Synthesis of condensed systems containing the tetrazole ring by base-catalyzed intramolecular cyclization of quaternary ammonium salts

Quaternary ammonium salts containing propargyl and 3-(2-methyltetrazol-5-yl)propargyl groups undergo base-catalyzed cyclization at room temperature with self heating to form condensed heterocyclic systems containing the tetrazole ring. Heating at 90–92°C for 2 h is necessary to cyclize the allyl analogs of the starting salts.Communication 234 of the series Research on Amines and Ammonium Compounds. For 233, see [1].Institute of Organic Chemistry, National Academy of Sciences of the Republic of Armenia, Erevan 375094. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 390–394, March, 1999.     

Dimerization of Sodium Enolates of Malonic Ester and Acetylacetone Effected by the Action of 4-Methyl-3,4-dibromotetrahydropyran

Russian Journal of Organic Chemistry -     

OnU ϕ-sets of trigonometric integrals

, (t) >0 E(–, +),E<, , ¦f(t)¦ (t) xE, f(t)=0 (–, +).     

Reaction of 2-substituted 4,4-dimethyl-5-methylene-1,3-dioxolanes with dichlorocarbene and certain transformations of adducts obtained

A series of derivatives of 4,4-dimethyl-5-methylene-1,3-dioxolane has been synthesized, and their reaction with dichlorocarbene, obtained under interphase catalysis conditions, has been studied. The adducts obtained undergo thermal isomerization into dichloroethylidene derivatives.     

Reactions of 1-halo-3-methyl-2,3-epoxybutane with alcohols

The reaction of 1-bromo(or chloro)-3-methyl-2,3-epoxybutane with alcohols in the presence of the alkali metal alkoxides leads to the formation of epoxy ethers by direct replacement of the halogen atoms without participation of the epoxide ring.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 878–880, July, 1981.     

Synthesis and intramolecular recyclization of 2,2-dialkyl-6-chloro-4-hydroxymethyl-benzo[<Emphasis Type="Italic">f</Emphasis>]isoindolinium salts

The intramolecular cyclization of dialkyl(2-butynyl-4-hydroxy)[3-(p-chlorophenyl)propargyl]ammonium chlorides, catalyzed by aqueous KOH, was realized. It was shown that the obtained products — 2,2-dialkyl-6-chloro-4-hydroxymethylbenzo[f]isoindolinium chlorides — readily undergo recyclization under the action of a twofold molar amount of KOH in aqueous solution with heating with the formation of 4-dialkylaminomethyl-8-chloro-1,3-dihydronaphtho[1,2-c]furans. __________ Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 834–840, June, 2007.     

Resonant Interaction of the Transitional Radiation of Charged Particles with Anisotropic Magnetodielectric Filling of the Waveguide Periodically Modulated in Space

Optics and Spectroscopy - The features of the interaction of the transition radiation of a charged particle with an anisotropic magnetodielectric medium periodically modulated in the waveguide in...     

Dielectric properties of liquid crystalline composites doped with nano-dimensional fragments of shungite carbon

A cholesteric liquid crystal (CLC) – cholesteryl tridecylate (X-20) was doped with nanoparticles of shungite carbon (Sh) to effectively improve some physicochemical properties of the CLC matrix for the further use in electronic devices. The influence of Sh (concentration of 0.005 and 0.02 wt. %) on phase transition temperatures of X-20 was studied. Addition of 0.005 wt. % of Sh shifts phase transition temperatures upward, while the concentration increase to 0.02 wt. % leads to the opposite effect. These data were taken into account during the study of dielectric properties in different phase states. The dielectric properties were studied in the frequency range from 20 Hz to 10 MHz. Only for the system X-20/Sh (0.02 wt. %), dispersion of the dielectric permittivity was observed. The dispersion was caused by the appearance of additional relaxation processes and it was substantially more extended than the classical Debye theory suggests. The results of the research show that the ‘CLC – Sh nanoparticles’ composites can be used as promising materials to increase the efficiency of radio electronics devices.     

Synthesis and transformations of polyhedral compounds. Synthesis of 2-[quinolin-3(2)-yl]-1,3-diazaadamantanes

A number of new 1,3-diazaadamantane derivatives containing quinoline fragments on C² have been synthesized by condensation of 1,5-dialkyl-3,7-diazabicyclo[3.3.1]nonan-9-one, 1,5-dimethyl-3,7-diazabicyclo-[3.3.1]nonan-9-ol, and 1,5-dimethyl-3,7-diazabicyclo[3.3.1]nonane with 2-oxo-1,2-dihydroquinoline-3-carbaldehyde, 2-chloro- and 2-iodoquinoline-3-carbaldehyde, and quinoline-2-carbaldehyde.