全文获取类型
收费全文 | 1123篇 |
免费 | 58篇 |
国内免费 | 6篇 |
专业分类
化学 | 663篇 |
晶体学 | 14篇 |
力学 | 12篇 |
数学 | 164篇 |
物理学 | 334篇 |
出版年
2023年 | 9篇 |
2022年 | 21篇 |
2021年 | 38篇 |
2020年 | 38篇 |
2019年 | 47篇 |
2018年 | 45篇 |
2017年 | 33篇 |
2016年 | 59篇 |
2015年 | 38篇 |
2014年 | 39篇 |
2013年 | 72篇 |
2012年 | 86篇 |
2011年 | 95篇 |
2010年 | 37篇 |
2009年 | 43篇 |
2008年 | 66篇 |
2007年 | 56篇 |
2006年 | 63篇 |
2005年 | 55篇 |
2004年 | 31篇 |
2003年 | 22篇 |
2002年 | 21篇 |
2001年 | 12篇 |
2000年 | 11篇 |
1999年 | 13篇 |
1998年 | 6篇 |
1997年 | 7篇 |
1996年 | 9篇 |
1995年 | 6篇 |
1994年 | 5篇 |
1993年 | 4篇 |
1992年 | 4篇 |
1991年 | 9篇 |
1990年 | 6篇 |
1989年 | 3篇 |
1988年 | 2篇 |
1987年 | 4篇 |
1986年 | 11篇 |
1985年 | 8篇 |
1984年 | 10篇 |
1983年 | 4篇 |
1982年 | 4篇 |
1981年 | 9篇 |
1980年 | 3篇 |
1979年 | 3篇 |
1978年 | 3篇 |
1975年 | 2篇 |
1974年 | 2篇 |
1972年 | 3篇 |
1971年 | 2篇 |
排序方式: 共有1187条查询结果,搜索用时 15 毫秒
1.
Chemistry of Heterocyclic Compounds - This microreview presents the current state of research on functionalization of α-mangostin, a natural hydroxyxanthone. Examples of transformations are... 相似文献
2.
S. G. Barsov A. L. Getalov S. L. Ginsburg V. P. Koptev S. P. Kruglov L. A. Kuzmin S. V. Maleyev E. I. Maltsev S. M. Mikirtychyants N. A. Tarasov G. V. Shcherbakov V. G. Grebinnik V. N. Duginov A. B. Lazarev V. G. Olshevski S. N. Shilov V. A. Zhukov I. I. Gurevich B. F. Kirillov A. I. Klimov B. A. Nikolski A. V. Pirogov A. N. Ponomarev V. A. Suetin 《Hyperfine Interactions》1991,64(1-4):415-419
The zero field μSR-method has been used to study the magnetism in the disordered magnetic alloy Fe82−xNixCr18 near the three-critical, pointx=25. The dynamic and static local field distributions are analyzed. The difference between spin-glass states obtained either
from the paramagnetic or after the double transition is discussed. 相似文献
3.
4.
It is shown that a system of quaternion equations equivalent to the Dirac-Kähler equation is invariant with respect to transformations of field functions inducible by translations in quaternion coordinate space.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 10, pp. 89–92, October, 1989. 相似文献
5.
I. G. Alekseev P. E. Budkovsky V. P. Kanavets L. I. Koroleva B. V. Morozov V. M. Nesterov V. V. Ryltsov D. N. Svirida A. D. Sulimov V. V. Zhurkin Yu. A. Beloglazov A. I. Kovalev S. P. Kruglov D. V. Novinsky V. A. Shchedrov V. V. Sumachev V. Yu. Trautman N. A. Bazhanov E. I. Bunyatova 《Physics of Atomic Nuclei》2002,65(2):220-228
New experimental data on the spin-rotation parameters A and R measured for elastic π ± p scattering in the resonance region and on the asymmetry in pC scattering at primary momenta in the range 1.35–2.02 GeV/c, as well as in quasielastic proton scattering on nuclei in the same momentum range, are summarized. All these data were recently obtained by using the proton synchrotron installed at the Institute of Theoretical and Experimental Physics (ITEP, Moscow). The spectrum and features of seven isospin-3/2 baryon resonances that form a peak in the total cross section at a c.m. energy of 1.9 GeV are analyzed on the basis of new data on the parameters A and R, and the results of this analysis are presented. The experiments surveyed in this article were performed by a collaboration of researchers from ITEP and the Petersburg Nuclear Physics Institute (PNPI, Gatchina), the ITEP-PNPI collaboration. 相似文献
6.
We study the aggregation of oxygen dipoles well dispersed in a CaF2 crystal upon annealing at temperatures ranging from 370 to 420 K. The concentration of oxygen dipoles is monitored by measuring the intensity of the ionic thermocurrent peak as well as by absorption and luminescence spectroscopies. Results from three methods agree within experimental error and yield an activation energy of (1.2±0.1) eV for the diffusion of isolated oxygen centres in the crystal. 相似文献
7.
Philippe Boyer Gilles Renversez Evgeny Popov Michel Nevière 《Optical and Quantum Electronics》2006,38(1-3):217-230
The present work adapts a recent grating theory called “Fast Fourier factorization” to cylindrical coordinates in order to study microstructured optical fibers (MOFs). Compared with the classical differential method, this new differential method takes into account the truncation of Fourier series and the discontinuities of the fields across the diffracting surface with the help of new factorization rules. The main advantage of this method is that the directrix of the diffracting cylindrical surface is arbitrary and permits anisotropic and inhomogeneous media although its numerical application needs longer computation time, compared with other well-known numerical methods. The S-propagation algorithm is used to avoid numerical contaminations. The numerical results are validated and compared with the well-established Multipole method in the case of a MOF with six circular cylinders. Further, a new cross-sectional profile (with sectorial inclusions) that the Multipole method cannot consider is studied. 相似文献
8.
9.
Yellowish crystals of K2[(UO2)As2O7] ( 1 ) have been synthesized by solid‐state reactions method. The structure of 1 [orthorhombic, Pmmn, a = 12.601(2), b = 13.242(2), c = 5.621(1) Å, V = 937.9(3) Å3, Z = 4] has been solved by direct methods and refined to R1 = 0.049, wR2 = 0.1060 for 1059 observed reflections. The structure of 1 is based upon [(UO2)As2O7]2? sheets formed by corner sharing between [UO6]6? distorted octahedra and [As2O7]4? polyarsenate groups. The K+ cations are either in eightfold or tenfold coordination and are located between the sheets. The topology of the uranyl arsenate sheet is related to silicate minerals of the melilite group and related synthetic silicate, aluminate and germanate compounds. 相似文献
10.
Kudrik EV Theodoridis A van Eldik R Makarov SV 《Dalton transactions (Cambridge, England : 2003)》2005,(6):1117-1122
Catalytic oxidation of N,N'-dimethylthiourea and thiourea by dioxygen in water using a new cobalt(II) complex of octasulfophenyltetrapyrazinoporphyrazine was performed under mild conditions. The reaction is shown to include the formation of an intermediate anionic five-coordinate complex followed by an unusual two-electron oxidation to produce the corresponding urea and elemental sulfur (S8). Kinetic and thermodynamic parameters for the different reaction steps of the process were determined. Drastic differences in catalytic activity of cobalt and iron octasulfophenyltetrapyrazinoporphyrazines were observed. 相似文献