Sulla K-variazione Essenziale di Una Funzione reale

In this paper we consider a definition of essentialK-variation for real functions which gives information on the absolute integrability of its approximate derivate on a measurable set.     

Derivative-free methods for mixed-integer nonsmooth constrained optimization

Computational Optimization and Applications - In this paper, mixed-integer nonsmooth constrained optimization problems are considered, where objective/constraint functions are available only as the...     

Anomalies in magnetic susceptibility of nonstoichiometric Nd2NiO4+δ (δ=0.049, 0.065, 0.077, 0.234)

We have investigated the influence of oxygen excess on structural and physical properties of the Nd₂NiO_4+δ compounds. Using the citrate method and subsequent annealing in air and in a reducing atmosphere a various oxygen-doped compounds were prepared. X-ray diffraction at room temperature shows that structure is strongly oxygen excess dependent. Thus, by increasing δ by up to 0.077, the compounds adopt a tetragonal structure gradually with a biphasic domain between orthorhombic and tetragonal structures. And at higher δ values, the structure becomes orthorhombic. Moreover, Rietveld analysis shows that for δ<0.077 the presence of two crystalline phases with different oxygen excess: it should be the signature of interstitial oxygen, which is distributed in heterogeneous way. The biphasic products are composed of a stoichiometric Nd₂NiO₄ phase (orthorhombic structure) and a tetragonal Nd₂NiO_4.077 phase. Magnetic susceptibility shows a deviation from Curie-Weiss law for lower oxygen excess (δ?0.077). Moreover, some anomalies in dc magnetic susceptibility curves was observed at 45, 95 and 130 K for δ<0.077. These transitions are connected to the tetragonal phase, and were attributed, respectively, to an antiferromagnetic transition, possible charge ordering and structural transition.     

Cathodic chloride extraction treatment of a late bronze-age artifact affected by bronze disease in room-temperature ionic-liquid 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide (EMI-TFSI)

This paper concentrates on a novel approach to the electrochemical treatment of bronze disease, based on the use of room-temperature ionic liquids (RTIL). In particular, we employed 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide as the electrolyte for the galvanostatic cathodic treatment of a late bronze-age artifact that had been exposed to marine environment during its history, dating back to ca. 1100 B.C. After an accurate metallographic and structural analysis of the as-found object—proving, among other findings, that bronze disease is essentially related to the presence of nantokite locked inside subsurface pits of typical equivalent diameter of several hundred micrometers, we subjected it to optimal electrochemical conditions, showing—on the basis of X-ray diffraction—that nantokite could be effectively removed and Cu(I) reduced to metallic Cu. Numerical computations in the full three-dimensional pit geometry, with realistic nonlinear electrochemical boundary conditions, provide the theoretical framework for the choice of RTIL—as opposed to aqueous solutions—and for the quantitative evaluation of Cl⁻ removal rates.     

Xanes (X-ray absorption near edge structure) of V in vanadium-iron phosphate glasses

The X-ray Absorption Near-Edge Structure (XANES) of V in vanadium-iron glasses (50P₂O₅ + (50?x)FeO + xV₂O₅) have been measured. The effective charge of V ions in glasses has been determined. At low V₂O₅ concentration (x ～ 5) only V⁴⁺ with 6-fold coordination is present on the contrary a static mixed valence state (V⁴⁺, V⁵⁺) has been found at high concentrations 20?x?50. The results explain the electron hopping conductivity effects at high V₂O₅ concentration (x ～ 50) involving V⁴⁺ ? V⁵⁺ pairs and at low V₂O₅ concentration (x?10) involving V⁴⁺ ? Fe³⁺ pairs.     

Optimization of power production and costs in microgrids

This paper proposes a mathematical formulation for energy management in a connected microgrid. The aim is determining the optimal operating strategy for energy storage, to fulfil a time-varying energy demand and operational constraints while achieving a tradeoff between microgrid running costs and energy storage system life. The microgrid is composed by various renewable power production plants, storage devices and controllable loads, and has the ability to increase energy efficiency and reduce costs for energy purchasing from the main grid. The problem is formulated as a mixed-integer linear optimization problem. The optimization is aimed at minimizing the overall cost function of the system while satisfying the customer demand and safety of the electrical network. A case study of an existing microgrid is investigated: the microgrid consists of a photovoltaic and a hydroelectric power plant, a battery storage, an office building and an industrial facility. The optimization problem is solved in an efficient way by using commercial software. Simulation results show the feasibility and the effectiveness of the proposed approach to satisfy the load and reduce total costs.     

Synthesis and anion exchange properties of a Zn/Ni double hydroxide salt with a guarinoite structure

In this study, the first route to synthesize a compound with the guarinoite structure (Zn,Co,Ni)₆(SO₄)(OH,Cl)₁₀·5H₂O is reported. Zn/Ni guarinoite is obtained from the reaction of NiSO₄·7H₂O with solid ZnO in aqueous solution. The resulting green Zn/Ni guarinoite ((Zn_3.52Ni_1.63)(SO₄)_1.33(OH_7.64)·4.67H₂O) was characterized by X-ray diffraction, infrared spectrometry, UV–Visible spectrometry and thermal analysis. It is shown that its structure is similar to the one described for the layered Zn sulfate hydroxide hydrate, i.e. brucite layers with empty octahedra presenting tetrahedrally coordinated divalent atoms above and below the empty octahedra. Ni atoms are located in the octahedra and zinc atoms in tetrahedra and octahedra. In this structure the exchangeable anions are located at the apex of tetrahedra. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) observations show that the Zn/Ni guarinoite is composed of aggregates of hexagonal plates of several hundreds of nanometers. Due to its interest for industrial or environmental applications, the exchange of sulfate groups by carbonates has been investigated. Results show a limited exchange and a higher affinity of the Zn/Ni guarinoite for sulfates compared to carbonates.     

Polycyclic compounds from aminopolyols and alpha-dicarbonyls: structure and application in the synthesis of exoditopic ligands

The structure and stereochemistry of the crystalline 2 : 2 condensation product ("glytham") of glyoxal and tris(hydroxymethyl)aminomethane was conclusively determined by X-ray diffractometric analysis. The singular disposition of the heteroatoms suggests the employment of glytham as starting material for the synthesis of ditopic ligands for metal ions. Some derivatives of glytham were prepared and their binding properties towards alkaline metal ions were preliminarily investigated by ESI-MS and NMR.