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1.
Xiaojuan Hao Camilla Nilsson Martin Jesberger Martina H. Stenzel Eva Malmstrm Thomas P. Davis Emma
stmark Christopher Barner‐Kowollik 《Journal of polymer science. Part A, Polymer chemistry》2004,42(23):5877-5890
The synthesis and characterization of novel first‐ and second‐generation true dendritic reversible addition–fragmentation chain transfer (RAFT) agents carrying 6 or 12 pendant 3‐benzylsulfanylthiocarbonylsulfanylpropionic acid RAFT end groups with Z‐group architecture based on 1,1,1‐hydroxyphenyl ethane and trimethylolpropane cores are described in detail. The multifunctional dendritic RAFT agents have been used to prepare star polymers of poly(butyl acrylate) (PBA) and polystyrene (PS) of narrow polydispersities (1.4 < polydispersity index < 1.1 for PBA and 1.5 < polydispersity index < 1.3 for PS) via bulk free‐radical polymerization at 60 °C. The novel dendrimer‐based multifunctional RAFT agents effect an efficient living polymerization process, as evidenced by the linear evolution of the number‐average molecular weight (Mn) with the monomer–polymer conversion, yielding star polymers with molecular weights of up to Mn = 160,000 g mol?1 for PBA (based on a linear PBA calibration) and up to Mn = 70,000 g mol?1 for PS (based on a linear PS calibration). A structural change in the chemical nature of the dendritic core (i.e., 1,1,1‐hydroxyphenyl ethane vs trimethylolpropane) has no influence on the observed molecular weight distributions. The star‐shaped structure of the generated polymers has been confirmed through the cleavage of the pendant arms off the core of the star‐shaped polymeric materials. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5877–5890, 2004 相似文献
2.
A new parallel storm surge model, the Parallel Environmental Model (PEM), is developed and tested by comparisons with analytic solutions. The PEM is a 2‐D vertically averaged, wetting and drying numerical model and can be operated in explicit, semi‐implicit and fully implicit modes. In the implicit mode, the propagation, Coriolis and bottom friction terms can all be treated implicitly. The advection and diffusion terms are solved with a parallel Eulerian–Lagrangian scheme developed for this study. The model is developed specifically for use on parallel computer systems and will function accordingly in either explicit of implicit modes. Storm boundary conditions are based on a simple exponential decay of pressure from the centre of a storm. The simulated flooding caused by a major Category 5 hurricane making landfall in the Indian River Lagoon, Florida is then presented as an example application of the PEM. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
3.
Nathalie Charton Achim Feldermann Alexander Theis Martina H. Stenzel Thomas P. Davis Christopher Barner‐Kowollik 《Journal of polymer science. Part A, Polymer chemistry》2004,42(21):5559-5559
The original article to which this Erratum refers was published in J Polym Sci Part A: Polym Chem (2004) 42(20) 5170–5179. No abstract. 相似文献
4.
Hydrogenated amorphous GaP films have been prepared by reactive rf sputtering. Infrared spectroscopy, optical transmission and reflection, photothermal deflection spectroscopy and dc conductivity have been studied to investigate the local bonding configurations, the optical absorption edges and the temperature dependence of the conductivity as a function of hydrogen content. The results are discussed and compared with the effects of hydrogenation on amorphous Si. 相似文献
5.
J. Pollanen K.R. Shirer S. Blinstein J.P. Davis H. Choi T.M. Lippman W.P. Halperin L.B. Lurio 《Journal of Non》2008,354(40-41):4668-4674
We discuss two methods by which high porosity silica aerogels can be engineered to exhibit global anisotropy. First, anisotropy can be introduced with axial strain (i.e. axial compression). In addition, intrinsic anisotropy can result during growth and drying stages and, suitably controlled, it can be correlated with preferential radial shrinkage in cylindrical samples. We have performed small angle X-ray scattering (SAXS) to characterize these two types of anisotropy. We show that global anisotropy originating from either strain or shrinkage leads to optical birefringence and that optical cross-polarization studies are a useful characterization of the uniformity of the imposed global anisotropy. 相似文献
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M.I. Bruce O.M.Abu Salah R.E. Davis N.V. Raghavan 《Journal of organometallic chemistry》1973,64(3):C48-C50
In contrast to a related iron—copper compound, the complex (π-C5H5)Ru(PPh3)2(C2Ph)CuCl is shown to be monomeric, and contains linear dicoordinate copper(I); the reactions of this and similar complexes with metal carbonyls are sources of new mixed-metal clusters, such as (π-C5H5)Fe2 Ru(C2Ph)(CO)6 (PPh3). 相似文献
10.
In an extension of studies of flameless atomizers for atomic-absorption spectrometry, an electrically heated tungsten-rhenium alloy wire loop was examined. Reduction of metallic salts to ground-state metal atoms was accomplished with the high temperature produced by the loop. Lead and nickel were investigated. Experimental parameters such as wavelength, slit width, atomization temperature and sheathing gas flow rate were optimized. Absolute detection limits of 6.6·10?10 and 1.2·10?10, and absolute sensitivities of 7·10?10 and 8·10?11 g of lead, were established for unenclosed and enclosed cells, respectively. The interferences of twenty cations and sixteen anions were studied; foreign cations generally enhanced the lead absorption by retarding its vaporization, allowing the slow detection system to respond more efficiently. Nickel was investigated as a representative less volatile metal; an absolute detection limit of 1.6·10?9 and an absolute sensitivity of 9·10?10 g of nickel were established. 相似文献