 3篇 |
2007年 | 9篇 |
2006年 | 2篇 |
2005年 | 1篇 |
2002年 | 3篇 |
2001年 | 1篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1995年 | 2篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1990年 | 1篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1984年 | 1篇 |
1983年 | 3篇 |
1974年 | 1篇 |
排序方式: 共有62条查询结果,搜索用时 15 毫秒
1.
2.
3.
Dr. Zhijia Wang Mikhail Ivanov Dr. Yuting Gao Laura Bussotti Prof. Paolo Foggi Huimin Zhang Prof. Nino Russo Prof. Bernhard Dick Prof. Jianzhang Zhao Prof. Mariangela Di Donato Dr. Gloria Mazzone Prof. Liang Luo Prof. Matvey Fedin 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(5):1091-1102
Spin–orbit charge-transfer intersystem crossing (SOCT-ISC) is useful for the preparation of heavy atom-free triplet photosensitisers (PSs). Herein, a series of perylene-Bodipy compact electron donor/acceptor dyads showing efficient SOCT-ISC is prepared. The photophysical properties of the dyads were studied with steady-state and time-resolved spectroscopies. Efficient triplet state formation (quantum yield ΦT=60 %) was observed, with a triplet state lifetime (τT=436 μs) much longer than that accessed with the conventional heavy atom effect (τT=62 μs). The SOCT-ISC mechanism was unambiguously confirmed by direct excitation of the charge transfer (CT) absorption band by using nanosecond transient absorption spectroscopy and time-resolved electron paramagnetic resonance (TREPR) spectroscopy. The factors affecting the SOCT-ISC efficiency include the geometry, the potential energy surface of the torsion, the spin density for the atoms of the linker, solvent polarity, and the energy matching of the 1CT/3LE states. Remarkably, these heavy atom-free triplet PSs were demonstrated as a new type of efficient photodynamic therapy (PDT) reagents (phototoxicity, EC50=75 nm ), with a negligible dark toxicity (EC50=78.1 μm ) compared with the conventional heavy atom PSs (dark toxicity, EC50=6.0 μm, light toxicity, EC50=4.0 nm ). This study provides in-depth understanding of the SOCT-ISC, unveils the design principles of triplet PSs based on SOCT-ISC, and underlines their application as a new generation of potent PDT reagents. 相似文献
4.
Luana Malacaria Giuseppina Anna Corrente Amerigo Beneduci Emilia Furia Tiziana Marino Gloria Mazzone 《Molecules (Basel, Switzerland)》2021,26(9)
This review focuses on the ability of some natural antioxidant molecules (i.e., hydroxycinnamic acids, coumarin-3-carboxylic acid, quercetin, luteolin and curcumin) to form Al(III)- and Fe(III)-complexes with the aim of evaluating the coordination properties from a combined experimental and theoretical point of view. Despite the contributions of previous studies on the chemical properties and biological activity of these metal complexes involving such natural antioxidants, further detailed relationships between the structure and properties are still required. In this context, the investigation on the coordination properties of Al(III) and Fe(III) toward these natural antioxidant molecules might deserve high interest to design water soluble molecule-based metal carriers that can improve the metal’s intake and/or its removal in living organisms. 相似文献
5.
Graphene oxide (GO) particles in aqueous dispersions can form liquid crystal (LC) phases at extremely low concentrations due to the extremely high aspect ratio of the flakes and noticeably, they possess an extremely large Kerr coefficient attractive for low power consumption electro‐optic devices. Reduced graphene does not easily form LC phases in water due to its hydrophobic nature but here we show that stable dispersions of reduced graphene oxide can be realized with surfactants and that they exhibit birefringence upon shearing as well as under application of electric fields. The performance of the system is largely superior to GO LC possessing longer time stability and drastically improved electro‐optic properties with an induced birefringence twice as large at the same field strength thanks to the almost recovery of graphene properties upon reduction. (© 2016 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim) 相似文献
6.
7.
Giusy Rita Caponio Miriam Cofano Tamara Lippolis Isabella Gigante Valentina De Nunzio Graziana Difonzo Mirella Noviello Luigi Tarricone Giuseppe Gambacorta Gianluigi Giannelli Maria De Angelis Maria Notarnicola 《Molecules (Basel, Switzerland)》2022,27(20)
Grape pomace (GP)—the major by-product of winemaking processes—still contains bioactive molecules with known beneficial properties for human health, such as an antiradical scavenging activity or an antiproliferative activity of tumors. In vitro studies have demonstrated that GP polyphenols specifically influence colon cancer cell proliferation. In addition to previously published work, we tested the phenolic compounds of Aglianico GP following an in vitro simulated gastrointestinal digestion on colorectal cancer cell lines at different degrees of differentiation. Our experiments, using HT29 and SW480 cells, confirmed the anti-proliferative effect of GP gastrointestinal digested extract and provided intriguing insights on the way it influences the cancer cell features (i.e., viability, proliferation, and apoptosis). We observed that Aglianico GP extract showed a great ability to affect cell proliferation and apoptosis. Interestingly, both HT29 and SW480 cells produced a significant increase in Bax, and a significant increase in the Bax/Bcl-2 ratio and caspase-3. The gastrointestinal digested GP extract was previously characterized both for antioxidant activity and phenolic composition. As a result, the TPC and the antioxidant activity reached high values in the Aglianico GP digested extract, and the main compounds assessed by UHPLC-DAD were anthocyanins, phenolic acids, and flavonoids. This work shed light on the use of digested GP extract as a dietary ingredient, a very sustainable source of nutritional compounds with potential health benefits for colon cancer cell proliferation. 相似文献
8.
9.
A.M. Mazzone 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,28(4):491-494
The thermal evolution of steps on Si(100) is well studied and experiment indicates that at temperatures below the roughening
transition (i.e.
T? 1000 K) the displacements of atoms at the step-edge are the basic factor of this evolution. However the evaluation of the
nature and participants of these displacements is beyond experimental observations and a theoretical approach is therefore
needed. The problem addressed by this study is the identification of the properties of atomic motions of step-edge atoms and
this investigation is performed applying an isothermal Molecular Dynamics simulation method to simple stepped configurations
on Si(100). The calculations describe the functional dependence of the motions of step-edge atoms on the step type, size and
temperature and on the nature of the interatomic forces. Possible mechanisms of kink formations are suggested.
Received 15 February 2002 Published online 13 August 2002 相似文献
10.
S.J. Pickart H.A. Alperin F. Menzinger G. Mazzone F. Sacchetti 《Physics letters. A》1983,95(7):397-399
The depolarization of neutrons by transmission through amorphous samples of NdFe2 and HoFe2 has been measured at temperatures in the neighborhood of their magnetic transitions. The results, when compared to other determinations of the Curie temperature (Tc) suggest that Tc may not be a well-defined quantity in these materials. 相似文献