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Chhavi Bhardwaj Jerry F. Moore Yang Cui Gerald L. Gasper Hans C. Bernstein Ross P. Carlson Luke Hanley 《Analytical and bioanalytical chemistry》2013,405(22):6969-6977
Laser desorption postionization mass spectrometry (LDPI-MS) imaging is demonstrated with a 10.5 eV photon energy source for analysis and imaging of small endogenous molecules within intact biofilms. Biofilm consortia comprised of a synthetic Escherichia coli K12 coculture engineered for syntrophic metabolite exchange are grown on membranes and then used to test LDPI-MS analysis and imaging. Both E. coli strains displayed many similar peaks in LDPI-MS up to m/z 650, although some observed differences in peak intensities were consistent with the appearance of byproducts preferentially expressed by one strain. The relatively low mass resolution and accuracy of this specific LDPI-MS instrument prevented definitive assignment of species to peaks, but strategies are discussed to overcome this shortcoming. The results are also discussed in terms of desorption and ionization issues related to the use of 10.5 eV single-photon ionization, with control experiments providing additional mechanistic information. Finally, 10.5 eV LDPI-MS was able to collect ion images from intact, electrically insulating biofilms at ~100 μm spatial resolution. Spatial resolution of ~20 μm was possible, although a relatively long acquisition time resulted from the 10 Hz repetition rate of the single-photon ionization source. Figure
Neutral species laser desorbed from cocultured biofilms undergo single photon ionization by VUV radiation and resultant ions are detected by time-of-flight mass spectrometry 相似文献
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The conformational character of a random copolymer of ethyl acrylate and acrylic acid (mole ratio 3:1) has been examined by intrinsic viscosity and light scattering in organic and in aqueous media. The unperturbed dimensions of this copolymer in its un-ionized state in an organic theta solvent are 1.3 to 1.4 times those obtained for the fully ionized polymer in an aqueous theta solvent. The data also suggest that a change in conformation from a swollen random coil to a compact random coil occurs in aqueous media as a function of ionic strength. These results are interpreted in terms of the hydrophobic interaction of the ester groups on the chain. An application of the wormlike chain model shows that viscosity data can be used to predict the light scattering results well with in experimental error. 相似文献
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F. Helus H. Gasper G. Rettig W. Maier-Borst 《Journal of Radioanalytical and Nuclear Chemistry》1985,94(3):149-159
A method for simple and fast production of34mCl as tracer for biomedical research work has been developed. Different target materials have been tested, the yield of34mCl and co-produced contaminants examined, the fast chemical separation procedure developed and target system constructed. 相似文献
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From the system MF(2)/PF(5)/XeF(2)/anhydrous hydrogen fluoride (aHF), four compounds [Sr(XeF(2))(3)](PF(6))(2), [Pb(XeF(2))(3)](PF(6))(2), [Sr(3)(XeF(2))(10)](PF(6))(6), and [Pb(3)(XeF(2))(11)](PF(6))(6) were isolated and characterized by Raman spectroscopy and X-ray single-crystal diffraction. The [M(XeF(2))(3)](PF(6))(2) (M = Sr, Pb) compounds are isostructural with the previously reported [Sr(XeF(2))(3)](AsF(6))(2). The structure of [Sr(3)(XeF(2))(10)](PF(6))(6) (space group C2/c; a = 11.778(6) Angstrom, b = 12.497(6) Angstrom, c = 34.60(2) Angstrom, beta = 95.574(4) degrees, V = 5069(4) Angstrom(3), Z = 4) contains two crystallographically independent metal centers with a coordination number of 10 and rather unusual coordination spheres in the shape of tetracapped trigonal prisms. The bridging XeF(2) molecules and one bridging PF(6)- anion, which connect the metal centers, form complicated 3D structures. The structure of [Pb(3)(XeF(2))(11)](PF(6))(6) (space group C2/m; a = 13.01(3) Angstrom, b = 11.437(4) Angstrom, c = 18.487(7) Angstrom, beta = 104.374(9) degrees, V = 2665(6) Angstrom(3), Z = 2) consists of a 3D network of the general formula {[Pb(3)(XeF(2))(10)](PF(6))(6)}n and a noncoordinated XeF(2) molecule fixed in the crystal structure only by weak electrostatic interactions. This structure also contains two crystallographically independent Pb atoms. One of them possesses a unique homoleptic environment built up by eight F atoms from eight XeF(2) molecules in the shape of a cube, whereas the second Pb atom with a coordination number of 9 adopts the shape of a tricapped trigonal prism common for lead compounds. [Pb(3)(XeF(2))(11)](PF(6))(6) and [Sr(3)(XeF(2))(10)](PF(6))(6) are formed when an excess of XeF(2) is used during the process of the crystallization of [M(XeF(2))(3)](PF(6))(2) from their aHF solutions. 相似文献
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Two silylene nickel carbonyl complexes of composition L·Ni(CO)(3) (1) {L = PhC(NtBu)(2)SiCl} and L'(2)·Ni(CO)(2) (2) { L' = RSiCl(2), R = (1,3-bis-(2,6-diisopropylphenyl)imidazol-2-ylidene)} were prepared by reacting 1 equivalent of Ni(CO)(4) with 1 equivalent of heteroleptic chlorosilylene L for 1 and with 2 equivalents of carbene stabilized dichlorosilylene L' for 2 in toluene at room temperature. Both complexes 1 and 2 were characterized by single-crystal X-ray analysis, NMR and IR spectroscopy, EI-MS spectrometry, and elemental analysis. 相似文献
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[M(XeF2)5](PF6)2 (M = Ca, Cd) complexes were prepared by the reaction of MF2 and XeF2 under pressure of gaseous PF5 in anhydrous HF as solvent. The coordination sphere of the Ca atom consists of nine fluorine atoms: three from two PF6(-) units (one bidentate and one monodentate) and one from each of six XeF2 molecules. The coordination sphere of the Cd atom consists of eight fluorine atoms: one from each of two PF6(-) units and one from each of six XeF2 molecules. Two of the XeF2 ligands about M in each compound are bridging ligands and are each linked to two M, generating infinite (-M-F-Xe-F-M-F-Xe-F-) chains along the b-axis in the Ca salt and along the c-axis in the Cd compound. The Cd2+ cation is smaller and more electronegative than the Ca2+ cation. These differences account for the higher F ligand coordination in the Ca2+ salt and for other structural features that distinguish them. The different stoichiometry of the PF6(-) salts when compared with their AsF6(-) analogues, which have the composition [M(XeF2)4](AsF6)2 (M = Ca, Cd), is in accord with the lower F ligand charge in the AsF6(-) when compared with that in the PF6(-) compound. Indeed, the AsF6(-) ligand charges appear to be similar to those in the XeF2-bridged species. 相似文献